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Recent Advances in the Electrocatalytic Performance of Nanoporous Materials for Hydrogen Evolution Reaction.

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Title: Recent Advances in the Electrocatalytic Performance of Nanoporous Materials for Hydrogen Evolution Reaction.
Authors: Li, Zhangyi1 (AUTHOR), Yang, Lin1,2 (AUTHOR), Chen, Yingqi1,3 (AUTHOR), Xu, Wence1,2,4 (AUTHOR), Gao, Zhonghui1,2 (AUTHOR), Zhu, Jiamin1,2 (AUTHOR) mfmzjm@tju.edu.cn, Liang, Yanqin1,2,3 (AUTHOR), Jiang, Hui1,2,3 (AUTHOR), Li, Zhaoyang1,2,3 (AUTHOR), Cui, Zhenduo1,2,3 (AUTHOR), Wang, Hao4 (AUTHOR) hwang@mat.shimane-u.ac.jp, Zhu, Shengli1,2,3 (AUTHOR)
Source: Nanomaterials (2079-4991). Dec2025, Vol. 15 Issue 23, p1782. 31p.
Subjects: Hydrogen evolution reactions, Nanoporous materials, Transition metals, Water electrolysis, Electrocatalysis, Nonferrous metals, Catalytic activity
Abstract: Electrocatalytic water splitting for hydrogen production is a crucial technology in achieving carbon neutrality. The development of efficient and stable hydrogen evolution reaction (HER) electrocatalysts is a core challenge in this field. This review systematically summarizes the latest research advancements in nanoporous transition metal-based catalysts, covering metal alloys and compounds. Through strategies such as compositional optimization, crystal structure modulation, interface engineering, and nanoporous structure design, these non-precious metal catalysts exhibit outstanding performance comparable to commercial platinum-carbon catalysts across a wide pH range. This paper thoroughly discusses the catalytic mechanisms of different material systems, including electronic structure regulation, active site exposure, and mass transport optimization. Finally, the challenges faced in current research are summarized, and future directions are projected, including scalable fabrication processes and performance validation in real electrolysis cell environments. This review provides significant insights into designing next-generation efficient and stable non-precious metal electrocatalysts. [ABSTRACT FROM AUTHOR]
Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Recent Advances in the Electrocatalytic Performance of Nanoporous Materials for Hydrogen Evolution Reaction.
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  Data: <searchLink fieldCode="AR" term="%22Li%2C+Zhangyi%22">Li, Zhangyi</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yang%2C+Lin%22">Yang, Lin</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Chen%2C+Yingqi%22">Chen, Yingqi</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xu%2C+Wence%22">Xu, Wence</searchLink><relatesTo>1,2,4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Gao%2C+Zhonghui%22">Gao, Zhonghui</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhu%2C+Jiamin%22">Zhu, Jiamin</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> mfmzjm@tju.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Liang%2C+Yanqin%22">Liang, Yanqin</searchLink><relatesTo>1,2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jiang%2C+Hui%22">Jiang, Hui</searchLink><relatesTo>1,2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Li%2C+Zhaoyang%22">Li, Zhaoyang</searchLink><relatesTo>1,2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Cui%2C+Zhenduo%22">Cui, Zhenduo</searchLink><relatesTo>1,2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Hao%22">Wang, Hao</searchLink><relatesTo>4</relatesTo> (AUTHOR)<i> hwang@mat.shimane-u.ac.jp</i><br /><searchLink fieldCode="AR" term="%22Zhu%2C+Shengli%22">Zhu, Shengli</searchLink><relatesTo>1,2,3</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Nanomaterials+%282079-4991%29%22">Nanomaterials (2079-4991)</searchLink>. Dec2025, Vol. 15 Issue 23, p1782. 31p.
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  Data: <searchLink fieldCode="DE" term="%22Hydrogen+evolution+reactions%22">Hydrogen evolution reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Nanoporous+materials%22">Nanoporous materials</searchLink><br /><searchLink fieldCode="DE" term="%22Transition+metals%22">Transition metals</searchLink><br /><searchLink fieldCode="DE" term="%22Water+electrolysis%22">Water electrolysis</searchLink><br /><searchLink fieldCode="DE" term="%22Electrocatalysis%22">Electrocatalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Nonferrous+metals%22">Nonferrous metals</searchLink><br /><searchLink fieldCode="DE" term="%22Catalytic+activity%22">Catalytic activity</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Electrocatalytic water splitting for hydrogen production is a crucial technology in achieving carbon neutrality. The development of efficient and stable hydrogen evolution reaction (HER) electrocatalysts is a core challenge in this field. This review systematically summarizes the latest research advancements in nanoporous transition metal-based catalysts, covering metal alloys and compounds. Through strategies such as compositional optimization, crystal structure modulation, interface engineering, and nanoporous structure design, these non-precious metal catalysts exhibit outstanding performance comparable to commercial platinum-carbon catalysts across a wide pH range. This paper thoroughly discusses the catalytic mechanisms of different material systems, including electronic structure regulation, active site exposure, and mass transport optimization. Finally, the challenges faced in current research are summarized, and future directions are projected, including scalable fabrication processes and performance validation in real electrolysis cell environments. This review provides significant insights into designing next-generation efficient and stable non-precious metal electrocatalysts. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/nano15231782
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      – Code: eng
        Text: English
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        PageCount: 31
        StartPage: 1782
    Subjects:
      – SubjectFull: Hydrogen evolution reactions
        Type: general
      – SubjectFull: Nanoporous materials
        Type: general
      – SubjectFull: Transition metals
        Type: general
      – SubjectFull: Water electrolysis
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      – SubjectFull: Electrocatalysis
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      – SubjectFull: Nonferrous metals
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      – SubjectFull: Catalytic activity
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      – TitleFull: Recent Advances in the Electrocatalytic Performance of Nanoporous Materials for Hydrogen Evolution Reaction.
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              Text: Dec2025
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