Corrosion Behaviour of Injection- and Compression-Moulded Nd–Fe–B and Sm–Fe–N Magnets with Different Polymer Binders.

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Title: Corrosion Behaviour of Injection- and Compression-Moulded Nd–Fe–B and Sm–Fe–N Magnets with Different Polymer Binders.
Authors: Lešić, Nikolina1,2 (AUTHOR), Kovačević, Nataša2,3 (AUTHOR), Milošev, Ingrid1,2,3 (AUTHOR) ingrid.milosev@ijs.si
Source: Polymers (20734360). May2026, Vol. 18 Issue 9, p1123. 21p.
Subjects: Injection molding, Compression molding, Polymeric composites, Thermal stability, Corrosion engineering, Magnetic particles, Permanent magnets
Abstract: The corrosion behaviour and environmental durability of injection- and compression-moulded Nd–Fe–B and Sm–Fe–N magnets were investigated. For injection-moulded magnets, the effects of magnetic powder type (Nd–Fe–B and Sm–Fe–N), magnetic powder particle size (100 µm and 400 µm), and polymer binder (PPS and PA12) on corrosion resistance were studied. For compression-moulded magnets with an epoxy binder, the effects of powder type and size were examined. Corrosion resistance was investigated using potentiodynamic polarisation in electrolytes of varying pH (1.8–12.8). The Sm–Fe–N magnets exhibited slightly better corrosion resistance than the Nd–Fe–B magnets, irrespective of the polymer binder. The finer magnetic powders (100 µm) showed lower corrosion resistance due to their larger specific surface area, with a more pronounced effect in the compression-moulded magnets. The type of polymer binder had only a minor effect. The hygrothermal corrosion resistance and thermal stability were evaluated using bulk corrosion (BCT) and thermal shock tests, respectively. Surface corrosion was observed in all magnets after the BCT, with the compression-moulded magnets exhibiting a greater irreversible loss of magnetic properties. The thermal shock test caused a temporary reduction in magnetic properties, with recovery after remagnetisation, demonstrating the good thermal stability of both magnet types. [ABSTRACT FROM AUTHOR]
Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Corrosion Behaviour of Injection- and Compression-Moulded Nd–Fe–B and Sm–Fe–N Magnets with Different Polymer Binders.
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  Data: <searchLink fieldCode="AR" term="%22Lešić%2C+Nikolina%22">Lešić, Nikolina</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Kovačević%2C+Nataša%22">Kovačević, Nataša</searchLink><relatesTo>2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Milošev%2C+Ingrid%22">Milošev, Ingrid</searchLink><relatesTo>1,2,3</relatesTo> (AUTHOR)<i> ingrid.milosev@ijs.si</i>
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  Data: <searchLink fieldCode="JN" term="%22Polymers+%2820734360%29%22">Polymers (20734360)</searchLink>. May2026, Vol. 18 Issue 9, p1123. 21p.
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  Data: <searchLink fieldCode="DE" term="%22Injection+molding%22">Injection molding</searchLink><br /><searchLink fieldCode="DE" term="%22Compression+molding%22">Compression molding</searchLink><br /><searchLink fieldCode="DE" term="%22Polymeric+composites%22">Polymeric composites</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+stability%22">Thermal stability</searchLink><br /><searchLink fieldCode="DE" term="%22Corrosion+engineering%22">Corrosion engineering</searchLink><br /><searchLink fieldCode="DE" term="%22Magnetic+particles%22">Magnetic particles</searchLink><br /><searchLink fieldCode="DE" term="%22Permanent+magnets%22">Permanent magnets</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The corrosion behaviour and environmental durability of injection- and compression-moulded Nd–Fe–B and Sm–Fe–N magnets were investigated. For injection-moulded magnets, the effects of magnetic powder type (Nd–Fe–B and Sm–Fe–N), magnetic powder particle size (100 µm and 400 µm), and polymer binder (PPS and PA12) on corrosion resistance were studied. For compression-moulded magnets with an epoxy binder, the effects of powder type and size were examined. Corrosion resistance was investigated using potentiodynamic polarisation in electrolytes of varying pH (1.8–12.8). The Sm–Fe–N magnets exhibited slightly better corrosion resistance than the Nd–Fe–B magnets, irrespective of the polymer binder. The finer magnetic powders (100 µm) showed lower corrosion resistance due to their larger specific surface area, with a more pronounced effect in the compression-moulded magnets. The type of polymer binder had only a minor effect. The hygrothermal corrosion resistance and thermal stability were evaluated using bulk corrosion (BCT) and thermal shock tests, respectively. Surface corrosion was observed in all magnets after the BCT, with the compression-moulded magnets exhibiting a greater irreversible loss of magnetic properties. The thermal shock test caused a temporary reduction in magnetic properties, with recovery after remagnetisation, demonstrating the good thermal stability of both magnet types. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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        Value: 10.3390/polym18091123
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      – Code: eng
        Text: English
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        PageCount: 21
        StartPage: 1123
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      – SubjectFull: Injection molding
        Type: general
      – SubjectFull: Compression molding
        Type: general
      – SubjectFull: Polymeric composites
        Type: general
      – SubjectFull: Thermal stability
        Type: general
      – SubjectFull: Corrosion engineering
        Type: general
      – SubjectFull: Magnetic particles
        Type: general
      – SubjectFull: Permanent magnets
        Type: general
    Titles:
      – TitleFull: Corrosion Behaviour of Injection- and Compression-Moulded Nd–Fe–B and Sm–Fe–N Magnets with Different Polymer Binders.
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          Name:
            NameFull: Lešić, Nikolina
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            NameFull: Kovačević, Nataša
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            NameFull: Milošev, Ingrid
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            – D: 01
              M: 05
              Text: May2026
              Type: published
              Y: 2026
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            – TitleFull: Polymers (20734360)
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