Dual-Emission Ratiometric Fluorescent Probe Based on UiO-66-NH2@CQDs for Quantitative Detection of Acetophenone.

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Title: Dual-Emission Ratiometric Fluorescent Probe Based on UiO-66-NH2@CQDs for Quantitative Detection of Acetophenone.
Authors: Shou, Yongze1 (AUTHOR), Xu, Zhouqing1 (AUTHOR) zhqxu@hpu.edu.cn, Li, Huijun1 (AUTHOR) lihuijunxgy@hpu.edu.cn, Liu, Wenjie1 (AUTHOR), Wang, Junkun1 (AUTHOR)
Source: Journal of Fluorescence. Jan2026, Vol. 36 Issue 1, p583-593. 11p.
Subjects: Acetophenone, Fluorescent probes, Environmental monitoring, Carbon nanodots, Metal-organic frameworks, Industrial wastes
Abstract: The pressing necessity to devise a fluorescent probe capable of identifying volatile organic compounds such as acetophenone (AP). This groundbreaking advancement plays a crucial role in preserving environmental health and ensuring public health. In this work, we synthesized a ratiometric UiO-66-NH2@CQDs sensor through post-synthetic modification by anchoring carbon quantum dots onto UiO-66-NH2 metal-organic framework, which could be readily utilized as self-calibrating nanoprobe for selective detection of AP over other potential interferants. Upon the addition of AP, UiO-66-NH2@CQDs featured a decreased emission at 430 nm and an enhanced emission at 550 nm, accompanied by a characteristic fluorescence color transition from blue-green to yellow. By adopting the ration of I430nm/I550nm as the detection signal, UiO-66-NH2@CQDs could distinguish AP with excellent performance. The limit of detection for AP was estimated to be 175.6 nM, which was a significant value. Additionally, we demonstrated that on-site visual inspection of AP in industrial wastewater using a paper-based UiO-66-NH2@CQDs analysis device. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Fluorescence is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Dual-Emission Ratiometric Fluorescent Probe Based on UiO-66-NH<subscript>2</subscript>@CQDs for Quantitative Detection of Acetophenone.
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  Data: <searchLink fieldCode="AR" term="%22Shou%2C+Yongze%22">Shou, Yongze</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xu%2C+Zhouqing%22">Xu, Zhouqing</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> zhqxu@hpu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Li%2C+Huijun%22">Li, Huijun</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> lihuijunxgy@hpu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Liu%2C+Wenjie%22">Liu, Wenjie</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Junkun%22">Wang, Junkun</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="DE" term="%22Acetophenone%22">Acetophenone</searchLink><br /><searchLink fieldCode="DE" term="%22Fluorescent+probes%22">Fluorescent probes</searchLink><br /><searchLink fieldCode="DE" term="%22Environmental+monitoring%22">Environmental monitoring</searchLink><br /><searchLink fieldCode="DE" term="%22Carbon+nanodots%22">Carbon nanodots</searchLink><br /><searchLink fieldCode="DE" term="%22Metal-organic+frameworks%22">Metal-organic frameworks</searchLink><br /><searchLink fieldCode="DE" term="%22Industrial+wastes%22">Industrial wastes</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: The pressing necessity to devise a fluorescent probe capable of identifying volatile organic compounds such as acetophenone (AP). This groundbreaking advancement plays a crucial role in preserving environmental health and ensuring public health. In this work, we synthesized a ratiometric UiO-66-NH2@CQDs sensor through post-synthetic modification by anchoring carbon quantum dots onto UiO-66-NH2 metal-organic framework, which could be readily utilized as self-calibrating nanoprobe for selective detection of AP over other potential interferants. Upon the addition of AP, UiO-66-NH2@CQDs featured a decreased emission at 430 nm and an enhanced emission at 550 nm, accompanied by a characteristic fluorescence color transition from blue-green to yellow. By adopting the ration of I430nm/I550nm as the detection signal, UiO-66-NH2@CQDs could distinguish AP with excellent performance. The limit of detection for AP was estimated to be 175.6 nM, which was a significant value. Additionally, we demonstrated that on-site visual inspection of AP in industrial wastewater using a paper-based UiO-66-NH2@CQDs analysis device. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Journal of Fluorescence is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1007/s10895-025-04596-1
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      – Code: eng
        Text: English
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        PageCount: 11
        StartPage: 583
    Subjects:
      – SubjectFull: Acetophenone
        Type: general
      – SubjectFull: Fluorescent probes
        Type: general
      – SubjectFull: Environmental monitoring
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      – SubjectFull: Carbon nanodots
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      – SubjectFull: Metal-organic frameworks
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      – SubjectFull: Industrial wastes
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      – TitleFull: Dual-Emission Ratiometric Fluorescent Probe Based on UiO-66-NH2@CQDs for Quantitative Detection of Acetophenone.
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            NameFull: Shou, Yongze
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            NameFull: Xu, Zhouqing
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            NameFull: Li, Huijun
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            NameFull: Liu, Wenjie
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            NameFull: Wang, Junkun
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            – D: 01
              M: 01
              Text: Jan2026
              Type: published
              Y: 2026
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