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Construction of MOF-on-COF with multifunctional sites for efficient capture and sequestration of radioactive iodine in high-humidity environments.

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Title: Construction of MOF-on-COF with multifunctional sites for efficient capture and sequestration of radioactive iodine in high-humidity environments.
Authors: Feng, Aiguo1 (AUTHOR), Yang, Libo1 (AUTHOR), Zhong, Chengsong1 (AUTHOR), Chen, Bihong1 (AUTHOR), Chen, Hao1 (AUTHOR), Wu, Jinyu1 (AUTHOR), Yin, Xiangbiao1,2 (AUTHOR) yinxb@usc.edu.cn, Wang, Xinpeng1,3 (AUTHOR) wangxinpeng@gxu.edu.cn
Source: Journal of Hazardous Materials. May2026, Vol. 508, pN.PAG-N.PAG. 1p.
Subjects: Iodine, Metal-organic frameworks, Adsorption capacity, Iodine isotopes, Physisorption
Abstract: Radioactive iodine has garnered extensive attention due to its severe hazards to human health and the environment. However, the ubiquitous presence of water vapor during iodine vapor capture significantly impairs the adsorption performance. This often leads to reduced activity or even deactivation of adsorbents. To achieve efficient iodine capture and stable immobilization under high-humidity conditions, this study constructed an environmentally friendly MOF-on-COF architecture (Tp-UiO) with multifunctional sites and a three-dimensional framework using the in-situ growth of a metal-organic framework (UiO-66-NH 2) on a three-dimensional scaffold of a covalent organic framework (Tp-Azo). Among the samples, the 200Tp-UiO sample exhibited a saturation adsorption capacity of 2585 mg/g under dry static adsorption conditions. This result represented a 261.5% and 55.1% improvement compared to UiO-66-NH 2 and Tp-Azo, respectively. The saturation adsorption capacity reached 2004 mg/g at a relative humidity of 74%, exceeding that of most reported adsorbents. Moreover, after iodine uptake and 7 days of storage, the iodine retention rate remained greater than 95%. A series of detailed characterizations confirmed that the excellent adsorption performance was attributed to the construction of the unique pore structure and the synergistic interactions among multiple functional sites (N − H, N = N, C O, and Zr−O groups). This study elucidated the feasibility of the MOF-on-COF composite structures for radioactive iodine adsorption in high-humidity environments and offered a novel perspective for the field of radioactive iodine capture. [Display omitted] • A MOF-on-COF material bearing multiple functional adsorption sites was synthesized. • The adsorbent's iodine adsorption capacity was 2585 mg/g under dry conditions. • The adsorbent's iodine adsorption capacity was 2004 mg/g at 74% R.H. • The N–H, C O, N = N and Zr–O sites played a crucial role in iodine adsorption. • DFT calculations elucidated the iodine adsorption mechanism of the materials. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Hazardous Materials is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 192926247
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Label: Title
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  Data: Construction of MOF-on-COF with multifunctional sites for efficient capture and sequestration of radioactive iodine in high-humidity environments.
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  Data: <searchLink fieldCode="AR" term="%22Feng%2C+Aiguo%22">Feng, Aiguo</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yang%2C+Libo%22">Yang, Libo</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhong%2C+Chengsong%22">Zhong, Chengsong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Chen%2C+Bihong%22">Chen, Bihong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Chen%2C+Hao%22">Chen, Hao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wu%2C+Jinyu%22">Wu, Jinyu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yin%2C+Xiangbiao%22">Yin, Xiangbiao</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> yinxb@usc.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Wang%2C+Xinpeng%22">Wang, Xinpeng</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<i> wangxinpeng@gxu.edu.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Hazardous+Materials%22">Journal of Hazardous Materials</searchLink>. May2026, Vol. 508, pN.PAG-N.PAG. 1p.
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  Data: <searchLink fieldCode="DE" term="%22Iodine%22">Iodine</searchLink><br /><searchLink fieldCode="DE" term="%22Metal-organic+frameworks%22">Metal-organic frameworks</searchLink><br /><searchLink fieldCode="DE" term="%22Adsorption+capacity%22">Adsorption capacity</searchLink><br /><searchLink fieldCode="DE" term="%22Iodine+isotopes%22">Iodine isotopes</searchLink><br /><searchLink fieldCode="DE" term="%22Physisorption%22">Physisorption</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Radioactive iodine has garnered extensive attention due to its severe hazards to human health and the environment. However, the ubiquitous presence of water vapor during iodine vapor capture significantly impairs the adsorption performance. This often leads to reduced activity or even deactivation of adsorbents. To achieve efficient iodine capture and stable immobilization under high-humidity conditions, this study constructed an environmentally friendly MOF-on-COF architecture (Tp-UiO) with multifunctional sites and a three-dimensional framework using the in-situ growth of a metal-organic framework (UiO-66-NH 2) on a three-dimensional scaffold of a covalent organic framework (Tp-Azo). Among the samples, the 200Tp-UiO sample exhibited a saturation adsorption capacity of 2585 mg/g under dry static adsorption conditions. This result represented a 261.5% and 55.1% improvement compared to UiO-66-NH 2 and Tp-Azo, respectively. The saturation adsorption capacity reached 2004 mg/g at a relative humidity of 74%, exceeding that of most reported adsorbents. Moreover, after iodine uptake and 7 days of storage, the iodine retention rate remained greater than 95%. A series of detailed characterizations confirmed that the excellent adsorption performance was attributed to the construction of the unique pore structure and the synergistic interactions among multiple functional sites (N − H, N = N, C O, and Zr−O groups). This study elucidated the feasibility of the MOF-on-COF composite structures for radioactive iodine adsorption in high-humidity environments and offered a novel perspective for the field of radioactive iodine capture. [Display omitted] • A MOF-on-COF material bearing multiple functional adsorption sites was synthesized. • The adsorbent's iodine adsorption capacity was 2585 mg/g under dry conditions. • The adsorbent's iodine adsorption capacity was 2004 mg/g at 74% R.H. • The N–H, C O, N = N and Zr–O sites played a crucial role in iodine adsorption. • DFT calculations elucidated the iodine adsorption mechanism of the materials. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Hazardous Materials is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.jhazmat.2026.141904
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Iodine
        Type: general
      – SubjectFull: Metal-organic frameworks
        Type: general
      – SubjectFull: Adsorption capacity
        Type: general
      – SubjectFull: Iodine isotopes
        Type: general
      – SubjectFull: Physisorption
        Type: general
    Titles:
      – TitleFull: Construction of MOF-on-COF with multifunctional sites for efficient capture and sequestration of radioactive iodine in high-humidity environments.
        Type: main
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          Name:
            NameFull: Feng, Aiguo
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            NameFull: Yang, Libo
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            NameFull: Zhong, Chengsong
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            NameFull: Chen, Bihong
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            NameFull: Chen, Hao
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            NameFull: Wu, Jinyu
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            NameFull: Yin, Xiangbiao
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            NameFull: Wang, Xinpeng
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          Dates:
            – D: 01
              M: 05
              Text: May2026
              Type: published
              Y: 2026
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            – Type: issn-print
              Value: 03043894
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              Value: 508
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            – TitleFull: Journal of Hazardous Materials
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