Easy Synthesis of a Multifunctional Macrophotoinitiator with Pendant Moieties of Benzoin Methyl Ether Derivative for Use as Active Surface-Modifier of Inorganic Fillers.
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| Title: | Easy Synthesis of a Multifunctional Macrophotoinitiator with Pendant Moieties of Benzoin Methyl Ether Derivative for Use as Active Surface-Modifier of Inorganic Fillers. |
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| Authors: | Ohar, Halyna1 (AUTHOR) halyna.o.ohar@lpnu.ua, Tokareva, Maria1,2 (AUTHOR), Tokarev, Viktor2 (AUTHOR) |
| Source: | Polymers (20734360). May2026, Vol. 18 Issue 10, p1265. 28p. |
| Subjects: | Photopolymerization, Titanium dioxide, Mechanical behavior of materials, Polymeric nanocomposites, Polymerization, Photopolymers, Surface preparation |
| Abstract: | A novel macromolecular photoinitiator (MPI) was synthesized from a copolymer of maleic anhydride and methyl methacrylate and subsequently functionalized with 3-hydroxy-2-methoxy-1,2-diphenylpropan-1-one moieties via a polymer-analogous acylation reaction. The structure and physicochemical properties of the MPI were characterized by IR, UV–Vis, NMR, DSC, and TGA analyses. TiO2 nanoparticles were successfully functionalized with the MPI, yielding materials with enhanced surface activity and photoinitiating efficiency. The MPI-modified TiO2 facilitated efficient UV-induced polymerization of methyl methacrylate, as confirmed by DLS and SEM analyses. Compared with unmodified fillers, the resulting composites exhibited improved dispersion, accelerated polymerization rates, and enhanced mechanical properties. This hybrid strategy offers a promising approach for the development of high-performance polymer nanocomposites through the integration of surface-engineered inorganic fillers and photoreactive polymers. [ABSTRACT FROM AUTHOR] |
| Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 194117866 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Easy Synthesis of a Multifunctional Macrophotoinitiator with Pendant Moieties of Benzoin Methyl Ether Derivative for Use as Active Surface-Modifier of Inorganic Fillers. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Ohar%2C+Halyna%22">Ohar, Halyna</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> halyna.o.ohar@lpnu.ua</i><br /><searchLink fieldCode="AR" term="%22Tokareva%2C+Maria%22">Tokareva, Maria</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Tokarev%2C+Viktor%22">Tokarev, Viktor</searchLink><relatesTo>2</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Polymers+%2820734360%29%22">Polymers (20734360)</searchLink>. May2026, Vol. 18 Issue 10, p1265. 28p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Photopolymerization%22">Photopolymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Titanium+dioxide%22">Titanium dioxide</searchLink><br /><searchLink fieldCode="DE" term="%22Mechanical+behavior+of+materials%22">Mechanical behavior of materials</searchLink><br /><searchLink fieldCode="DE" term="%22Polymeric+nanocomposites%22">Polymeric nanocomposites</searchLink><br /><searchLink fieldCode="DE" term="%22Polymerization%22">Polymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Photopolymers%22">Photopolymers</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+preparation%22">Surface preparation</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: A novel macromolecular photoinitiator (MPI) was synthesized from a copolymer of maleic anhydride and methyl methacrylate and subsequently functionalized with 3-hydroxy-2-methoxy-1,2-diphenylpropan-1-one moieties via a polymer-analogous acylation reaction. The structure and physicochemical properties of the MPI were characterized by IR, UV–Vis, NMR, DSC, and TGA analyses. TiO2 nanoparticles were successfully functionalized with the MPI, yielding materials with enhanced surface activity and photoinitiating efficiency. The MPI-modified TiO2 facilitated efficient UV-induced polymerization of methyl methacrylate, as confirmed by DLS and SEM analyses. Compared with unmodified fillers, the resulting composites exhibited improved dispersion, accelerated polymerization rates, and enhanced mechanical properties. This hybrid strategy offers a promising approach for the development of high-performance polymer nanocomposites through the integration of surface-engineered inorganic fillers and photoreactive polymers. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
| PLink | https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=194117866 |
| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.3390/polym18101265 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 28 StartPage: 1265 Subjects: – SubjectFull: Photopolymerization Type: general – SubjectFull: Titanium dioxide Type: general – SubjectFull: Mechanical behavior of materials Type: general – SubjectFull: Polymeric nanocomposites Type: general – SubjectFull: Polymerization Type: general – SubjectFull: Photopolymers Type: general – SubjectFull: Surface preparation Type: general Titles: – TitleFull: Easy Synthesis of a Multifunctional Macrophotoinitiator with Pendant Moieties of Benzoin Methyl Ether Derivative for Use as Active Surface-Modifier of Inorganic Fillers. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Ohar, Halyna – PersonEntity: Name: NameFull: Tokareva, Maria – PersonEntity: Name: NameFull: Tokarev, Viktor IsPartOfRelationships: – BibEntity: Dates: – D: 15 M: 05 Text: May2026 Type: published Y: 2026 Identifiers: – Type: issn-print Value: 20734360 Numbering: – Type: volume Value: 18 – Type: issue Value: 10 Titles: – TitleFull: Polymers (20734360) Type: main |
| ResultId | 1 |
