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Characterization of Electron Beam-Induced Polymerization of Isodecyl Methacrylate, Benzyl Methacrylate, and Their Equimolar Mixture Based on Monomer Properties.

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Title: Characterization of Electron Beam-Induced Polymerization of Isodecyl Methacrylate, Benzyl Methacrylate, and Their Equimolar Mixture Based on Monomer Properties.
Authors: Antonov, Ilia1 (AUTHOR) iliya.antonov92@yandex.ru, Mikhailenko, Mikhail1,2 (AUTHOR), Shakhtshneider, Tatyana1,3 (AUTHOR), Ulihin, Artem1 (AUTHOR), Zelikman, Maxim1,2 (AUTHOR), Bryazgin, Alexandr2,3 (AUTHOR), Eltsov, Ilia3 (AUTHOR)
Source: Polymers (20734360). Feb2026, Vol. 18 Issue 3, p368. 16p.
Subjects: Polymerization, Copolymerization, Heat treatment, Ionizing radiation, Chemical properties, Methyl methacrylate
Abstract: The study examined the polymerization of methacrylic acid derivatives with bulky substituents (isodecyl-, benzyl-), as well as the synthesis of their copolymer through radiation initiation followed by thermal treatment. It has been discovered that the polymerization rate in equimolar monomer mixtures substantially surpasses the rate in pure monomers. We hypothesize that the substantial degree of association with the liquid monomer hinders structural rearrangements preceding polymerization. We tested this hypothesis by employing various analytical methods. [ABSTRACT FROM AUTHOR]
Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 191587408
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PubType: Academic Journal
PubTypeId: academicJournal
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  Label: Title
  Group: Ti
  Data: Characterization of Electron Beam-Induced Polymerization of Isodecyl Methacrylate, Benzyl Methacrylate, and Their Equimolar Mixture Based on Monomer Properties.
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  Data: <searchLink fieldCode="AR" term="%22Antonov%2C+Ilia%22">Antonov, Ilia</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> iliya.antonov92@yandex.ru</i><br /><searchLink fieldCode="AR" term="%22Mikhailenko%2C+Mikhail%22">Mikhailenko, Mikhail</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Shakhtshneider%2C+Tatyana%22">Shakhtshneider, Tatyana</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ulihin%2C+Artem%22">Ulihin, Artem</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zelikman%2C+Maxim%22">Zelikman, Maxim</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Bryazgin%2C+Alexandr%22">Bryazgin, Alexandr</searchLink><relatesTo>2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Eltsov%2C+Ilia%22">Eltsov, Ilia</searchLink><relatesTo>3</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Polymers+%2820734360%29%22">Polymers (20734360)</searchLink>. Feb2026, Vol. 18 Issue 3, p368. 16p.
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  Data: <searchLink fieldCode="DE" term="%22Polymerization%22">Polymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Copolymerization%22">Copolymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Heat+treatment%22">Heat treatment</searchLink><br /><searchLink fieldCode="DE" term="%22Ionizing+radiation%22">Ionizing radiation</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+properties%22">Chemical properties</searchLink><br /><searchLink fieldCode="DE" term="%22Methyl+methacrylate%22">Methyl methacrylate</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The study examined the polymerization of methacrylic acid derivatives with bulky substituents (isodecyl-, benzyl-), as well as the synthesis of their copolymer through radiation initiation followed by thermal treatment. It has been discovered that the polymerization rate in equimolar monomer mixtures substantially surpasses the rate in pure monomers. We hypothesize that the substantial degree of association with the liquid monomer hinders structural rearrangements preceding polymerization. We tested this hypothesis by employing various analytical methods. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/polym18030368
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      – Code: eng
        Text: English
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        StartPage: 368
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        Type: general
      – SubjectFull: Copolymerization
        Type: general
      – SubjectFull: Heat treatment
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      – SubjectFull: Ionizing radiation
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      – SubjectFull: Chemical properties
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      – SubjectFull: Methyl methacrylate
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      – TitleFull: Characterization of Electron Beam-Induced Polymerization of Isodecyl Methacrylate, Benzyl Methacrylate, and Their Equimolar Mixture Based on Monomer Properties.
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              Text: Feb2026
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              Y: 2026
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