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A Case Study in Biomimetic Total Synthesis: Polyolefin Carbocyclizations to Terpenes and Steroids.

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Title: A Case Study in Biomimetic Total Synthesis: Polyolefin Carbocyclizations to Terpenes and Steroids.
Authors: Yoder, Ryan A.1, Johnston, Jeffrey N.1 Jeffrey.N.Johnston@vanderbilt.edu
Source: Chemical Reviews. Dec2005, Vol. 105 Issue 12, p4730-4756. 27p. 18 Diagrams.
Subjects: Polyolefins, Organic synthesis, Terpenes, Steroids, Biosynthesis, Biochemistry
Abstract: The article presents a comprehensive review on polyolefin cyclizations, illustrated as a case study in biomimetic total synthesis. The author has discussed how his research contributed to the development of synthetic methods that converge upon the efficient techniques of nature. He has however conceded that intriguing new questions about these transformations remain, thereby stimulating questions on biosynthesis mechanisms and synthesis possibilities. He has likewise emphasized the need to clearly understand their mutual benefits.
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 19344831
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: A Case Study in Biomimetic Total Synthesis: Polyolefin Carbocyclizations to Terpenes and Steroids.
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  Data: <searchLink fieldCode="JN" term="%22Chemical+Reviews%22">Chemical Reviews</searchLink>. Dec2005, Vol. 105 Issue 12, p4730-4756. 27p. 18 Diagrams.
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  Data: <searchLink fieldCode="DE" term="%22Polyolefins%22">Polyolefins</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+synthesis%22">Organic synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Terpenes%22">Terpenes</searchLink><br /><searchLink fieldCode="DE" term="%22Steroids%22">Steroids</searchLink><br /><searchLink fieldCode="DE" term="%22Biosynthesis%22">Biosynthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Biochemistry%22">Biochemistry</searchLink>
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  Data: The article presents a comprehensive review on polyolefin cyclizations, illustrated as a case study in biomimetic total synthesis. The author has discussed how his research contributed to the development of synthetic methods that converge upon the efficient techniques of nature. He has however conceded that intriguing new questions about these transformations remain, thereby stimulating questions on biosynthesis mechanisms and synthesis possibilities. He has likewise emphasized the need to clearly understand their mutual benefits.
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RecordInfo BibRecord:
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        Value: 10.1021/cr040623l
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 27
        StartPage: 4730
    Subjects:
      – SubjectFull: Polyolefins
        Type: general
      – SubjectFull: Organic synthesis
        Type: general
      – SubjectFull: Terpenes
        Type: general
      – SubjectFull: Steroids
        Type: general
      – SubjectFull: Biosynthesis
        Type: general
      – SubjectFull: Biochemistry
        Type: general
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      – TitleFull: A Case Study in Biomimetic Total Synthesis: Polyolefin Carbocyclizations to Terpenes and Steroids.
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            NameFull: Yoder, Ryan A.
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            NameFull: Johnston, Jeffrey N.
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            – D: 01
              M: 12
              Text: Dec2005
              Type: published
              Y: 2005
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              Value: 105
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              Value: 12
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            – TitleFull: Chemical Reviews
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