Bibliographic Details
| Title: |
Interzeolite-type transformation between microporous titanosilicates. |
| Authors: |
Ferdov, Stanislav1,2 (AUTHOR) sferdov@fisica.uminho.pt |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. 1/27/2026, Vol. 55 Issue 4, p1653-1658. 6p. |
| Subjects: |
Titanium silicate, Silicates, Crystallization, Molecular self-assembly, Potassium hydroxide |
| Abstract: |
This work reveals the first example of an interzeolite-type transformation between microporous heteropolyhedral silicates. In KOH solution, preformed spherulitic particles of the microporous titanosilicate ETS-4 (Engelhard Titanium Silicate-4) transform into single crystals of GTS-1 (Grace Titanium Silicate-1). Mechanistically, the transformation follows a distinct reversed crystallization pathway, beginning on the surface of a seed particle and ending in the reconstructive self-assembly of multiple single crystals. In addition to advancing synthesis methodologies for microporous titanosilicates, this work provides mechanistic insights into a crystallization route that enables templating of the crystal morphology through particle self-assembly. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
