Tribocorrosion Behavior of Mg Alloys on Sliding Friction in Hank's Balanced Salt Solution.

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Title: Tribocorrosion Behavior of Mg Alloys on Sliding Friction in Hank's Balanced Salt Solution.
Authors: Miura, Eri1 (AUTHOR) emiura@eng.u-hyogo.ac.jp, Shiraishi, Chihiro1,2 (AUTHOR), Hiromoto, Sachiko1,2 (AUTHOR)
Source: Materials (1996-1944). Apr2026, Vol. 19 Issue 8, p1513. 20p.
Subjects: Tribo-corrosion, Sliding friction, Magnesium alloys, Buffer solutions, Corrosion resistance, Electrochemical analysis, Sliding wear, Mechanical behavior of materials
Abstract: The tribocorrosion behavior of AZ31 and WE43 was investigated during sliding wear tests in Hank's balanced salt solution (HBSS) and pure water. While wear volume increased monotonically with load in air and water, HBSS exhibited a distinct non-monotonic trend; the maximum material loss occurred at the minimum load (0.98 N) and decreased at 2.94 N before rising again. This indicates that at low loads, degradation is primarily driven by accelerated chemical dissolution (tribocorrosion) rather than by purely mechanical abrasion. The magnitude of wear followed the order [HBSS] > [air] > [water] in the low-load range (0.98–1.96 N), whereas it shifted to [air] > [HBSS] > [water] in the high-load range (2.94–5.88 N). A comparison of the wear rate of the alloys shows that the wear rate in HBSS differs from that in water, depending on the hardness of the substrate, similar to conditions in air. Notably, the specific wear rate decreased as test duration increased under low loads, further suggesting that corrosion-induced volume loss significantly outweighs mechanical wear in this regime. The static corrosion test revealed that volume loss during tribocorrosion was higher than that under static corrosion conditions. While the deposition of corrosion products affected net volume loss, chemical dissolution remained the primary driver of the observed wear trends at low loads. Electrochemical data from anodic polarization curves confirmed that the specimen tested under a 0.98 N load exhibited lower corrosion resistance. Mechanistically, it was suggested that Cl− ions contributed to the overall increase in wear, while NaHCO3 specifically contributed to the increase in wear in the low-load range. [ABSTRACT FROM AUTHOR]
Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Tribocorrosion Behavior of Mg Alloys on Sliding Friction in Hank's Balanced Salt Solution.
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  Data: <searchLink fieldCode="AR" term="%22Miura%2C+Eri%22">Miura, Eri</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> emiura@eng.u-hyogo.ac.jp</i><br /><searchLink fieldCode="AR" term="%22Shiraishi%2C+Chihiro%22">Shiraishi, Chihiro</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hiromoto%2C+Sachiko%22">Hiromoto, Sachiko</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Materials+%281996-1944%29%22">Materials (1996-1944)</searchLink>. Apr2026, Vol. 19 Issue 8, p1513. 20p.
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  Data: <searchLink fieldCode="DE" term="%22Tribo-corrosion%22">Tribo-corrosion</searchLink><br /><searchLink fieldCode="DE" term="%22Sliding+friction%22">Sliding friction</searchLink><br /><searchLink fieldCode="DE" term="%22Magnesium+alloys%22">Magnesium alloys</searchLink><br /><searchLink fieldCode="DE" term="%22Buffer+solutions%22">Buffer solutions</searchLink><br /><searchLink fieldCode="DE" term="%22Corrosion+resistance%22">Corrosion resistance</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemical+analysis%22">Electrochemical analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Sliding+wear%22">Sliding wear</searchLink><br /><searchLink fieldCode="DE" term="%22Mechanical+behavior+of+materials%22">Mechanical behavior of materials</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The tribocorrosion behavior of AZ31 and WE43 was investigated during sliding wear tests in Hank's balanced salt solution (HBSS) and pure water. While wear volume increased monotonically with load in air and water, HBSS exhibited a distinct non-monotonic trend; the maximum material loss occurred at the minimum load (0.98 N) and decreased at 2.94 N before rising again. This indicates that at low loads, degradation is primarily driven by accelerated chemical dissolution (tribocorrosion) rather than by purely mechanical abrasion. The magnitude of wear followed the order [HBSS] > [air] > [water] in the low-load range (0.98–1.96 N), whereas it shifted to [air] > [HBSS] > [water] in the high-load range (2.94–5.88 N). A comparison of the wear rate of the alloys shows that the wear rate in HBSS differs from that in water, depending on the hardness of the substrate, similar to conditions in air. Notably, the specific wear rate decreased as test duration increased under low loads, further suggesting that corrosion-induced volume loss significantly outweighs mechanical wear in this regime. The static corrosion test revealed that volume loss during tribocorrosion was higher than that under static corrosion conditions. While the deposition of corrosion products affected net volume loss, chemical dissolution remained the primary driver of the observed wear trends at low loads. Electrochemical data from anodic polarization curves confirmed that the specimen tested under a 0.98 N load exhibited lower corrosion resistance. Mechanistically, it was suggested that Cl− ions contributed to the overall increase in wear, while NaHCO3 specifically contributed to the increase in wear in the low-load range. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.3390/ma19081513
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 20
        StartPage: 1513
    Subjects:
      – SubjectFull: Tribo-corrosion
        Type: general
      – SubjectFull: Sliding friction
        Type: general
      – SubjectFull: Magnesium alloys
        Type: general
      – SubjectFull: Buffer solutions
        Type: general
      – SubjectFull: Corrosion resistance
        Type: general
      – SubjectFull: Electrochemical analysis
        Type: general
      – SubjectFull: Sliding wear
        Type: general
      – SubjectFull: Mechanical behavior of materials
        Type: general
    Titles:
      – TitleFull: Tribocorrosion Behavior of Mg Alloys on Sliding Friction in Hank's Balanced Salt Solution.
        Type: main
  BibRelationships:
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      – PersonEntity:
          Name:
            NameFull: Miura, Eri
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            NameFull: Shiraishi, Chihiro
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            NameFull: Hiromoto, Sachiko
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          Dates:
            – D: 15
              M: 04
              Text: Apr2026
              Type: published
              Y: 2026
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              Value: 19
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              Value: 8
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            – TitleFull: Materials (1996-1944)
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