Novel sustainable carbon dot as dual replacements for emulsion stabilizers and Photoinitiators in macroporous polymerized high internal phase emulsion fabrication.
Saved in:
| Title: | Novel sustainable carbon dot as dual replacements for emulsion stabilizers and Photoinitiators in macroporous polymerized high internal phase emulsion fabrication. |
|---|---|
| Authors: | Gao, Woming1 (AUTHOR) wgao20@sheffield.ac.uk, Cheng, Zeming1,2 (AUTHOR), Farr, Nicholas T.H.1,2 (AUTHOR), Rodenburg, Cornelia1,2 (AUTHOR) c.rodenburg@sheffield.ac.uk, Claeyssens, Frederik1,2 (AUTHOR) f.claeyssens@sheffield.ac.uk |
| Source: | Journal of Colloid & Interface Science. Apr2026, Vol. 708, pN.PAG-N.PAG. 1p. |
| Subjects: | Carbon nanodots, Emulsions, Environmental sciences, Biocompatibility, Photopolymerization, Permeability, Tissue engineering |
| Abstract: | Both emulsion stabilizers and photoinitiators are essential components in preparing photocurable water-in-oil (w/o) Polymerized High Internal Phase Emulsions (PolyHIPEs). Conventional stabilizers like Hypermer B246 and photoinitiators like 2,4,6-Trimethylbenzoyldiphenylphosphine oxide (TPO) pose environmental and biological hazards, requiring careful removal before use in bioengineering applications. Furthermore, PolyHIPEs prepared with traditional surfactants often feature narrow pores and pore throats, limiting effective fluid and cell infiltration. As a class of easy-synthesizing and biocompatible nanoparticles, carbon dots (CDs) exhibit potential for use as emulsion stabilizers and photoinitiators. Herein, novel amphiphilic carbon dots (GW CDs) were synthesised from Gromwell root waste, a byproduct of shikonin extraction, as sustainable alternative. GW CDs demonstrated excellent emulsion-stabilizing ability, effective photoinitiating performance and superior biocompatibility. GW CDs were employed to stabilize the emulsions and successfully crosslink them under UV light to fabricate 2-ethylhexyl acrylate (EHA)- isobornyl acrylate (IBOA)- trimethylolpropane triacrylate (TMPTA) PolyHIPEs. The pore size and pore throat formation of the resulting PolyHIPEs could be effectively tuned by adjusting the GW CDs content. Compared to PolyHIPEs prepared using Hypermer B246 and TPO, the GW CD-stabilized counterparts exhibited significantly larger pore sizes and pore throats, improving fluid and cell permeability for tissue engineering applications. Additionally, GW CDs possess upconversion luminescence, pH sensitivity, and cell-imaging capabilities, further highlighting their potential in biomedical engineering and environmental science applications. [Display omitted] • Novel sustainable amphiphilic carbon dots (GW CDs) made from the post shikonin extraction gromwell roots residue. • For the first time GW CDs have been used as a biocompatible dual replacement for traditional surfactants and photoinitiators. • w/o EHA-IBOA-TMPTA PolyHIPE was successfully stabilized and cured only using GW CDs. • GW CDs-stabilized PolyHIPEs have larger, tunable pores and throats, aiding fluid flow and cell infiltration for tissue engineering. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Colloid & Interface Science is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
|---|---|
| Header | DbId: egs DbLabel: Engineering Source An: 191325268 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
| IllustrationInfo | |
| Items | – Name: Title Label: Title Group: Ti Data: Novel sustainable carbon dot as dual replacements for emulsion stabilizers and Photoinitiators in macroporous polymerized high internal phase emulsion fabrication. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Gao%2C+Woming%22">Gao, Woming</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> wgao20@sheffield.ac.uk</i><br /><searchLink fieldCode="AR" term="%22Cheng%2C+Zeming%22">Cheng, Zeming</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Farr%2C+Nicholas+T%2EH%2E%22">Farr, Nicholas T.H.</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Rodenburg%2C+Cornelia%22">Rodenburg, Cornelia</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> c.rodenburg@sheffield.ac.uk</i><br /><searchLink fieldCode="AR" term="%22Claeyssens%2C+Frederik%22">Claeyssens, Frederik</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> f.claeyssens@sheffield.ac.uk</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Colloid+%26+Interface+Science%22">Journal of Colloid & Interface Science</searchLink>. Apr2026, Vol. 708, pN.PAG-N.PAG. 1p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Carbon+nanodots%22">Carbon nanodots</searchLink><br /><searchLink fieldCode="DE" term="%22Emulsions%22">Emulsions</searchLink><br /><searchLink fieldCode="DE" term="%22Environmental+sciences%22">Environmental sciences</searchLink><br /><searchLink fieldCode="DE" term="%22Biocompatibility%22">Biocompatibility</searchLink><br /><searchLink fieldCode="DE" term="%22Photopolymerization%22">Photopolymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Permeability%22">Permeability</searchLink><br /><searchLink fieldCode="DE" term="%22Tissue+engineering%22">Tissue engineering</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Both emulsion stabilizers and photoinitiators are essential components in preparing photocurable water-in-oil (w/o) Polymerized High Internal Phase Emulsions (PolyHIPEs). Conventional stabilizers like Hypermer B246 and photoinitiators like 2,4,6-Trimethylbenzoyldiphenylphosphine oxide (TPO) pose environmental and biological hazards, requiring careful removal before use in bioengineering applications. Furthermore, PolyHIPEs prepared with traditional surfactants often feature narrow pores and pore throats, limiting effective fluid and cell infiltration. As a class of easy-synthesizing and biocompatible nanoparticles, carbon dots (CDs) exhibit potential for use as emulsion stabilizers and photoinitiators. Herein, novel amphiphilic carbon dots (GW CDs) were synthesised from Gromwell root waste, a byproduct of shikonin extraction, as sustainable alternative. GW CDs demonstrated excellent emulsion-stabilizing ability, effective photoinitiating performance and superior biocompatibility. GW CDs were employed to stabilize the emulsions and successfully crosslink them under UV light to fabricate 2-ethylhexyl acrylate (EHA)- isobornyl acrylate (IBOA)- trimethylolpropane triacrylate (TMPTA) PolyHIPEs. The pore size and pore throat formation of the resulting PolyHIPEs could be effectively tuned by adjusting the GW CDs content. Compared to PolyHIPEs prepared using Hypermer B246 and TPO, the GW CD-stabilized counterparts exhibited significantly larger pore sizes and pore throats, improving fluid and cell permeability for tissue engineering applications. Additionally, GW CDs possess upconversion luminescence, pH sensitivity, and cell-imaging capabilities, further highlighting their potential in biomedical engineering and environmental science applications. [Display omitted] • Novel sustainable amphiphilic carbon dots (GW CDs) made from the post shikonin extraction gromwell roots residue. • For the first time GW CDs have been used as a biocompatible dual replacement for traditional surfactants and photoinitiators. • w/o EHA-IBOA-TMPTA PolyHIPE was successfully stabilized and cured only using GW CDs. • GW CDs-stabilized PolyHIPEs have larger, tunable pores and throats, aiding fluid flow and cell infiltration for tissue engineering. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Colloid & Interface Science is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
| PLink | https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=191325268 |
| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.jcis.2026.139838 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 1 StartPage: N.PAG Subjects: – SubjectFull: Carbon nanodots Type: general – SubjectFull: Emulsions Type: general – SubjectFull: Environmental sciences Type: general – SubjectFull: Biocompatibility Type: general – SubjectFull: Photopolymerization Type: general – SubjectFull: Permeability Type: general – SubjectFull: Tissue engineering Type: general Titles: – TitleFull: Novel sustainable carbon dot as dual replacements for emulsion stabilizers and Photoinitiators in macroporous polymerized high internal phase emulsion fabrication. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Gao, Woming – PersonEntity: Name: NameFull: Cheng, Zeming – PersonEntity: Name: NameFull: Farr, Nicholas T.H. – PersonEntity: Name: NameFull: Rodenburg, Cornelia – PersonEntity: Name: NameFull: Claeyssens, Frederik IsPartOfRelationships: – BibEntity: Dates: – D: 15 M: 04 Text: Apr2026 Type: published Y: 2026 Identifiers: – Type: issn-print Value: 00219797 Numbering: – Type: volume Value: 708 Titles: – TitleFull: Journal of Colloid & Interface Science Type: main |
| ResultId | 1 |
