Effect of compositions and processing parameters on eutectoid reaction in AlCoFeNi multi-component alloys.

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Title: Effect of compositions and processing parameters on eutectoid reaction in AlCoFeNi multi-component alloys.
Authors: Mazullah1,2 (AUTHOR), Ismail, Muhammad1 (AUTHOR), Zhang, Ke3 (AUTHOR) huzhude@yeah.net, Zhu, Haofei4 (AUTHOR), Noreen, Iqra1 (AUTHOR), Ahmad, Hammad5 (AUTHOR), Xiong, Zhiping1,2 (AUTHOR) zpxiong@bit.edu.cn
Source: Journal of Materials Science. Jul2026, Vol. 61 Issue 28, p20367-20391. 25p.
Subjects: Phase transitions, Microstructure, Activation energy, Tensile strength, High-entropy alloys
Abstract: Suitable chemical compositions for lamellar microstructures (LMs) via eutectoid reaction in multi-component alloys (MCAs) is a challenging task. This study employed Thermo-Calc (TCHEA3 database) to calculate phase diagrams by systematically varying Al, Co, Fe and Ni content within the AlCoFeNi system. Based on these calculations, selected compositions were arc-melted and thoroughly investigated for the optimal chemical compositions, initial phase microstructures and phase transformation to LMs. The optimal compositions of MCAs for LMs were determined to be Al7(CoFeNi)93 and Al10(CoFeNi1.5)90 at.%, which are in single face centered cubic (FCC) phase. SEM analysis confirmed that aging the solid-solution MCAs at 500–600 °C induces LMs transformation. For the Al7(CoFeNi)93 MCA, aging at 500, 560, and 600 °C yielded LMs spacings of 75 ± 13 nm, 138 ± 29 nm, and 364 ± 102 nm, respectively; under the same conditions, the Al13(CoFeNi)87 MCA gave spacings of 103 ± 51 nm, 188 ± 18 nm, and 347 ± 51 nm. The tensile properties of Al7(CoFeNi)93 MCA were governed aging temperatures transforming the FCC phase into LMs. Aging at 500 and 560 °C increased strength (YS: 414–620 MPa; UTS: 493–799 MPa) but reduced ductility (UE: 0.94–0.50%). Aging at 600 °C (24 h, WQ) provide balanced tensile properties (UTS: 603 MPa; UE: 29.12%). Aging for 48 h gives enhanced strength (749 MPa) at the cost of ductility (4.60%). Furthermore, Johnson–Mehl–Avrami-Kolmogorov (JMAK) analysis at 560 °C yielded transformation kinetics parameters (n, k) of (1.08, 0.028) for Al7(CoFeNi)93 MCA and (1.47, 0.15) for Al13(CoFeNi)90 MCA. The corresponding activation energies for the eutectoid LMs determined via the Arrhenius model, are 199.71 and 268 kJ/mol. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Effect of compositions and processing parameters on eutectoid reaction in AlCoFeNi multi-component alloys.
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  Data: <searchLink fieldCode="AR" term="%22Mazullah%22">Mazullah</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ismail%2C+Muhammad%22">Ismail, Muhammad</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Ke%22">Zhang, Ke</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> huzhude@yeah.net</i><br /><searchLink fieldCode="AR" term="%22Zhu%2C+Haofei%22">Zhu, Haofei</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Noreen%2C+Iqra%22">Noreen, Iqra</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ahmad%2C+Hammad%22">Ahmad, Hammad</searchLink><relatesTo>5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xiong%2C+Zhiping%22">Xiong, Zhiping</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> zpxiong@bit.edu.cn</i>
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  Data: <searchLink fieldCode="DE" term="%22Phase+transitions%22">Phase transitions</searchLink><br /><searchLink fieldCode="DE" term="%22Microstructure%22">Microstructure</searchLink><br /><searchLink fieldCode="DE" term="%22Activation+energy%22">Activation energy</searchLink><br /><searchLink fieldCode="DE" term="%22Tensile+strength%22">Tensile strength</searchLink><br /><searchLink fieldCode="DE" term="%22High-entropy+alloys%22">High-entropy alloys</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Suitable chemical compositions for lamellar microstructures (LMs) via eutectoid reaction in multi-component alloys (MCAs) is a challenging task. This study employed Thermo-Calc (TCHEA3 database) to calculate phase diagrams by systematically varying Al, Co, Fe and Ni content within the AlCoFeNi system. Based on these calculations, selected compositions were arc-melted and thoroughly investigated for the optimal chemical compositions, initial phase microstructures and phase transformation to LMs. The optimal compositions of MCAs for LMs were determined to be Al7(CoFeNi)93 and Al10(CoFeNi1.5)90 at.%, which are in single face centered cubic (FCC) phase. SEM analysis confirmed that aging the solid-solution MCAs at 500–600 °C induces LMs transformation. For the Al7(CoFeNi)93 MCA, aging at 500, 560, and 600 °C yielded LMs spacings of 75 ± 13 nm, 138 ± 29 nm, and 364 ± 102 nm, respectively; under the same conditions, the Al13(CoFeNi)87 MCA gave spacings of 103 ± 51 nm, 188 ± 18 nm, and 347 ± 51 nm. The tensile properties of Al7(CoFeNi)93 MCA were governed aging temperatures transforming the FCC phase into LMs. Aging at 500 and 560 °C increased strength (YS: 414–620 MPa; UTS: 493–799 MPa) but reduced ductility (UE: 0.94–0.50%). Aging at 600 °C (24 h, WQ) provide balanced tensile properties (UTS: 603 MPa; UE: 29.12%). Aging for 48 h gives enhanced strength (749 MPa) at the cost of ductility (4.60%). Furthermore, Johnson–Mehl–Avrami-Kolmogorov (JMAK) analysis at 560 °C yielded transformation kinetics parameters (n, k) of (1.08, 0.028) for Al7(CoFeNi)93 MCA and (1.47, 0.15) for Al13(CoFeNi)90 MCA. The corresponding activation energies for the eutectoid LMs determined via the Arrhenius model, are 199.71 and 268 kJ/mol. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1007/s10853-026-12997-1
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      – Code: eng
        Text: English
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        PageCount: 25
        StartPage: 20367
    Subjects:
      – SubjectFull: Phase transitions
        Type: general
      – SubjectFull: Microstructure
        Type: general
      – SubjectFull: Activation energy
        Type: general
      – SubjectFull: Tensile strength
        Type: general
      – SubjectFull: High-entropy alloys
        Type: general
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      – TitleFull: Effect of compositions and processing parameters on eutectoid reaction in AlCoFeNi multi-component alloys.
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            NameFull: Mazullah
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            NameFull: Ismail, Muhammad
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            NameFull: Zhang, Ke
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            NameFull: Ahmad, Hammad
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            – D: 22
              M: 07
              Text: Jul2026
              Type: published
              Y: 2026
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