Heteroatom engineering of carbon electrodes: Lithium-ion selective capacitive deionization.

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Title: Heteroatom engineering of carbon electrodes: Lithium-ion selective capacitive deionization.
Authors: Seffar, Yassine1 (AUTHOR), Burger, Peter R.2 (AUTHOR), Brzhezinskaya, Maria3 (AUTHOR), Dahbi, Mouad1 (AUTHOR) mouad.dahbi@um6p.ma, Presser, Volker1,2,4,5 (AUTHOR) volker.presser@leibniz-inm.de
Source: Desalination. Sep2026, Vol. 634, pN.PAG-N.PAG. 1p.
Subjects: Carbon electrodes, Doping agents (Chemistry), Electrolyte solutions, Saline water conversion, Adsorption capacity, Materials science, Boron
Abstract: The development of efficient carbon-based materials is crucial for overcoming the performance limitations of traditional electrodes in capacitive deionization (CDI). However, the practical performance of heteroatom-doped carbon electrodes for desalination in complex multi-ion water matrices remains largely unexplored. In this work, we studied the ion selectivity toward Li+ and the removal efficiency of nitrogen‑sulfur co-doped and boron-doped carbon electrodes in brackish water, using multi-salt cation solutions containing monovalent (Li+, Na+, K+) and divalent (Ca2+, Mg2+) ions. These modifications enhanced charge distribution, wettability, and ion diffusion within the electrodes. As a result, the N,S-AC electrode exhibited pronounced lithium selectivity in brackish water, while the B-AC electrode delivered higher adsorption capacity. The B-AC electrode achieved both high capacity and enhanced lithium selectivity even under strong competition from Na+, Mg2+, and Ca2+. These findings demonstrate the distinct and complementary roles of N,S-co-doping and B-doping, offering valuable insights into how heteroatom engineering can advance CDI performance. [ABSTRACT FROM AUTHOR]
Copyright of Desalination is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 194167966
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  Data: Heteroatom engineering of carbon electrodes: Lithium-ion selective capacitive deionization.
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  Data: <searchLink fieldCode="AR" term="%22Seffar%2C+Yassine%22">Seffar, Yassine</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Burger%2C+Peter+R%2E%22">Burger, Peter R.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Brzhezinskaya%2C+Maria%22">Brzhezinskaya, Maria</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Dahbi%2C+Mouad%22">Dahbi, Mouad</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> mouad.dahbi@um6p.ma</i><br /><searchLink fieldCode="AR" term="%22Presser%2C+Volker%22">Presser, Volker</searchLink><relatesTo>1,2,4,5</relatesTo> (AUTHOR)<i> volker.presser@leibniz-inm.de</i>
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  Data: <searchLink fieldCode="JN" term="%22Desalination%22">Desalination</searchLink>. Sep2026, Vol. 634, pN.PAG-N.PAG. 1p.
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  Data: <searchLink fieldCode="DE" term="%22Carbon+electrodes%22">Carbon electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Doping+agents+%28Chemistry%29%22">Doping agents (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Electrolyte+solutions%22">Electrolyte solutions</searchLink><br /><searchLink fieldCode="DE" term="%22Saline+water+conversion%22">Saline water conversion</searchLink><br /><searchLink fieldCode="DE" term="%22Adsorption+capacity%22">Adsorption capacity</searchLink><br /><searchLink fieldCode="DE" term="%22Materials+science%22">Materials science</searchLink><br /><searchLink fieldCode="DE" term="%22Boron%22">Boron</searchLink>
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  Label: Abstract
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  Data: The development of efficient carbon-based materials is crucial for overcoming the performance limitations of traditional electrodes in capacitive deionization (CDI). However, the practical performance of heteroatom-doped carbon electrodes for desalination in complex multi-ion water matrices remains largely unexplored. In this work, we studied the ion selectivity toward Li+ and the removal efficiency of nitrogen‑sulfur co-doped and boron-doped carbon electrodes in brackish water, using multi-salt cation solutions containing monovalent (Li+, Na+, K+) and divalent (Ca2+, Mg2+) ions. These modifications enhanced charge distribution, wettability, and ion diffusion within the electrodes. As a result, the N,S-AC electrode exhibited pronounced lithium selectivity in brackish water, while the B-AC electrode delivered higher adsorption capacity. The B-AC electrode achieved both high capacity and enhanced lithium selectivity even under strong competition from Na+, Mg2+, and Ca2+. These findings demonstrate the distinct and complementary roles of N,S-co-doping and B-doping, offering valuable insights into how heteroatom engineering can advance CDI performance. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Desalination is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
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      – Type: doi
        Value: 10.1016/j.desal.2026.120232
    Languages:
      – Code: eng
        Text: English
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      Pagination:
        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Carbon electrodes
        Type: general
      – SubjectFull: Doping agents (Chemistry)
        Type: general
      – SubjectFull: Electrolyte solutions
        Type: general
      – SubjectFull: Saline water conversion
        Type: general
      – SubjectFull: Adsorption capacity
        Type: general
      – SubjectFull: Materials science
        Type: general
      – SubjectFull: Boron
        Type: general
    Titles:
      – TitleFull: Heteroatom engineering of carbon electrodes: Lithium-ion selective capacitive deionization.
        Type: main
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          Name:
            NameFull: Seffar, Yassine
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            NameFull: Burger, Peter R.
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            NameFull: Brzhezinskaya, Maria
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            NameFull: Dahbi, Mouad
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            NameFull: Presser, Volker
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            – D: 15
              M: 09
              Text: Sep2026
              Type: published
              Y: 2026
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              Value: 634
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            – TitleFull: Desalination
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