Collision-induced first overtone band of in binary mixtures – and –CO

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Title: Collision-induced first overtone band of in binary mixtures – and –CO
Authors: Abu-Kharma, M. mkharma@physics.mun.ca, Stamp, C.1, Varghese, G.1, Paddi Reddy, S.1 spreddy@physics.mun.ca
Source: Journal of Quantitative Spectroscopy & Radiative Transfer. Feb2006, Vol. 97 Issue 3, p332-343. 12p.
Subjects: Spectrum analysis, Absorption, Infrared spectra, Physical & theoretical chemistry
Abstract: Abstract: Enhancement spectra of the collision-induced absorption (CIA) of in its first overtone region 7500– in binary mixtures – and –CO were studied at 298K for base densities of in the range 89–145amagat and for partial densities of and CO in the range 19–392amagat. The observed spectra confirm that the isotropic overlap induction is absent in the 2–0 band of unlike in the CIA spectra of the fundamental band of . Binary and ternary absorption coefficients were determined from the integrated absorption coefficients of the band. Enhancement absorption profiles of – and –CO consist of a total of 434 components of quadrupolar double transitions. Profile analysis of the spectra was carried out using Birnbaum–Cohen line shape function for the individual components of the band and characteristic line shape parameters were determined from the analysis. [Copyright &y& Elsevier]
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Abstract:Abstract: Enhancement spectra of the collision-induced absorption (CIA) of in its first overtone region 7500– in binary mixtures – and –CO were studied at 298K for base densities of in the range 89–145amagat and for partial densities of and CO in the range 19–392amagat. The observed spectra confirm that the isotropic overlap induction is absent in the 2–0 band of unlike in the CIA spectra of the fundamental band of . Binary and ternary absorption coefficients were determined from the integrated absorption coefficients of the band. Enhancement absorption profiles of – and –CO consist of a total of 434 components of quadrupolar double transitions. Profile analysis of the spectra was carried out using Birnbaum–Cohen line shape function for the individual components of the band and characteristic line shape parameters were determined from the analysis. [Copyright &y& Elsevier]
ISSN:00224073
DOI:10.1016/j.jqsrt.2005.04.012