NH 4 F and VO (Acac) 2 Tuning of Hexagram-Shaped Co 3 O 4 Morphology for High-Performance Supercapacitor Electrodes.
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| Title: | NH 4 F and VO (Acac) 2 Tuning of Hexagram-Shaped Co 3 O 4 Morphology for High-Performance Supercapacitor Electrodes. |
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| Authors: | Yang, Huanping1 (AUTHOR) hpyang@zust.edu.cn, Zhang, Zhiguo1,2 (AUTHOR), Fang, Ziming1,3 (AUTHOR), Zhao, Yutian3,4 (AUTHOR), Xiong, Bitao1 (AUTHOR), Lang, Xiaoli1,2 (AUTHOR), Shen, Yanting1,3 (AUTHOR), Li, Xing'ao1,4 (AUTHOR), Wang, Yan1 (AUTHOR) |
| Source: | Nanomaterials (2079-4991). Feb2026, Vol. 16 Issue 3, p162. 14p. |
| Subjects: | Supercapacitor electrodes, Ammonium fluoride, Nanostructured materials, Kirkendall effect, Supercapacitor performance |
| Abstract: | In this work, by employing NH4F as a structure-directing agent (SDA) and VO(acac)2, we have manipulated the morphology of Co3O4, leading to the creation of a novel hexagram-like structure with exceptional evenness in distribution. To comprehend the growth mechanism and elucidate the functions of various agents involved, experiments were conducted under diverse conditions with varying reagent ratios. The results indicate that, under the influence of NH4F as the structure-directing agent (SDA), the hexagram-shaped Co3O4 structure exhibits sensitivity to both reaction time and temperature, implying that its growth mechanism is regulated by the Kirkendall effect and involves partial cation exchange. Additionally, with alteration of reagent ratios, Co3O4 with ball-flower morphology was synthesized successfully. Through cross-section SEM examination, the observed growth mechanisms for both the hexagram and ball-flower structures were substantiated. Lastly, electrochemical performance tests of the hexagram and ball-flower structures on SC electrode were carried out, and specific capacitances were 452 C/g (1062 F/g) and 696 C/g (1339 F/g), respectively. The hexagram-shaped Co3O4 structure displays exceptional SC electrode material characteristics, retaining an outstanding capacitance of 93.1% even after 10,000 cycles, highlighting its superior cycle performance. This paper hopes to inspire further SC electrode materials studies based on its novel morphology modulation strategy. [ABSTRACT FROM AUTHOR] |
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| Database: | Engineering Source |
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| Abstract: | In this work, by employing NH4F as a structure-directing agent (SDA) and VO(acac)2, we have manipulated the morphology of Co3O4, leading to the creation of a novel hexagram-like structure with exceptional evenness in distribution. To comprehend the growth mechanism and elucidate the functions of various agents involved, experiments were conducted under diverse conditions with varying reagent ratios. The results indicate that, under the influence of NH4F as the structure-directing agent (SDA), the hexagram-shaped Co3O4 structure exhibits sensitivity to both reaction time and temperature, implying that its growth mechanism is regulated by the Kirkendall effect and involves partial cation exchange. Additionally, with alteration of reagent ratios, Co3O4 with ball-flower morphology was synthesized successfully. Through cross-section SEM examination, the observed growth mechanisms for both the hexagram and ball-flower structures were substantiated. Lastly, electrochemical performance tests of the hexagram and ball-flower structures on SC electrode were carried out, and specific capacitances were 452 C/g (1062 F/g) and 696 C/g (1339 F/g), respectively. The hexagram-shaped Co3O4 structure displays exceptional SC electrode material characteristics, retaining an outstanding capacitance of 93.1% even after 10,000 cycles, highlighting its superior cycle performance. This paper hopes to inspire further SC electrode materials studies based on its novel morphology modulation strategy. [ABSTRACT FROM AUTHOR] |
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| ISSN: | 20794991 |
| DOI: | 10.3390/nano16030162 |
