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Fine and hyperfine interactions with multi-level spin relaxation of the purified Giese-salt in veterinary medicine: Prussian blue compound ammonium-ferric-hexacyano-ferrate.

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Title: Fine and hyperfine interactions with multi-level spin relaxation of the purified Giese-salt in veterinary medicine: Prussian blue compound ammonium-ferric-hexacyano-ferrate.
Authors: Bräuninger, Sascha A.1 (AUTHOR) Sascha.Albert.Braeuninger@tiho-hannover.de, Motz, Damian A.1,2 (AUTHOR) motz@isah.uni-hannover.de, Praetz, Sebastian3 (AUTHOR) sebastian.praetz@tu-berlin.de, Seewald, Felix4 (AUTHOR) felix.seewald@tu-dresden.de, Strecker, Katharina5 (AUTHOR) Katharina.Strecker@chemie.tu-freiberg.de, Vogt, Carla5 (AUTHOR) Carla.Vogt@chemie.tu-freiberg.de, Klauss, Hans-Henning4 (AUTHOR) henning.klauss@tu-dresden.de, Kanngießer, Birgit3 (AUTHOR) birgit.kanngiesser@tu-berlin.de, Seifert, Hermann1 (AUTHOR) Hermann.Seifert@tiho-hannover.de
Source: Journal of Radioanalytical & Nuclear Chemistry. Apr2026, Vol. 335 Issue 4, p3103-3128. 26p.
Subjects: Veterinary medicine, Prussian blue, Ferromagnetism, Spin-lattice relaxation, Mössbauer spectroscopy, Nanostructured materials
Abstract: Ammonium ferric hexacyanoferrate is a veterinary-medical milestone and antidote against radiocesium, well-known as Giese-salt after the Chernobyl disaster fed to domestic and wild animals, which shows even a rich interplay of properties in nanostructural chemistry and ferromagnetism. Among the broad analytical techniques, the ambivalence of macroscopic micrometer-sized agglomerates and nanoparticle sizes, a suggested enlarged Fe II - C ≡ N - Fe III bond length by Fe K-edge XAFS results and multi-level spin relaxation in 57 Fe Mössbauer spectroscopy are highlighted. This sets this underestimated compound in a new light, e.g., for modern biomedicine and biofunctionality, extending its essential importance in addition to hypothetical future nuclear incidents. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Radioanalytical & Nuclear Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Fine and hyperfine interactions with multi-level spin relaxation of the purified Giese-salt in veterinary medicine: Prussian blue compound ammonium-ferric-hexacyano-ferrate.
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  Data: <searchLink fieldCode="AR" term="%22Bräuninger%2C+Sascha+A%2E%22">Bräuninger, Sascha A.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> Sascha.Albert.Braeuninger@tiho-hannover.de</i><br /><searchLink fieldCode="AR" term="%22Motz%2C+Damian+A%2E%22">Motz, Damian A.</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> motz@isah.uni-hannover.de</i><br /><searchLink fieldCode="AR" term="%22Praetz%2C+Sebastian%22">Praetz, Sebastian</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> sebastian.praetz@tu-berlin.de</i><br /><searchLink fieldCode="AR" term="%22Seewald%2C+Felix%22">Seewald, Felix</searchLink><relatesTo>4</relatesTo> (AUTHOR)<i> felix.seewald@tu-dresden.de</i><br /><searchLink fieldCode="AR" term="%22Strecker%2C+Katharina%22">Strecker, Katharina</searchLink><relatesTo>5</relatesTo> (AUTHOR)<i> Katharina.Strecker@chemie.tu-freiberg.de</i><br /><searchLink fieldCode="AR" term="%22Vogt%2C+Carla%22">Vogt, Carla</searchLink><relatesTo>5</relatesTo> (AUTHOR)<i> Carla.Vogt@chemie.tu-freiberg.de</i><br /><searchLink fieldCode="AR" term="%22Klauss%2C+Hans-Henning%22">Klauss, Hans-Henning</searchLink><relatesTo>4</relatesTo> (AUTHOR)<i> henning.klauss@tu-dresden.de</i><br /><searchLink fieldCode="AR" term="%22Kanngießer%2C+Birgit%22">Kanngießer, Birgit</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> birgit.kanngiesser@tu-berlin.de</i><br /><searchLink fieldCode="AR" term="%22Seifert%2C+Hermann%22">Seifert, Hermann</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> Hermann.Seifert@tiho-hannover.de</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Radioanalytical+%26+Nuclear+Chemistry%22">Journal of Radioanalytical & Nuclear Chemistry</searchLink>. Apr2026, Vol. 335 Issue 4, p3103-3128. 26p.
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  Data: <searchLink fieldCode="DE" term="%22Veterinary+medicine%22">Veterinary medicine</searchLink><br /><searchLink fieldCode="DE" term="%22Prussian+blue%22">Prussian blue</searchLink><br /><searchLink fieldCode="DE" term="%22Ferromagnetism%22">Ferromagnetism</searchLink><br /><searchLink fieldCode="DE" term="%22Spin-lattice+relaxation%22">Spin-lattice relaxation</searchLink><br /><searchLink fieldCode="DE" term="%22Mössbauer+spectroscopy%22">Mössbauer spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Nanostructured+materials%22">Nanostructured materials</searchLink>
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  Data: Ammonium ferric hexacyanoferrate is a veterinary-medical milestone and antidote against radiocesium, well-known as Giese-salt after the Chernobyl disaster fed to domestic and wild animals, which shows even a rich interplay of properties in nanostructural chemistry and ferromagnetism. Among the broad analytical techniques, the ambivalence of macroscopic micrometer-sized agglomerates and nanoparticle sizes, a suggested enlarged Fe II - C ≡ N - Fe III bond length by Fe K-edge XAFS results and multi-level spin relaxation in 57 Fe Mössbauer spectroscopy are highlighted. This sets this underestimated compound in a new light, e.g., for modern biomedicine and biofunctionality, extending its essential importance in addition to hypothetical future nuclear incidents. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Journal of Radioanalytical & Nuclear Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1007/s10967-026-10838-8
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        Text: English
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        PageCount: 26
        StartPage: 3103
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      – SubjectFull: Veterinary medicine
        Type: general
      – SubjectFull: Prussian blue
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      – SubjectFull: Ferromagnetism
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      – SubjectFull: Spin-lattice relaxation
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      – SubjectFull: Mössbauer spectroscopy
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      – SubjectFull: Nanostructured materials
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      – TitleFull: Fine and hyperfine interactions with multi-level spin relaxation of the purified Giese-salt in veterinary medicine: Prussian blue compound ammonium-ferric-hexacyano-ferrate.
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              Text: Apr2026
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