Study on adsorptive removal of carmoisine azo dye from aqueous solution using the modification of activated carbon from rubber fruit shells and its magnetic composite.

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Title: Study on adsorptive removal of carmoisine azo dye from aqueous solution using the modification of activated carbon from rubber fruit shells and its magnetic composite.
Authors: Meena, Hari Mohan1 (AUTHOR) harimohanmeena@hrc.du.ac.in, Kukreti, Shrikant2 (AUTHOR), Jassal, P. S.3 (AUTHOR)
Source: Materials Research Innovations. Jun2026, Vol. 30 Issue 4, p357-382. 26p.
Subjects: Activated carbon, Composite materials, Biosorption, Fruit skins, Adsorption kinetics, Adsorption capacity, Azo dyes, Adsorption (Chemistry)
Abstract: A Carmoisine azo dye was removed through the modification of activated carbon from rubber fruit shells (AC-RFs) and its magnetic composite (MC). While adsorbents were synthesised using the co-precipitation method, the surface characteristics of activated carbon obtained from rubber fruit shells (AC-RFs) and magnetic composites (MC) were characterised using XRD, FTIR, XPS, TGA-DTA, DLS, VSM, UV-Visible, Raman spectra, HR-TEM, AFM, FE-SEM & EDAX, and SEM methods. In batch experimental mode, the ideal conditions for carmoisine azo dye uptake were a contact time of 180 min. temperature of 25°C, and pH 3 for the adsorbents AC-RFs and MC, respectively. The effect of surfactants, metals, and salt content on biosorption capacity was also examined. Kinetic studies showed that the pseudo-second-order kinetic model well followed the experimental data. Langmuir isotherm and Temkin isotherm showed well fit for AC-RFs/MC adsorbent, with the maximum adsorption capacity for AC-RFs/MC adsorbents being 2732.11 mg/g at 25°C. After 180 min. of dye agitation, a removal rate of close to 99.9% was examined. The findings showed that 30 mg of adsorbent, with 180 min. and a pH range of 2–4 was the optimum condition for maximum dye removal efficiency onto AC-RFs/MC. A thermodynamic study on carmoisine azo dye showed endothermic and consistent biosorption onto AC-RFs and MC. The study examined the effect of bed height and concentration under a constant flow rate. Kinetic models BDST (bed depth service time) and Thomas were utilised using column experimental data. This research indicates that magnetic biocomposites synthesised from activated carbon from rubber fruit shell biomass exhibit significant adsorbent properties for the removal of carmoisine azo dye from aqueous solutions. [ABSTRACT FROM AUTHOR]
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  Label: Title
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  Data: Study on adsorptive removal of carmoisine azo dye from aqueous solution using the modification of activated carbon from rubber fruit shells and its magnetic composite.
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  Data: <searchLink fieldCode="AR" term="%22Meena%2C+Hari+Mohan%22">Meena, Hari Mohan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> harimohanmeena@hrc.du.ac.in</i><br /><searchLink fieldCode="AR" term="%22Kukreti%2C+Shrikant%22">Kukreti, Shrikant</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jassal%2C+P%2E+S%2E%22">Jassal, P. S.</searchLink><relatesTo>3</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Materials+Research+Innovations%22">Materials Research Innovations</searchLink>. Jun2026, Vol. 30 Issue 4, p357-382. 26p.
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  Data: <searchLink fieldCode="DE" term="%22Activated+carbon%22">Activated carbon</searchLink><br /><searchLink fieldCode="DE" term="%22Composite+materials%22">Composite materials</searchLink><br /><searchLink fieldCode="DE" term="%22Biosorption%22">Biosorption</searchLink><br /><searchLink fieldCode="DE" term="%22Fruit+skins%22">Fruit skins</searchLink><br /><searchLink fieldCode="DE" term="%22Adsorption+kinetics%22">Adsorption kinetics</searchLink><br /><searchLink fieldCode="DE" term="%22Adsorption+capacity%22">Adsorption capacity</searchLink><br /><searchLink fieldCode="DE" term="%22Azo+dyes%22">Azo dyes</searchLink><br /><searchLink fieldCode="DE" term="%22Adsorption+%28Chemistry%29%22">Adsorption (Chemistry)</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A Carmoisine azo dye was removed through the modification of activated carbon from rubber fruit shells (AC-RFs) and its magnetic composite (MC). While adsorbents were synthesised using the co-precipitation method, the surface characteristics of activated carbon obtained from rubber fruit shells (AC-RFs) and magnetic composites (MC) were characterised using XRD, FTIR, XPS, TGA-DTA, DLS, VSM, UV-Visible, Raman spectra, HR-TEM, AFM, FE-SEM & EDAX, and SEM methods. In batch experimental mode, the ideal conditions for carmoisine azo dye uptake were a contact time of 180 min. temperature of 25°C, and pH 3 for the adsorbents AC-RFs and MC, respectively. The effect of surfactants, metals, and salt content on biosorption capacity was also examined. Kinetic studies showed that the pseudo-second-order kinetic model well followed the experimental data. Langmuir isotherm and Temkin isotherm showed well fit for AC-RFs/MC adsorbent, with the maximum adsorption capacity for AC-RFs/MC adsorbents being 2732.11 mg/g at 25°C. After 180 min. of dye agitation, a removal rate of close to 99.9% was examined. The findings showed that 30 mg of adsorbent, with 180 min. and a pH range of 2–4 was the optimum condition for maximum dye removal efficiency onto AC-RFs/MC. A thermodynamic study on carmoisine azo dye showed endothermic and consistent biosorption onto AC-RFs and MC. The study examined the effect of bed height and concentration under a constant flow rate. Kinetic models BDST (bed depth service time) and Thomas were utilised using column experimental data. This research indicates that magnetic biocomposites synthesised from activated carbon from rubber fruit shell biomass exhibit significant adsorbent properties for the removal of carmoisine azo dye from aqueous solutions. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Materials Research Innovations is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1080/14328917.2025.2600256
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 26
        StartPage: 357
    Subjects:
      – SubjectFull: Activated carbon
        Type: general
      – SubjectFull: Composite materials
        Type: general
      – SubjectFull: Biosorption
        Type: general
      – SubjectFull: Fruit skins
        Type: general
      – SubjectFull: Adsorption kinetics
        Type: general
      – SubjectFull: Adsorption capacity
        Type: general
      – SubjectFull: Azo dyes
        Type: general
      – SubjectFull: Adsorption (Chemistry)
        Type: general
    Titles:
      – TitleFull: Study on adsorptive removal of carmoisine azo dye from aqueous solution using the modification of activated carbon from rubber fruit shells and its magnetic composite.
        Type: main
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      – PersonEntity:
          Name:
            NameFull: Meena, Hari Mohan
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            NameFull: Kukreti, Shrikant
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            NameFull: Jassal, P. S.
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            – D: 01
              M: 06
              Text: Jun2026
              Type: published
              Y: 2026
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              Value: 30
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            – TitleFull: Materials Research Innovations
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