Applications for TiAlN- and TiO2-coatings with nanoscale surface topographies

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Title: Applications for TiAlN- and TiO2-coatings with nanoscale surface topographies
Authors: Burmeister, F.1 frank.burmeister@iwm.fhg.de, Kohn, C.1, Kuebler, R.1, Kleer, G.1, Bläsi, B.2, Gombert, A.2
Source: Surface & Coatings Technology. Nov2005, Vol. 200 Issue 5/6, p1555-1559. 5p.
Subjects: Coating processes, Nanotechnology, Electron microscopy, Chemical reactions
Abstract: Abstract: This paper reports on the development of nanostructured, multifunctional TiAlN- and TiO2-coatings where the multifunctionality stems from their nanoscale surface topography. The coatings were sputter-deposited on silicon and steel substrates by a reactive RF-magnetron-process. For both types of coatings deposition parameters which led to a columnar growth with mean column diameters between 100 nm and 500 nm were elaborated. The columns itself were terminated by pyramid-shaped tips where the geometric forms of the pyramids were determined by the crystal system of the coating material. Investigations of microstructure and surface morphology were carried out with scanning electron microscopy, atomic force microscopy and X-ray diffraction techniques. A power law was found for the dependence of the mean column diameter on coating thickness in qualitative agreement with phenomenological models for thin film growth. In order to test the coating''s suitability for industrial applications, both coating materials were deposited on steel tools and replicated into the surfaces of PMMA sheets. The resulting sheet''s surface morphologies proved to be comparable to the antireflective surfaces of motheyes and led to a pronounced decrease in reflectivity. A second possible application, namely the modification of wetting properties of surfaces due to their structuring, was tested by fluorination of the nanostructured TiO2-surface which led to an ultrahydrophobic surface with water contact angles up to 150°. [Copyright &y& Elsevier]
Copyright of Surface & Coatings Technology is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 19332149
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  Data: Applications for TiAlN- and TiO<subscript>2</subscript>-coatings with nanoscale surface topographies
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  Data: <searchLink fieldCode="JN" term="%22Surface+%26+Coatings+Technology%22">Surface & Coatings Technology</searchLink>. Nov2005, Vol. 200 Issue 5/6, p1555-1559. 5p.
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  Label: Abstract
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  Data: Abstract: This paper reports on the development of nanostructured, multifunctional TiAlN- and TiO2-coatings where the multifunctionality stems from their nanoscale surface topography. The coatings were sputter-deposited on silicon and steel substrates by a reactive RF-magnetron-process. For both types of coatings deposition parameters which led to a columnar growth with mean column diameters between 100 nm and 500 nm were elaborated. The columns itself were terminated by pyramid-shaped tips where the geometric forms of the pyramids were determined by the crystal system of the coating material. Investigations of microstructure and surface morphology were carried out with scanning electron microscopy, atomic force microscopy and X-ray diffraction techniques. A power law was found for the dependence of the mean column diameter on coating thickness in qualitative agreement with phenomenological models for thin film growth. In order to test the coating''s suitability for industrial applications, both coating materials were deposited on steel tools and replicated into the surfaces of PMMA sheets. The resulting sheet''s surface morphologies proved to be comparable to the antireflective surfaces of motheyes and led to a pronounced decrease in reflectivity. A second possible application, namely the modification of wetting properties of surfaces due to their structuring, was tested by fluorination of the nanostructured TiO2-surface which led to an ultrahydrophobic surface with water contact angles up to 150°. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Surface & Coatings Technology is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.surfcoat.2005.08.062
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      – Code: eng
        Text: English
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      – SubjectFull: Electron microscopy
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      – SubjectFull: Chemical reactions
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              Text: Nov2005
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