Defect‐Anchored Carbon Nanotubes With Tailored Electronic Structure as a Single Platform for Thermal Energy Storage, Li‐Ion Battery Anodes, and Thermoelectric Conversion.

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Title: Defect‐Anchored Carbon Nanotubes With Tailored Electronic Structure as a Single Platform for Thermal Energy Storage, Li‐Ion Battery Anodes, and Thermoelectric Conversion.
Authors: Mehdi, Syed Muhammad Zain1 (AUTHOR), Faizan, Muhammad2 (AUTHOR), Mohan, Man3,4 (AUTHOR), Shridharan, Tatachari Santhanagopalan3,5 (AUTHOR), Awasthi, Abhishek6 (AUTHOR), Youn, Gyosik5 (AUTHOR), Cho, In Sun3,5,7 (AUTHOR), Nam, Kyung-Wan8 (AUTHOR), Lee, Naesung1 (AUTHOR) nslee@sejong.ac.kr, Ahn, Byungmin3,5,7 (AUTHOR) byungmin@ajou.ac.kr, Parale, Vinayak (AUTHOR) vinayak@yonsei.ac.kr
Source: International Journal of Energy Research. 4/24/2026, Vol. 2026, p1-25. 25p.
Subjects: Carbon nanotubes, Boron, Energy storage, Lithium-ion batteries, Nanostructured materials, Thermoelectric conversion, Photothermal conversion, Heat storage
Abstract: Heteroatom doping offers a unified and energy‐efficient strategy to tailor the electronic structure of carbon nanotubes (CNTs) for multifunctional energy applications. In this study, boron‐doped CNTs (B‐CNTs) synthesized via a single‐step arc discharge method are evaluated across four domains: thermal energy storage, photothermal conversion, lithium‐ion batteries, and thermoelectric generation. The present study benefits from p‐type defect formation in CNT, which includes a work function increase and a shifted Fermi level. In thermal energy storage, a paraffin/B‐CNT composite demonstrated superior thermal conductivity (0.303 W/m·K), latent heat capacity (144.7 J/g), and crystallinity (51.9%) due to enhanced dispersion and nanoconfinement. For photothermal conversion, the composite exhibited a broadened absorption spectrum and achieved a high efficiency of 91.0%, nearly three times higher than paraffin/As‐synthesized CNT (As‐CNT) composite. As an anode in lithium‐ion batteries, B‐CNTs delivered a reversible capacity of 361.02 mAh/g after 100 cycles, more than double that of pristine CNTs due to improved conductivity and Li+ diffusion. Furthermore, in a paraffin/B‐CNT‐integrated thermoelectric module, enhanced interfacial heat transfer enabled stable heat‐source functionality and a conversion efficiency of 0.33%. These findings demonstrate the practical potential of B‐CNTs as a multifunctional material for improving performance in diverse energy storage and conversion systems. [ABSTRACT FROM AUTHOR]
Copyright of International Journal of Energy Research is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Defect‐Anchored Carbon Nanotubes With Tailored Electronic Structure as a Single Platform for Thermal Energy Storage, Li‐Ion Battery Anodes, and Thermoelectric Conversion.
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  Data: <searchLink fieldCode="AR" term="%22Mehdi%2C+Syed+Muhammad+Zain%22">Mehdi, Syed Muhammad Zain</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Faizan%2C+Muhammad%22">Faizan, Muhammad</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Mohan%2C+Man%22">Mohan, Man</searchLink><relatesTo>3,4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Shridharan%2C+Tatachari+Santhanagopalan%22">Shridharan, Tatachari Santhanagopalan</searchLink><relatesTo>3,5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Awasthi%2C+Abhishek%22">Awasthi, Abhishek</searchLink><relatesTo>6</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Youn%2C+Gyosik%22">Youn, Gyosik</searchLink><relatesTo>5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Cho%2C+In+Sun%22">Cho, In Sun</searchLink><relatesTo>3,5,7</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Nam%2C+Kyung-Wan%22">Nam, Kyung-Wan</searchLink><relatesTo>8</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Lee%2C+Naesung%22">Lee, Naesung</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> nslee@sejong.ac.kr</i><br /><searchLink fieldCode="AR" term="%22Ahn%2C+Byungmin%22">Ahn, Byungmin</searchLink><relatesTo>3,5,7</relatesTo> (AUTHOR)<i> byungmin@ajou.ac.kr</i><br /><searchLink fieldCode="AR" term="%22Parale%2C+Vinayak%22">Parale, Vinayak</searchLink> (AUTHOR)<i> vinayak@yonsei.ac.kr</i>
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  Data: <searchLink fieldCode="JN" term="%22International+Journal+of+Energy+Research%22">International Journal of Energy Research</searchLink>. 4/24/2026, Vol. 2026, p1-25. 25p.
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  Data: <searchLink fieldCode="DE" term="%22Carbon+nanotubes%22">Carbon nanotubes</searchLink><br /><searchLink fieldCode="DE" term="%22Boron%22">Boron</searchLink><br /><searchLink fieldCode="DE" term="%22Energy+storage%22">Energy storage</searchLink><br /><searchLink fieldCode="DE" term="%22Lithium-ion+batteries%22">Lithium-ion batteries</searchLink><br /><searchLink fieldCode="DE" term="%22Nanostructured+materials%22">Nanostructured materials</searchLink><br /><searchLink fieldCode="DE" term="%22Thermoelectric+conversion%22">Thermoelectric conversion</searchLink><br /><searchLink fieldCode="DE" term="%22Photothermal+conversion%22">Photothermal conversion</searchLink><br /><searchLink fieldCode="DE" term="%22Heat+storage%22">Heat storage</searchLink>
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  Label: Abstract
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  Data: Heteroatom doping offers a unified and energy‐efficient strategy to tailor the electronic structure of carbon nanotubes (CNTs) for multifunctional energy applications. In this study, boron‐doped CNTs (B‐CNTs) synthesized via a single‐step arc discharge method are evaluated across four domains: thermal energy storage, photothermal conversion, lithium‐ion batteries, and thermoelectric generation. The present study benefits from p‐type defect formation in CNT, which includes a work function increase and a shifted Fermi level. In thermal energy storage, a paraffin/B‐CNT composite demonstrated superior thermal conductivity (0.303 W/m·K), latent heat capacity (144.7 J/g), and crystallinity (51.9%) due to enhanced dispersion and nanoconfinement. For photothermal conversion, the composite exhibited a broadened absorption spectrum and achieved a high efficiency of 91.0%, nearly three times higher than paraffin/As‐synthesized CNT (As‐CNT) composite. As an anode in lithium‐ion batteries, B‐CNTs delivered a reversible capacity of 361.02 mAh/g after 100 cycles, more than double that of pristine CNTs due to improved conductivity and Li+ diffusion. Furthermore, in a paraffin/B‐CNT‐integrated thermoelectric module, enhanced interfacial heat transfer enabled stable heat‐source functionality and a conversion efficiency of 0.33%. These findings demonstrate the practical potential of B‐CNTs as a multifunctional material for improving performance in diverse energy storage and conversion systems. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of International Journal of Energy Research is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1155/er/8883932
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      – Code: eng
        Text: English
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        PageCount: 25
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      – SubjectFull: Carbon nanotubes
        Type: general
      – SubjectFull: Boron
        Type: general
      – SubjectFull: Energy storage
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      – SubjectFull: Lithium-ion batteries
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      – SubjectFull: Nanostructured materials
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      – SubjectFull: Thermoelectric conversion
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      – SubjectFull: Photothermal conversion
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      – SubjectFull: Heat storage
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      – TitleFull: Defect‐Anchored Carbon Nanotubes With Tailored Electronic Structure as a Single Platform for Thermal Energy Storage, Li‐Ion Battery Anodes, and Thermoelectric Conversion.
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              Text: 4/24/2026
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              Y: 2026
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