Precision graphene nanoribbons: chemical strategies for tailored edge, backbone, and electronic structure.

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Title: Precision graphene nanoribbons: chemical strategies for tailored edge, backbone, and electronic structure.
Authors: Chen, Xinyu1 (AUTHOR), Qiu, Yuanhuan1 (AUTHOR), Zhang, Jin-Jiang2 (AUTHOR), Liu, Xiangyang1 (AUTHOR), Ma, Ji3,4 (AUTHOR) maji26@iccas.ac.cn, Wang, Xu1 (AUTHOR) wangxu@scu.edu.cn, Feng, Xinliang2,5 (AUTHOR) xinliang.feng@mpi-halle.mpg.de
Source: Chemical Society Reviews. 5/26/2026, Vol. 55 Issue 10, p5590-5641. 52p.
Subjects: Chemical synthesis, Edges (Geometry), Nanoribbons, Nanostructures, Electronic materials, Optoelectronics, Spintronics
Abstract: Graphene nanoribbons (GNRs), quasi-one-dimensional graphene nanostructures, are promising candidates for next-generation electronic, optoelectronic, and spintronic applications due to their tunable (opto-)electronic and magnetic properties. The intrinsic properties of GNRs are critically determined by atomic-scale structural parameters such as width, edge configuration, and backbone architecture, all of which can be precisely designed and regulated through bottom-up synthetic strategies. Recent years have witnessed remarkable progress in the bottom-up chemical synthesis of GNRs, and a diverse array of innovative structural engineering strategies, such as edge topology modulation, backbone modification, and heterojunction construction, have been developed. These advances have enabled precise control over GNR characteristics and have deepened understanding of their structure–property relationships, correlating atomic-scale features with electronic band structure, charge-carrier mobility, spin polarization, and topological states. This review summarizes the latest developments of precision GNRs, focusing on how rational design and synthetic breakthroughs have transformed GNRs into a versatile, atomically precise materials platform. By integrating advanced synthesis and characterization methods, the research field is paving the way for functional GNR-based devices in future electronic, spintronic, and quantum information systems. [ABSTRACT FROM AUTHOR]
Copyright of Chemical Society Reviews is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Precision graphene nanoribbons: chemical strategies for tailored edge, backbone, and electronic structure.
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  Data: <searchLink fieldCode="AR" term="%22Chen%2C+Xinyu%22">Chen, Xinyu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Qiu%2C+Yuanhuan%22">Qiu, Yuanhuan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Jin-Jiang%22">Zhang, Jin-Jiang</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Liu%2C+Xiangyang%22">Liu, Xiangyang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ma%2C+Ji%22">Ma, Ji</searchLink><relatesTo>3,4</relatesTo> (AUTHOR)<i> maji26@iccas.ac.cn</i><br /><searchLink fieldCode="AR" term="%22Wang%2C+Xu%22">Wang, Xu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> wangxu@scu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Feng%2C+Xinliang%22">Feng, Xinliang</searchLink><relatesTo>2,5</relatesTo> (AUTHOR)<i> xinliang.feng@mpi-halle.mpg.de</i>
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  Data: <searchLink fieldCode="JN" term="%22Chemical+Society+Reviews%22">Chemical Society Reviews</searchLink>. 5/26/2026, Vol. 55 Issue 10, p5590-5641. 52p.
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  Data: <searchLink fieldCode="DE" term="%22Chemical+synthesis%22">Chemical synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Edges+%28Geometry%29%22">Edges (Geometry)</searchLink><br /><searchLink fieldCode="DE" term="%22Nanoribbons%22">Nanoribbons</searchLink><br /><searchLink fieldCode="DE" term="%22Nanostructures%22">Nanostructures</searchLink><br /><searchLink fieldCode="DE" term="%22Electronic+materials%22">Electronic materials</searchLink><br /><searchLink fieldCode="DE" term="%22Optoelectronics%22">Optoelectronics</searchLink><br /><searchLink fieldCode="DE" term="%22Spintronics%22">Spintronics</searchLink>
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  Label: Abstract
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  Data: Graphene nanoribbons (GNRs), quasi-one-dimensional graphene nanostructures, are promising candidates for next-generation electronic, optoelectronic, and spintronic applications due to their tunable (opto-)electronic and magnetic properties. The intrinsic properties of GNRs are critically determined by atomic-scale structural parameters such as width, edge configuration, and backbone architecture, all of which can be precisely designed and regulated through bottom-up synthetic strategies. Recent years have witnessed remarkable progress in the bottom-up chemical synthesis of GNRs, and a diverse array of innovative structural engineering strategies, such as edge topology modulation, backbone modification, and heterojunction construction, have been developed. These advances have enabled precise control over GNR characteristics and have deepened understanding of their structure–property relationships, correlating atomic-scale features with electronic band structure, charge-carrier mobility, spin polarization, and topological states. This review summarizes the latest developments of precision GNRs, focusing on how rational design and synthetic breakthroughs have transformed GNRs into a versatile, atomically precise materials platform. By integrating advanced synthesis and characterization methods, the research field is paving the way for functional GNR-based devices in future electronic, spintronic, and quantum information systems. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Chemical Society Reviews is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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        Value: 10.1039/d6cs00220j
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        Text: English
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      – SubjectFull: Edges (Geometry)
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      – SubjectFull: Nanoribbons
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      – SubjectFull: Nanostructures
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      – SubjectFull: Electronic materials
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      – SubjectFull: Optoelectronics
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      – SubjectFull: Spintronics
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              M: 05
              Text: 5/26/2026
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              Y: 2026
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