Measurement and Analysis of Overlapping Ammonia Spectral Lines via Dual‐Comb Spectroscopy.

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Title: Measurement and Analysis of Overlapping Ammonia Spectral Lines via Dual‐Comb Spectroscopy.
Authors: Rong, Shuangquan1 (AUTHOR), Sun, Xiaocong1,2 (AUTHOR) sunxiaocong@tyust.edu.cn, Zhou, Yueting2 (AUTHOR), Gong, Ting2 (AUTHOR), Tian, Yali2 (AUTHOR), Qiu, Xuanbing2 (AUTHOR), Li, Chuanliang1,2 (AUTHOR) clli@tyust.edu.cn
Source: Microwave & Optical Technology Letters. Mar2026, Vol. 68 Issue 3, p1-6. 6p.
Subjects: Spectral lines, Atmospheric ammonia, Light absorption, Measurement, Spectrometry, Near infrared spectroscopy, Detection limit
Abstract: Ammonia (NH₃) emissions pose significant hazards to both the environment and human health, making high‐precision monitoring of ambient NH₃ concentrations particularly crucial. In this study, a high‐precision NH₃ detection system was designed based on near‐infrared dual‐comb spectroscopy (DCS). A laser source with a central wavelength of 1531 nm is employed as the laser relay; by locking the relative frequencies of two optical combs to the relay laser separately, dual‐comb with a central frequency of 1531 nm, a repetition rate of 518.25 Hz, and an output power of 30 μW is generated. A multi‐pass gas absorption cell with a base length of 0.113 m and 250 reflections is utilized to achieve an effective optical path length of approximately 25 m. Under conditions of 296.15 K and 1 atm, three overlapping absorption lines at 6528.78 cm⁻¹, 6528.88 cm⁻¹, and 6529.18 cm⁻¹ of 1000 ppm NH₃ are detected, verifying the feasibility of high‐resolution dual‐comb spectroscopy for measuring overlapping spectral lines. Allan variance analysis is performed on the experimental data, yielding a minimum detection limit (MDL) of 0.00128 for absorbance at an integration time of 972 s, corresponding to a concentration MDL of ~2 ppm. This research provides technical insights for achieving high‐precision measurement and analysis of overlapping spectral lines. [ABSTRACT FROM AUTHOR]
Copyright of Microwave & Optical Technology Letters is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Measurement and Analysis of Overlapping Ammonia Spectral Lines via Dual‐Comb Spectroscopy.
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  Data: <searchLink fieldCode="AR" term="%22Rong%2C+Shuangquan%22">Rong, Shuangquan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sun%2C+Xiaocong%22">Sun, Xiaocong</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> sunxiaocong@tyust.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Zhou%2C+Yueting%22">Zhou, Yueting</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Gong%2C+Ting%22">Gong, Ting</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Tian%2C+Yali%22">Tian, Yali</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Qiu%2C+Xuanbing%22">Qiu, Xuanbing</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Li%2C+Chuanliang%22">Li, Chuanliang</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> clli@tyust.edu.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Microwave+%26+Optical+Technology+Letters%22">Microwave & Optical Technology Letters</searchLink>. Mar2026, Vol. 68 Issue 3, p1-6. 6p.
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  Data: <searchLink fieldCode="DE" term="%22Spectral+lines%22">Spectral lines</searchLink><br /><searchLink fieldCode="DE" term="%22Atmospheric+ammonia%22">Atmospheric ammonia</searchLink><br /><searchLink fieldCode="DE" term="%22Light+absorption%22">Light absorption</searchLink><br /><searchLink fieldCode="DE" term="%22Measurement%22">Measurement</searchLink><br /><searchLink fieldCode="DE" term="%22Spectrometry%22">Spectrometry</searchLink><br /><searchLink fieldCode="DE" term="%22Near+infrared+spectroscopy%22">Near infrared spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Detection+limit%22">Detection limit</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Ammonia (NH₃) emissions pose significant hazards to both the environment and human health, making high‐precision monitoring of ambient NH₃ concentrations particularly crucial. In this study, a high‐precision NH₃ detection system was designed based on near‐infrared dual‐comb spectroscopy (DCS). A laser source with a central wavelength of 1531 nm is employed as the laser relay; by locking the relative frequencies of two optical combs to the relay laser separately, dual‐comb with a central frequency of 1531 nm, a repetition rate of 518.25 Hz, and an output power of 30 μW is generated. A multi‐pass gas absorption cell with a base length of 0.113 m and 250 reflections is utilized to achieve an effective optical path length of approximately 25 m. Under conditions of 296.15 K and 1 atm, three overlapping absorption lines at 6528.78 cm⁻¹, 6528.88 cm⁻¹, and 6529.18 cm⁻¹ of 1000 ppm NH₃ are detected, verifying the feasibility of high‐resolution dual‐comb spectroscopy for measuring overlapping spectral lines. Allan variance analysis is performed on the experimental data, yielding a minimum detection limit (MDL) of 0.00128 for absorbance at an integration time of 972 s, corresponding to a concentration MDL of ~2 ppm. This research provides technical insights for achieving high‐precision measurement and analysis of overlapping spectral lines. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Microwave & Optical Technology Letters is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1002/mop.70519
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      – Code: eng
        Text: English
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        PageCount: 6
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    Subjects:
      – SubjectFull: Spectral lines
        Type: general
      – SubjectFull: Atmospheric ammonia
        Type: general
      – SubjectFull: Light absorption
        Type: general
      – SubjectFull: Measurement
        Type: general
      – SubjectFull: Spectrometry
        Type: general
      – SubjectFull: Near infrared spectroscopy
        Type: general
      – SubjectFull: Detection limit
        Type: general
    Titles:
      – TitleFull: Measurement and Analysis of Overlapping Ammonia Spectral Lines via Dual‐Comb Spectroscopy.
        Type: main
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          Name:
            NameFull: Rong, Shuangquan
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            NameFull: Sun, Xiaocong
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            NameFull: Zhou, Yueting
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            NameFull: Gong, Ting
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            NameFull: Tian, Yali
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            NameFull: Qiu, Xuanbing
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            NameFull: Li, Chuanliang
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            – D: 01
              M: 03
              Text: Mar2026
              Type: published
              Y: 2026
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              Value: 68
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            – TitleFull: Microwave & Optical Technology Letters
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