Dual-Functional TiO2/SiO2@Poly(Hexadecyl Methacrylate-co-Butyl Methacrylate-co-Methyl Acrylate) Composites: Nanointegrated Enhancements in Oil Absorption and High-Efficiency Emulsion Interface Demulsification.
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| Title: | Dual-Functional TiO |
|---|---|
| Authors: | Dai, Weiren1 (AUTHOR), Xu, Bo1 (AUTHOR) boxu416@sina.com, Lan, Guihong1 (AUTHOR), Qiu, Haiyan1 (AUTHOR), Luo, Pan1 (AUTHOR), Su, Bin2 (AUTHOR) |
| Source: | Journal of Macromolecular Science: Physics. 2026, Vol. 65 Issue 1, p1-27. 27p. |
| Subjects: | Demulsification, Oil removal (Sewage purification), Acrylic resins, Environmental remediation, Absorption, Nanostructured materials, Composite materials, Emulsion polymerization |
| Abstract: | Our research described in this report introduces a multifunctional composite resin, TiO2/SiO2@poly(hexadecyl methacrylate-co-butyl methacrylate-co-methyl acrylate), synthesized to enhance oil absorption and demulsification for oily wastewater treatment. By incorporating hydrophobically modified nano-titanium dioxide (nano-TiO2) and nano-silicon dioxide (nano-SiO2) into a polyacrylate resin through suspension polymerization, we aimed to overcome the limitations of traditional oil absorbent resins. The resin's formulation included hexadecyl methacrylate, butyl methacrylate, and methyl acrylate. Characterization was conducted through measurements of contact angle, Fourier-transform infrared spectroscopy, scanning electron microscopy, and Brunauer–Emmett–Teller surface area analyses. The study meticulously optimized the chemical synthesis conditions, focusing on the amount of monomer, initiator and crosslinker, which are crucial for the polymerization reaction. Additionally, the physical parameters, such as the particle size and quantity of the nano-materials, were carefully controlled to achieve the desired material properties. The inclusion of nano-TiO2 and nano-SiO2 significantly enriched the resin's porous structure, boosting its oil absorption ratios for oil in various solvents, notably enhancing stability and recyclability. The resin exhibited superior oil absorption capacities (e.g. 54.7 g/g for trichloromethane) and improved emulsion separation efficiency (e.g. 98.10% for trichloromethane emulsions), marking a substantial advancement in materials for environmental remediation applications. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Macromolecular Science: Physics is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 190438604 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Dual-Functional TiO<subscript>2</subscript>/SiO<subscript>2</subscript>@Poly(Hexadecyl Methacrylate-co-Butyl Methacrylate-co-Methyl Acrylate) Composites: Nanointegrated Enhancements in Oil Absorption and High-Efficiency Emulsion Interface Demulsification. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Dai%2C+Weiren%22">Dai, Weiren</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xu%2C+Bo%22">Xu, Bo</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> boxu416@sina.com</i><br /><searchLink fieldCode="AR" term="%22Lan%2C+Guihong%22">Lan, Guihong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Qiu%2C+Haiyan%22">Qiu, Haiyan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Luo%2C+Pan%22">Luo, Pan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Su%2C+Bin%22">Su, Bin</searchLink><relatesTo>2</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Macromolecular+Science%3A+Physics%22">Journal of Macromolecular Science: Physics</searchLink>. 2026, Vol. 65 Issue 1, p1-27. 27p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Demulsification%22">Demulsification</searchLink><br /><searchLink fieldCode="DE" term="%22Oil+removal+%28Sewage+purification%29%22">Oil removal (Sewage purification)</searchLink><br /><searchLink fieldCode="DE" term="%22Acrylic+resins%22">Acrylic resins</searchLink><br /><searchLink fieldCode="DE" term="%22Environmental+remediation%22">Environmental remediation</searchLink><br /><searchLink fieldCode="DE" term="%22Absorption%22">Absorption</searchLink><br /><searchLink fieldCode="DE" term="%22Nanostructured+materials%22">Nanostructured materials</searchLink><br /><searchLink fieldCode="DE" term="%22Composite+materials%22">Composite materials</searchLink><br /><searchLink fieldCode="DE" term="%22Emulsion+polymerization%22">Emulsion polymerization</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Our research described in this report introduces a multifunctional composite resin, TiO2/SiO2@poly(hexadecyl methacrylate-co-butyl methacrylate-co-methyl acrylate), synthesized to enhance oil absorption and demulsification for oily wastewater treatment. By incorporating hydrophobically modified nano-titanium dioxide (nano-TiO2) and nano-silicon dioxide (nano-SiO2) into a polyacrylate resin through suspension polymerization, we aimed to overcome the limitations of traditional oil absorbent resins. The resin's formulation included hexadecyl methacrylate, butyl methacrylate, and methyl acrylate. Characterization was conducted through measurements of contact angle, Fourier-transform infrared spectroscopy, scanning electron microscopy, and Brunauer–Emmett–Teller surface area analyses. The study meticulously optimized the chemical synthesis conditions, focusing on the amount of monomer, initiator and crosslinker, which are crucial for the polymerization reaction. Additionally, the physical parameters, such as the particle size and quantity of the nano-materials, were carefully controlled to achieve the desired material properties. The inclusion of nano-TiO2 and nano-SiO2 significantly enriched the resin's porous structure, boosting its oil absorption ratios for oil in various solvents, notably enhancing stability and recyclability. The resin exhibited superior oil absorption capacities (e.g. 54.7 g/g for trichloromethane) and improved emulsion separation efficiency (e.g. 98.10% for trichloromethane emulsions), marking a substantial advancement in materials for environmental remediation applications. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Macromolecular Science: Physics is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1080/00222348.2024.2406151 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 27 StartPage: 1 Subjects: – SubjectFull: Demulsification Type: general – SubjectFull: Oil removal (Sewage purification) Type: general – SubjectFull: Acrylic resins Type: general – SubjectFull: Environmental remediation Type: general – SubjectFull: Absorption Type: general – SubjectFull: Nanostructured materials Type: general – SubjectFull: Composite materials Type: general – SubjectFull: Emulsion polymerization Type: general Titles: – TitleFull: Dual-Functional TiO2/SiO2@Poly(Hexadecyl Methacrylate-co-Butyl Methacrylate-co-Methyl Acrylate) Composites: Nanointegrated Enhancements in Oil Absorption and High-Efficiency Emulsion Interface Demulsification. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Dai, Weiren – PersonEntity: Name: NameFull: Xu, Bo – PersonEntity: Name: NameFull: Lan, Guihong – PersonEntity: Name: NameFull: Qiu, Haiyan – PersonEntity: Name: NameFull: Luo, Pan – PersonEntity: Name: NameFull: Su, Bin IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 01 Text: 2026 Type: published Y: 2026 Identifiers: – Type: issn-print Value: 00222348 Numbering: – Type: volume Value: 65 – Type: issue Value: 1 Titles: – TitleFull: Journal of Macromolecular Science: Physics Type: main |
| ResultId | 1 |
