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Design and construction of metal-organic frameworks for proton conductivity through the synergistic effect of dual groups.

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Title: Design and construction of metal-organic frameworks for proton conductivity through the synergistic effect of dual groups.
Authors: Guo, Xin-Ling1 (AUTHOR), Zhang, Wei1 (AUTHOR), Liu, Jing-Rui1 (AUTHOR), Shi, Xin-Qing1 (AUTHOR), Cui, Ru-Ping1 (AUTHOR), Zhang, Wen-Qian1 (AUTHOR) zwenqian@yeah.net, Bai, Xiang-Ru1 (AUTHOR)
Source: Journal of Solid State Chemistry. Jul2026, Vol. 359, pN.PAG-N.PAG. 1p.
Subjects: Proton conductivity, Ligands (Chemistry), Proton transfer reactions, Humidity, Metal-organic frameworks, Hydrogen bonding, Temperature effect
Abstract: Constructing metal-organic frameworks (MOFs) with high proton conductivity is a challenging task. This work constructed a novel MOF (Ag-BDSA) with excellent proton conductivity by selecting functional ligands. Ag-BDSA demonstrated excellent stability. The functional groups on the ligand formed numerous hydrogen bond interactions with water molecules, enabling rapid and efficient proton transfer. Its proton conductivity is dependent on temperature and humidity. And under the conditions of 98% RH and 90 °C, it exhibited the best proton conduction properties (0.94 × 10−2 S∙cm−1). The mechanism study indicated that it conformed to the Vehicle mechanism. This work had demonstrated the reliability and simplicity of functional ligands in the construction of MOFs with proton-conducting properties, and it was expected to be applied in the design of various functional MOFs. [Display omitted] • The best proton conduction property was 0.94 × 10−2 S∙cm−1. • Functionalized ligands enable the simple construction of MOFs. • Abundant proton acceptors and proton donors. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Solid State Chemistry is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 192928574
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Label: Title
  Group: Ti
  Data: Design and construction of metal-organic frameworks for proton conductivity through the synergistic effect of dual groups.
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  Data: <searchLink fieldCode="AR" term="%22Guo%2C+Xin-Ling%22">Guo, Xin-Ling</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Wei%22">Zhang, Wei</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Liu%2C+Jing-Rui%22">Liu, Jing-Rui</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Shi%2C+Xin-Qing%22">Shi, Xin-Qing</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Cui%2C+Ru-Ping%22">Cui, Ru-Ping</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Wen-Qian%22">Zhang, Wen-Qian</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> zwenqian@yeah.net</i><br /><searchLink fieldCode="AR" term="%22Bai%2C+Xiang-Ru%22">Bai, Xiang-Ru</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Solid+State+Chemistry%22">Journal of Solid State Chemistry</searchLink>. Jul2026, Vol. 359, pN.PAG-N.PAG. 1p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Proton+conductivity%22">Proton conductivity</searchLink><br /><searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Proton+transfer+reactions%22">Proton transfer reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Humidity%22">Humidity</searchLink><br /><searchLink fieldCode="DE" term="%22Metal-organic+frameworks%22">Metal-organic frameworks</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen+bonding%22">Hydrogen bonding</searchLink><br /><searchLink fieldCode="DE" term="%22Temperature+effect%22">Temperature effect</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Constructing metal-organic frameworks (MOFs) with high proton conductivity is a challenging task. This work constructed a novel MOF (Ag-BDSA) with excellent proton conductivity by selecting functional ligands. Ag-BDSA demonstrated excellent stability. The functional groups on the ligand formed numerous hydrogen bond interactions with water molecules, enabling rapid and efficient proton transfer. Its proton conductivity is dependent on temperature and humidity. And under the conditions of 98% RH and 90 °C, it exhibited the best proton conduction properties (0.94 × 10−2 S∙cm−1). The mechanism study indicated that it conformed to the Vehicle mechanism. This work had demonstrated the reliability and simplicity of functional ligands in the construction of MOFs with proton-conducting properties, and it was expected to be applied in the design of various functional MOFs. [Display omitted] • The best proton conduction property was 0.94 × 10−2 S∙cm−1. • Functionalized ligands enable the simple construction of MOFs. • Abundant proton acceptors and proton donors. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Solid State Chemistry is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.jssc.2026.125974
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Proton conductivity
        Type: general
      – SubjectFull: Ligands (Chemistry)
        Type: general
      – SubjectFull: Proton transfer reactions
        Type: general
      – SubjectFull: Humidity
        Type: general
      – SubjectFull: Metal-organic frameworks
        Type: general
      – SubjectFull: Hydrogen bonding
        Type: general
      – SubjectFull: Temperature effect
        Type: general
    Titles:
      – TitleFull: Design and construction of metal-organic frameworks for proton conductivity through the synergistic effect of dual groups.
        Type: main
  BibRelationships:
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      – PersonEntity:
          Name:
            NameFull: Guo, Xin-Ling
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          Name:
            NameFull: Zhang, Wei
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            NameFull: Liu, Jing-Rui
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            NameFull: Shi, Xin-Qing
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            NameFull: Cui, Ru-Ping
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            NameFull: Zhang, Wen-Qian
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            NameFull: Bai, Xiang-Ru
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          Dates:
            – D: 01
              M: 07
              Text: Jul2026
              Type: published
              Y: 2026
          Identifiers:
            – Type: issn-print
              Value: 00224596
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            – Type: volume
              Value: 359
          Titles:
            – TitleFull: Journal of Solid State Chemistry
              Type: main
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