Nickel-Lanthanum Impregnated into Natural Zeolite as a Catalyst for Biofuel Production from Sunflower Oil via Hydrocracking Process.
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| Title: | Nickel-Lanthanum Impregnated into Natural Zeolite as a Catalyst for Biofuel Production from Sunflower Oil via Hydrocracking Process. |
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| Authors: | Santiko, Erik Budi1, Fauziah, Sarah2, Priyanto, Sugeng3, Yustinah, Y.2, Marlinda, Lenny4, Sudibyo, S.5, Aziz, Abdul6, Oktiarmi, Peri7, Yati, Indri1, Al Muttaqii, Muhammad1 muhammad.al.muttaqii@brin.go.id |
| Source: | Bulletin of Chemical Reaction Engineering & Catalysis. Apr2026, Vol. 21 Issue 1, p68-79. 12p. |
| Subjects: | Zeolite catalysts, Hydrocracking, Zeolites, Sunflower seed oil, Catalysis, Biomass energy, Hydrocarbon manufacturing |
| Abstract: | The increasing demand for crude oil or fossil fuel as a raw material for oil fuel has been steadily rising over time in line with the development that is taking place in Indonesia. However, biofuels are potential vegetable fuels that can be developed as alternative energy because they are renewable and can be renewed to overcome the energy crisis in the future. For this purpose, a double metal catalyst (impregnated with nickel and lanthanum), is used to make biofuels from sunflower seed oil. The effect of metal ratio on the yield of biofuel products is the concern in this study. The temperature of hydrocracking process was 250-330 - with ratio of metal 5% and 10% (metal ratio 1:1 and 1:2). X-ray diffraction (XRD) shows that natural zeolite has a clinoptilolite phase, X-Ray Fluorescence (XRF) shows that acid and base activation increases the Si/Al ratio from 4.5 to 5, Scanning Electron Microscope - Energy Dispersive X-Ray (SEMEDX) shows images of natural zeolite surfaces in the form of aggregate pieces, and Brunauer Emmett Teller (BET) shows that acid and base activation increases SBET from 29.96 to 49.73 m2/g and forms a hierarchical natural zeolite. The impregnation of Ni-La/Zeolite catalyst has been successfully carried out using the incipient wetness impregnation method and the best catalyst results were obtained, namely Ni-La/Zeolite 10% (1:2) with a surface area of 15.33 m2/gS. The addition of Nickel and Lanthanum metals caused a decrease in the surface area and average pore diameter of the zeolite. The lowest surface area and average pore diameter were found in the variation of the Ni-La/Zeolite 10% (1:2) catalyst, namely 15.33 m2/g and 13.99 nm. The highest hydrocarbon yield was found in the hydrocracking process with the Ni-La/Zeolite 10% (1:1) catalyst with gasoline, kerosene and gasoil fractions of 0.91; 0.39 and 8.32 (%wt), respectively. The hydrocarbon compound composition of the catalyst includes n-paraffin 4.43%, isoparaffin 0.21%, cycloparaffin 2.99% and olefin 2.71%. [ABSTRACT FROM AUTHOR] |
| Copyright of Bulletin of Chemical Reaction Engineering & Catalysis is the property of Universitas Diponegoro and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 191676952 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Nickel-Lanthanum Impregnated into Natural Zeolite as a Catalyst for Biofuel Production from Sunflower Oil via Hydrocracking Process. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Santiko%2C+Erik+Budi%22">Santiko, Erik Budi</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Fauziah%2C+Sarah%22">Fauziah, Sarah</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Priyanto%2C+Sugeng%22">Priyanto, Sugeng</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Yustinah%2C+Y%2E%22">Yustinah, Y.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Marlinda%2C+Lenny%22">Marlinda, Lenny</searchLink><relatesTo>4</relatesTo><br /><searchLink fieldCode="AR" term="%22Sudibyo%2C+S%2E%22">Sudibyo, S.</searchLink><relatesTo>5</relatesTo><br /><searchLink fieldCode="AR" term="%22Aziz%2C+Abdul%22">Aziz, Abdul</searchLink><relatesTo>6</relatesTo><br /><searchLink fieldCode="AR" term="%22Oktiarmi%2C+Peri%22">Oktiarmi, Peri</searchLink><relatesTo>7</relatesTo><br /><searchLink fieldCode="AR" term="%22Yati%2C+Indri%22">Yati, Indri</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Al+Muttaqii%2C+Muhammad%22">Al Muttaqii, Muhammad</searchLink><relatesTo>1</relatesTo><i> muhammad.al.muttaqii@brin.go.id</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Bulletin+of+Chemical+Reaction+Engineering+%26+Catalysis%22">Bulletin of Chemical Reaction Engineering & Catalysis</searchLink>. Apr2026, Vol. 21 Issue 1, p68-79. 12p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Zeolite+catalysts%22">Zeolite catalysts</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrocracking%22">Hydrocracking</searchLink><br /><searchLink fieldCode="DE" term="%22Zeolites%22">Zeolites</searchLink><br /><searchLink fieldCode="DE" term="%22Sunflower+seed+oil%22">Sunflower seed oil</searchLink><br /><searchLink fieldCode="DE" term="%22Catalysis%22">Catalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Biomass+energy%22">Biomass energy</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrocarbon+manufacturing%22">Hydrocarbon manufacturing</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: The increasing demand for crude oil or fossil fuel as a raw material for oil fuel has been steadily rising over time in line with the development that is taking place in Indonesia. However, biofuels are potential vegetable fuels that can be developed as alternative energy because they are renewable and can be renewed to overcome the energy crisis in the future. For this purpose, a double metal catalyst (impregnated with nickel and lanthanum), is used to make biofuels from sunflower seed oil. The effect of metal ratio on the yield of biofuel products is the concern in this study. The temperature of hydrocracking process was 250-330 - with ratio of metal 5% and 10% (metal ratio 1:1 and 1:2). X-ray diffraction (XRD) shows that natural zeolite has a clinoptilolite phase, X-Ray Fluorescence (XRF) shows that acid and base activation increases the Si/Al ratio from 4.5 to 5, Scanning Electron Microscope - Energy Dispersive X-Ray (SEMEDX) shows images of natural zeolite surfaces in the form of aggregate pieces, and Brunauer Emmett Teller (BET) shows that acid and base activation increases SBET from 29.96 to 49.73 m2/g and forms a hierarchical natural zeolite. The impregnation of Ni-La/Zeolite catalyst has been successfully carried out using the incipient wetness impregnation method and the best catalyst results were obtained, namely Ni-La/Zeolite 10% (1:2) with a surface area of 15.33 m2/gS. The addition of Nickel and Lanthanum metals caused a decrease in the surface area and average pore diameter of the zeolite. The lowest surface area and average pore diameter were found in the variation of the Ni-La/Zeolite 10% (1:2) catalyst, namely 15.33 m2/g and 13.99 nm. The highest hydrocarbon yield was found in the hydrocracking process with the Ni-La/Zeolite 10% (1:1) catalyst with gasoline, kerosene and gasoil fractions of 0.91; 0.39 and 8.32 (%wt), respectively. The hydrocarbon compound composition of the catalyst includes n-paraffin 4.43%, isoparaffin 0.21%, cycloparaffin 2.99% and olefin 2.71%. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Bulletin of Chemical Reaction Engineering & Catalysis is the property of Universitas Diponegoro and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.9767/bcrec.20503 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 12 StartPage: 68 Subjects: – SubjectFull: Zeolite catalysts Type: general – SubjectFull: Hydrocracking Type: general – SubjectFull: Zeolites Type: general – SubjectFull: Sunflower seed oil Type: general – SubjectFull: Catalysis Type: general – SubjectFull: Biomass energy Type: general – SubjectFull: Hydrocarbon manufacturing Type: general Titles: – TitleFull: Nickel-Lanthanum Impregnated into Natural Zeolite as a Catalyst for Biofuel Production from Sunflower Oil via Hydrocracking Process. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Santiko, Erik Budi – PersonEntity: Name: NameFull: Fauziah, Sarah – PersonEntity: Name: NameFull: Priyanto, Sugeng – PersonEntity: Name: NameFull: Yustinah, Y. – PersonEntity: Name: NameFull: Marlinda, Lenny – PersonEntity: Name: NameFull: Sudibyo, S. – PersonEntity: Name: NameFull: Aziz, Abdul – PersonEntity: Name: NameFull: Oktiarmi, Peri – PersonEntity: Name: NameFull: Yati, Indri – PersonEntity: Name: NameFull: Al Muttaqii, Muhammad IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 04 Text: Apr2026 Type: published Y: 2026 Identifiers: – Type: issn-print Value: 19782993 Numbering: – Type: volume Value: 21 – Type: issue Value: 1 Titles: – TitleFull: Bulletin of Chemical Reaction Engineering & Catalysis Type: main |
| ResultId | 1 |
