View in EDS

Synthesis and axial electropolymerization of novel amino-derived silicon phthalocyanine-based organic semiconductors.

Saved in:
Bibliographic Details
Title: Synthesis and axial electropolymerization of novel amino-derived silicon phthalocyanine-based organic semiconductors.
Authors: Cyr, Mélanie1,2 (AUTHOR), Magna, Gabriele3 (AUTHOR), Pizzoli, Francesco3 (AUTHOR), Mita, Alessandro3 (AUTHOR), Di Zazzo, Lorena3 (AUTHOR), Paolesse, Roberto3 (AUTHOR) roberto.paolesse@uniroma2.it, Lessard, Benoît H.2,4 (AUTHOR) benoit.lessard@uottawa.ca, Brusso, Jaclyn L.1 (AUTHOR) jbrusso@uottawa.ca
Source: Journal of Materials Science. Mar2026, Vol. 61 Issue 11, p7621-7632. 12p.
Subjects: Electropolymerization, Phthalocyanines, Spectrum analysis, Phenazine, Amino compounds, Semiconductor films, Organic semiconductors, Cyclic voltammetry
Abstract: Silicon phthalocyanines (SiPcs) are a class of molecules that have garnered large amounts of interest in the past decades, notably in the field of organic electronics. Their high level of conjugation allows them to promote charge transfer in an easy and efficient manner, in addition to holding high thermal and chemical stability. Herein, the synthesis of five novel amino-derived silicon phthalocyanines is reported, where the monomers are probed for in situ electropolymerization onto ITO conductive glass. Conductive films are obtained for the para- and ortho-bis(aminophenoxy) SiPc derivatives. The other three monomeric derivatives, however, did not yield any electropolymerized films. The polymerization is catalyzed by oxidation of the amino groups, introducing a phenazine bridge between the axial positions of the SiPcs. The electropolymerization is performed using cyclic voltammetry and further investigated through optical and spectroelectronic spectroscopy. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 191838979
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Synthesis and axial electropolymerization of novel amino-derived silicon phthalocyanine-based organic semiconductors.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Cyr%2C+Mélanie%22">Cyr, Mélanie</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Magna%2C+Gabriele%22">Magna, Gabriele</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Pizzoli%2C+Francesco%22">Pizzoli, Francesco</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Mita%2C+Alessandro%22">Mita, Alessandro</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Di+Zazzo%2C+Lorena%22">Di Zazzo, Lorena</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Paolesse%2C+Roberto%22">Paolesse, Roberto</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> roberto.paolesse@uniroma2.it</i><br /><searchLink fieldCode="AR" term="%22Lessard%2C+Benoît+H%2E%22">Lessard, Benoît H.</searchLink><relatesTo>2,4</relatesTo> (AUTHOR)<i> benoit.lessard@uottawa.ca</i><br /><searchLink fieldCode="AR" term="%22Brusso%2C+Jaclyn+L%2E%22">Brusso, Jaclyn L.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> jbrusso@uottawa.ca</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Journal+of+Materials+Science%22">Journal of Materials Science</searchLink>. Mar2026, Vol. 61 Issue 11, p7621-7632. 12p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Electropolymerization%22">Electropolymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Phthalocyanines%22">Phthalocyanines</searchLink><br /><searchLink fieldCode="DE" term="%22Spectrum+analysis%22">Spectrum analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Phenazine%22">Phenazine</searchLink><br /><searchLink fieldCode="DE" term="%22Amino+compounds%22">Amino compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Semiconductor+films%22">Semiconductor films</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+semiconductors%22">Organic semiconductors</searchLink><br /><searchLink fieldCode="DE" term="%22Cyclic+voltammetry%22">Cyclic voltammetry</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Silicon phthalocyanines (SiPcs) are a class of molecules that have garnered large amounts of interest in the past decades, notably in the field of organic electronics. Their high level of conjugation allows them to promote charge transfer in an easy and efficient manner, in addition to holding high thermal and chemical stability. Herein, the synthesis of five novel amino-derived silicon phthalocyanines is reported, where the monomers are probed for in situ electropolymerization onto ITO conductive glass. Conductive films are obtained for the para- and ortho-bis(aminophenoxy) SiPc derivatives. The other three monomeric derivatives, however, did not yield any electropolymerized films. The polymerization is catalyzed by oxidation of the amino groups, introducing a phenazine bridge between the axial positions of the SiPcs. The electropolymerization is performed using cyclic voltammetry and further investigated through optical and spectroelectronic spectroscopy. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=191838979
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1007/s10853-026-12263-4
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 12
        StartPage: 7621
    Subjects:
      – SubjectFull: Electropolymerization
        Type: general
      – SubjectFull: Phthalocyanines
        Type: general
      – SubjectFull: Spectrum analysis
        Type: general
      – SubjectFull: Phenazine
        Type: general
      – SubjectFull: Amino compounds
        Type: general
      – SubjectFull: Semiconductor films
        Type: general
      – SubjectFull: Organic semiconductors
        Type: general
      – SubjectFull: Cyclic voltammetry
        Type: general
    Titles:
      – TitleFull: Synthesis and axial electropolymerization of novel amino-derived silicon phthalocyanine-based organic semiconductors.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Cyr, Mélanie
      – PersonEntity:
          Name:
            NameFull: Magna, Gabriele
      – PersonEntity:
          Name:
            NameFull: Pizzoli, Francesco
      – PersonEntity:
          Name:
            NameFull: Mita, Alessandro
      – PersonEntity:
          Name:
            NameFull: Di Zazzo, Lorena
      – PersonEntity:
          Name:
            NameFull: Paolesse, Roberto
      – PersonEntity:
          Name:
            NameFull: Lessard, Benoît H.
      – PersonEntity:
          Name:
            NameFull: Brusso, Jaclyn L.
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 15
              M: 03
              Text: Mar2026
              Type: published
              Y: 2026
          Identifiers:
            – Type: issn-print
              Value: 00222461
          Numbering:
            – Type: volume
              Value: 61
            – Type: issue
              Value: 11
          Titles:
            – TitleFull: Journal of Materials Science
              Type: main
ResultId 1