Facile Preparation of a Plasmon-Enhanced Ag-CuO/TiO 2 for the Efficient Visible-Light-Driven Photodegradation of Tetracycline Hydrochloride.
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| Title: | Facile Preparation of a Plasmon-Enhanced Ag-CuO/TiO 2 for the Efficient Visible-Light-Driven Photodegradation of Tetracycline Hydrochloride. |
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| Authors: | Cui, Lianmin1 (AUTHOR), Ren, Li1 (AUTHOR), Chen, Zhi1 (AUTHOR), Zhu, Benfeng1 (AUTHOR), Xu, Chen1 (AUTHOR), Wei, Guoying1 (AUTHOR) |
| Source: | Materials (1996-1944). Jun2026, Vol. 19 Issue 11, p2189. 18p. |
| Subjects: | Photocatalysts, Photodegradation, Photocatalysis, Organic compounds removal (Sewage purification), Water pollution |
| Abstract: | Water pollution caused by antibiotics is a growing problem. Therefore, photodegradation by efficient catalysts is an environmentally friendly technology that can effectively degrade organic pollutants in water. In this work, a method was innovatively used to prepare a ternary heterostructure of plasmon-enhanced Ag-CuO/TiO2. The composite was synthesized through a facile stepwise strategy involving the formation of CuO nanorods, TiO2 coating, and subsequent deposition of Ag nanoparticles on their surface using AgNO3, enabling intimate interfacial contact among the different components. The prepared samples were characterized by XRD, HRTEM, XPS, and UV-Vis. The chemical composition of the composite Ag-CuO/TiO2 showed a Cu/Ti atomic ratio of 2.58, as well as a Ag/Cu ratio of 0.91. The UV-Vis spectrum reveals the largest absorption peak at 550 nm for the composite Ag-CuO/TiO2. The prepared Ag-CuO/TiO2 composites were applied to the visible-light degradation of tetracycline hydrochloride, with the photocatalytic degradation rate reaching 80.7% under the optimal conditions within 60 min, which is significantly better than CuO and CuO/TiO2 without silver nanoparticles. Capture experiments indicated that h+ are involved during the course of the photodegradation and that h+ are the main active substances. Furthermore, the proposed mechanism for the photodegradation of the Ag-CuO/TiO2 composites is given. It has potential applications in the treatment of organic pollutants in water. [ABSTRACT FROM AUTHOR] |
| Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 194587100 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Facile Preparation of a Plasmon-Enhanced Ag-CuO/TiO 2 for the Efficient Visible-Light-Driven Photodegradation of Tetracycline Hydrochloride. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Cui%2C+Lianmin%22">Cui, Lianmin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ren%2C+Li%22">Ren, Li</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Chen%2C+Zhi%22">Chen, Zhi</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhu%2C+Benfeng%22">Zhu, Benfeng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xu%2C+Chen%22">Xu, Chen</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wei%2C+Guoying%22">Wei, Guoying</searchLink><relatesTo>1</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Materials+%281996-1944%29%22">Materials (1996-1944)</searchLink>. Jun2026, Vol. 19 Issue 11, p2189. 18p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Photocatalysts%22">Photocatalysts</searchLink><br /><searchLink fieldCode="DE" term="%22Photodegradation%22">Photodegradation</searchLink><br /><searchLink fieldCode="DE" term="%22Photocatalysis%22">Photocatalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+compounds+removal+%28Sewage+purification%29%22">Organic compounds removal (Sewage purification)</searchLink><br /><searchLink fieldCode="DE" term="%22Water+pollution%22">Water pollution</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Water pollution caused by antibiotics is a growing problem. Therefore, photodegradation by efficient catalysts is an environmentally friendly technology that can effectively degrade organic pollutants in water. In this work, a method was innovatively used to prepare a ternary heterostructure of plasmon-enhanced Ag-CuO/TiO2. The composite was synthesized through a facile stepwise strategy involving the formation of CuO nanorods, TiO2 coating, and subsequent deposition of Ag nanoparticles on their surface using AgNO3, enabling intimate interfacial contact among the different components. The prepared samples were characterized by XRD, HRTEM, XPS, and UV-Vis. The chemical composition of the composite Ag-CuO/TiO2 showed a Cu/Ti atomic ratio of 2.58, as well as a Ag/Cu ratio of 0.91. The UV-Vis spectrum reveals the largest absorption peak at 550 nm for the composite Ag-CuO/TiO2. The prepared Ag-CuO/TiO2 composites were applied to the visible-light degradation of tetracycline hydrochloride, with the photocatalytic degradation rate reaching 80.7% under the optimal conditions within 60 min, which is significantly better than CuO and CuO/TiO2 without silver nanoparticles. Capture experiments indicated that h+ are involved during the course of the photodegradation and that h+ are the main active substances. Furthermore, the proposed mechanism for the photodegradation of the Ag-CuO/TiO2 composites is given. It has potential applications in the treatment of organic pollutants in water. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.3390/ma19112189 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 18 StartPage: 2189 Subjects: – SubjectFull: Photocatalysts Type: general – SubjectFull: Photodegradation Type: general – SubjectFull: Photocatalysis Type: general – SubjectFull: Organic compounds removal (Sewage purification) Type: general – SubjectFull: Water pollution Type: general Titles: – TitleFull: Facile Preparation of a Plasmon-Enhanced Ag-CuO/TiO 2 for the Efficient Visible-Light-Driven Photodegradation of Tetracycline Hydrochloride. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Cui, Lianmin – PersonEntity: Name: NameFull: Ren, Li – PersonEntity: Name: NameFull: Chen, Zhi – PersonEntity: Name: NameFull: Zhu, Benfeng – PersonEntity: Name: NameFull: Xu, Chen – PersonEntity: Name: NameFull: Wei, Guoying IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 06 Text: Jun2026 Type: published Y: 2026 Identifiers: – Type: issn-print Value: 19961944 Numbering: – Type: volume Value: 19 – Type: issue Value: 11 Titles: – TitleFull: Materials (1996-1944) Type: main |
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