Geochemistry of the Upper Jurassic–Lower Cretaceous limestone of the Bilecik Formation in the Dümrek area (Eskişehir, western Central Anatolia): implications for depositional environment and paleotemperature.

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Title: Geochemistry of the Upper Jurassic–Lower Cretaceous limestone of the Bilecik Formation in the Dümrek area (Eskişehir, western Central Anatolia): implications for depositional environment and paleotemperature.
Authors: KAHYA, Asuman1 asuman27@gmail.com, BAĞCI, Metin2
Source: Turkish Journal of Earth Sciences. 2026, Vol. 35 Issue 2, p108-128. 21p.
Subjects: Limestone, Geochemistry, Sedimentation & deposition, Cretaceous Period, Temperature, Jurassic Period
Geographic Terms: Eskisehir (Turkey), Turkey
Abstract: Upper Jurassic–Lower Cretaceous limestones of the Bilecik Formation are exposed near the village of Dümrek (Eskişehir Province) within the Sakarya Zone. Mineralogical analyses reveal that these limestones are predominantly composed of calcite and include intraclasts, fossil shell fragments, ooids, and peloids, cemented by sparry and micritic calcite. The U/Th, Ni/Co, V/(V+Ni), V/ Cr, and Ce/Ce* ratios indicate that these carbonates were deposited in an oxic environment. Furthermore, the Mn/Sr ratios imply no diagenetic alteration, indicating preservation of the original geochemical signature. The PAAS-normalized REE+Y patterns of these limestones display depletion in light rare earth elements, a pronounced positive La anomaly (La/La* = 2.13–6.2), a distinct negative Ce anomaly (Ce/Ce* = 0.18–1.76), a slight positive Eu anomaly (Eu/Eu* = 1–1.41), and an enrichment in Y, all pointing to a well-oxygenated depositional environment with negligible detrital input. Stable isotope data show that the average δ13C (V-PDB) value is 2.47‰, while the average δ18O (V-PDB) value is –2.10‰. The δ18O values display slight alteration with negative values, which are interpreted as evidence of early marine diagenesis. Based on these oxygen isotope values, the estimated paleotemperature during carbonate precipitation was approximately 26.15 °C. The calculated paleosalinity index (Z) of 131.40, obtained using the average δ18O and δ13C values, corroborates a marine origin for the carbonates. Furthermore, the paleoclimate proxy ratio ∑(Fe + Mn + Cr + Ni + V + Co)/∑(Ca + Mg + Sr + Ba + K + Na) ranges between 0.087 and 0.09, indicative of an arid climate during limestone formation. The δ13C (V-PDB) ‰ versus δ18O (V-PDB) ‰ bivariate diagram confirms the marine character of the limestone. [ABSTRACT FROM AUTHOR]
Copyright of Turkish Journal of Earth Sciences is the property of Scientific and Technical Research Council of Turkey and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Geochemistry of the Upper Jurassic–Lower Cretaceous limestone of the Bilecik Formation in the Dümrek area (Eskişehir, western Central Anatolia): implications for depositional environment and paleotemperature.
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  Data: <searchLink fieldCode="AR" term="%22KAHYA%2C+Asuman%22">KAHYA, Asuman</searchLink><relatesTo>1</relatesTo><i> asuman27@gmail.com</i><br /><searchLink fieldCode="AR" term="%22BAĞCI%2C+Metin%22">BAĞCI, Metin</searchLink><relatesTo>2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Turkish+Journal+of+Earth+Sciences%22">Turkish Journal of Earth Sciences</searchLink>. 2026, Vol. 35 Issue 2, p108-128. 21p.
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  Data: <searchLink fieldCode="DE" term="%22Limestone%22">Limestone</searchLink><br /><searchLink fieldCode="DE" term="%22Geochemistry%22">Geochemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Sedimentation+%26+deposition%22">Sedimentation & deposition</searchLink><br /><searchLink fieldCode="DE" term="%22Cretaceous+Period%22">Cretaceous Period</searchLink><br /><searchLink fieldCode="DE" term="%22Temperature%22">Temperature</searchLink><br /><searchLink fieldCode="DE" term="%22Jurassic+Period%22">Jurassic Period</searchLink>
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  Data: <searchLink fieldCode="DE" term="%22Eskisehir+%28Turkey%29%22">Eskisehir (Turkey)</searchLink><br /><searchLink fieldCode="DE" term="%22Turkey%22">Turkey</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Upper Jurassic–Lower Cretaceous limestones of the Bilecik Formation are exposed near the village of Dümrek (Eskişehir Province) within the Sakarya Zone. Mineralogical analyses reveal that these limestones are predominantly composed of calcite and include intraclasts, fossil shell fragments, ooids, and peloids, cemented by sparry and micritic calcite. The U/Th, Ni/Co, V/(V+Ni), V/ Cr, and Ce/Ce* ratios indicate that these carbonates were deposited in an oxic environment. Furthermore, the Mn/Sr ratios imply no diagenetic alteration, indicating preservation of the original geochemical signature. The PAAS-normalized REE+Y patterns of these limestones display depletion in light rare earth elements, a pronounced positive La anomaly (La/La* = 2.13–6.2), a distinct negative Ce anomaly (Ce/Ce* = 0.18–1.76), a slight positive Eu anomaly (Eu/Eu* = 1–1.41), and an enrichment in Y, all pointing to a well-oxygenated depositional environment with negligible detrital input. Stable isotope data show that the average δ13C (V-PDB) value is 2.47‰, while the average δ18O (V-PDB) value is –2.10‰. The δ18O values display slight alteration with negative values, which are interpreted as evidence of early marine diagenesis. Based on these oxygen isotope values, the estimated paleotemperature during carbonate precipitation was approximately 26.15 °C. The calculated paleosalinity index (Z) of 131.40, obtained using the average δ18O and δ13C values, corroborates a marine origin for the carbonates. Furthermore, the paleoclimate proxy ratio ∑(Fe + Mn + Cr + Ni + V + Co)/∑(Ca + Mg + Sr + Ba + K + Na) ranges between 0.087 and 0.09, indicative of an arid climate during limestone formation. The δ13C (V-PDB) ‰ versus δ18O (V-PDB) ‰ bivariate diagram confirms the marine character of the limestone. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Turkish Journal of Earth Sciences is the property of Scientific and Technical Research Council of Turkey and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.55730/1300-0985.2009
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      – Code: eng
        Text: English
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        PageCount: 21
        StartPage: 108
    Subjects:
      – SubjectFull: Limestone
        Type: general
      – SubjectFull: Geochemistry
        Type: general
      – SubjectFull: Sedimentation & deposition
        Type: general
      – SubjectFull: Cretaceous Period
        Type: general
      – SubjectFull: Temperature
        Type: general
      – SubjectFull: Jurassic Period
        Type: general
      – SubjectFull: Eskisehir (Turkey)
        Type: general
      – SubjectFull: Turkey
        Type: general
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      – TitleFull: Geochemistry of the Upper Jurassic–Lower Cretaceous limestone of the Bilecik Formation in the Dümrek area (Eskişehir, western Central Anatolia): implications for depositional environment and paleotemperature.
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            NameFull: KAHYA, Asuman
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            NameFull: BAĞCI, Metin
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              Text: 2026
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              Y: 2026
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