Interzeolite-type transformation between microporous titanosilicates.
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| Title: | Interzeolite-type transformation between microporous titanosilicates. |
|---|---|
| Authors: | Ferdov, Stanislav1,2 (AUTHOR) sferdov@fisica.uminho.pt |
| Source: | Dalton Transactions: An International Journal of Inorganic Chemistry. 1/27/2026, Vol. 55 Issue 4, p1653-1658. 6p. |
| Subjects: | Titanium silicate, Silicates, Crystallization, Molecular self-assembly, Potassium hydroxide |
| Abstract: | This work reveals the first example of an interzeolite-type transformation between microporous heteropolyhedral silicates. In KOH solution, preformed spherulitic particles of the microporous titanosilicate ETS-4 (Engelhard Titanium Silicate-4) transform into single crystals of GTS-1 (Grace Titanium Silicate-1). Mechanistically, the transformation follows a distinct reversed crystallization pathway, beginning on the surface of a seed particle and ending in the reconstructive self-assembly of multiple single crystals. In addition to advancing synthesis methodologies for microporous titanosilicates, this work provides mechanistic insights into a crystallization route that enables templating of the crystal morphology through particle self-assembly. [ABSTRACT FROM AUTHOR] |
| Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 191103312 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Interzeolite-type transformation between microporous titanosilicates. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Ferdov%2C+Stanislav%22">Ferdov, Stanislav</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> sferdov@fisica.uminho.pt</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 1/27/2026, Vol. 55 Issue 4, p1653-1658. 6p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Titanium+silicate%22">Titanium silicate</searchLink><br /><searchLink fieldCode="DE" term="%22Silicates%22">Silicates</searchLink><br /><searchLink fieldCode="DE" term="%22Crystallization%22">Crystallization</searchLink><br /><searchLink fieldCode="DE" term="%22Molecular+self-assembly%22">Molecular self-assembly</searchLink><br /><searchLink fieldCode="DE" term="%22Potassium+hydroxide%22">Potassium hydroxide</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: This work reveals the first example of an interzeolite-type transformation between microporous heteropolyhedral silicates. In KOH solution, preformed spherulitic particles of the microporous titanosilicate ETS-4 (Engelhard Titanium Silicate-4) transform into single crystals of GTS-1 (Grace Titanium Silicate-1). Mechanistically, the transformation follows a distinct reversed crystallization pathway, beginning on the surface of a seed particle and ending in the reconstructive self-assembly of multiple single crystals. In addition to advancing synthesis methodologies for microporous titanosilicates, this work provides mechanistic insights into a crystallization route that enables templating of the crystal morphology through particle self-assembly. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
| PLink | https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=191103312 |
| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1039/d5dt02300a Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 6 StartPage: 1653 Subjects: – SubjectFull: Titanium silicate Type: general – SubjectFull: Silicates Type: general – SubjectFull: Crystallization Type: general – SubjectFull: Molecular self-assembly Type: general – SubjectFull: Potassium hydroxide Type: general Titles: – TitleFull: Interzeolite-type transformation between microporous titanosilicates. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Ferdov, Stanislav IsPartOfRelationships: – BibEntity: Dates: – D: 27 M: 01 Text: 1/27/2026 Type: published Y: 2026 Identifiers: – Type: issn-print Value: 14779226 Numbering: – Type: volume Value: 55 – Type: issue Value: 4 Titles: – TitleFull: Dalton Transactions: An International Journal of Inorganic Chemistry Type: main |
| ResultId | 1 |
