Three-Dimensional Electro-Fenton System with CuFe 2 O 4 -Loaded Granular Activated Carbon as the Catalytic Particle Electrode for Removal of Bisphenol A.

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Title: Three-Dimensional Electro-Fenton System with CuFe 2 O 4 -Loaded Granular Activated Carbon as the Catalytic Particle Electrode for Removal of Bisphenol A.
Authors: Tao, Sheng1,2 (AUTHOR), Luo, Zhang2,3 (AUTHOR), Kong, Defeng3,4 (AUTHOR), Chai, Yifan1,2,4 (AUTHOR), Kuai, Shenglong5 (AUTHOR), Liu, Huilai5 (AUTHOR), Yin, Cheng5 (AUTHOR), Chen, Xing1,2 (AUTHOR) xingchen@hfut.edu.cn
Source: Nanomaterials (2079-4991). Jun2026, Vol. 16 Issue 12, p722. 18p.
Subjects: Bisphenol A, Granular activated carbon, Environmental remediation, Bimetallic catalysts, Endocrine disruptors, Hydroxyl group, Electrodes
Abstract: Bisphenol A (BPA) is a typical endocrine disruptor that poses a significant threat to ecosystems. Therefore, it is crucial to develop an efficient and environmentally friendly degradation technology. In this study, a novel bimetallic oxide-loaded GAC (Granulated Activated Carbon) particle electrode (CuFe2O4@GAC) was designed and applied to a three-dimensional electro-Fenton (3D-EF) system for efficient removal of BPA. The bimetallic synergistic effect of Cu and Fe was used to promote the Fenton reaction and enhance the efficiency of hydroxyl radical ·OH generation. The results show that under conditions of 20 g/L CuFe2O4@GAC, pH = 3, 10 mA/cm2, and an electrode spacing of 2.0 cm, a BPA removal rate of over 93% (20 mg/L) was achieved within 45 min. The prepared CuFe2O4@GAC exhibits good stability, maintaining an 86.2% BPA degradation rate over five cycle experiments. The catalytic mechanism and degradation pathways were further analyzed through characterization methods such as radical quenching experiments, XPS analysis, EPR, and LC-MS detection. Radical quenching experiments confirmed that ·OH radicals play a significant role in the decomposition of BPA. Based on the identification of intermediates, a possible decomposition pathway for BPA was proposed. Toxicity analysis indicated that the toxicity of most intermediates was significantly lower than that of BPA. This work provides an efficient and energy-saving strategy for BPA removal. [ABSTRACT FROM AUTHOR]
Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Three-Dimensional Electro-Fenton System with CuFe 2 O 4 -Loaded Granular Activated Carbon as the Catalytic Particle Electrode for Removal of Bisphenol A.
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  Data: <searchLink fieldCode="AR" term="%22Tao%2C+Sheng%22">Tao, Sheng</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Luo%2C+Zhang%22">Luo, Zhang</searchLink><relatesTo>2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Kong%2C+Defeng%22">Kong, Defeng</searchLink><relatesTo>3,4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Chai%2C+Yifan%22">Chai, Yifan</searchLink><relatesTo>1,2,4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Kuai%2C+Shenglong%22">Kuai, Shenglong</searchLink><relatesTo>5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Liu%2C+Huilai%22">Liu, Huilai</searchLink><relatesTo>5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yin%2C+Cheng%22">Yin, Cheng</searchLink><relatesTo>5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Chen%2C+Xing%22">Chen, Xing</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> xingchen@hfut.edu.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Nanomaterials+%282079-4991%29%22">Nanomaterials (2079-4991)</searchLink>. Jun2026, Vol. 16 Issue 12, p722. 18p.
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  Data: <searchLink fieldCode="DE" term="%22Bisphenol+A%22">Bisphenol A</searchLink><br /><searchLink fieldCode="DE" term="%22Granular+activated+carbon%22">Granular activated carbon</searchLink><br /><searchLink fieldCode="DE" term="%22Environmental+remediation%22">Environmental remediation</searchLink><br /><searchLink fieldCode="DE" term="%22Bimetallic+catalysts%22">Bimetallic catalysts</searchLink><br /><searchLink fieldCode="DE" term="%22Endocrine+disruptors%22">Endocrine disruptors</searchLink><br /><searchLink fieldCode="DE" term="%22Hydroxyl+group%22">Hydroxyl group</searchLink><br /><searchLink fieldCode="DE" term="%22Electrodes%22">Electrodes</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Bisphenol A (BPA) is a typical endocrine disruptor that poses a significant threat to ecosystems. Therefore, it is crucial to develop an efficient and environmentally friendly degradation technology. In this study, a novel bimetallic oxide-loaded GAC (Granulated Activated Carbon) particle electrode (CuFe2O4@GAC) was designed and applied to a three-dimensional electro-Fenton (3D-EF) system for efficient removal of BPA. The bimetallic synergistic effect of Cu and Fe was used to promote the Fenton reaction and enhance the efficiency of hydroxyl radical ·OH generation. The results show that under conditions of 20 g/L CuFe2O4@GAC, pH = 3, 10 mA/cm2, and an electrode spacing of 2.0 cm, a BPA removal rate of over 93% (20 mg/L) was achieved within 45 min. The prepared CuFe2O4@GAC exhibits good stability, maintaining an 86.2% BPA degradation rate over five cycle experiments. The catalytic mechanism and degradation pathways were further analyzed through characterization methods such as radical quenching experiments, XPS analysis, EPR, and LC-MS detection. Radical quenching experiments confirmed that ·OH radicals play a significant role in the decomposition of BPA. Based on the identification of intermediates, a possible decomposition pathway for BPA was proposed. Toxicity analysis indicated that the toxicity of most intermediates was significantly lower than that of BPA. This work provides an efficient and energy-saving strategy for BPA removal. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/nano16120722
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      – Code: eng
        Text: English
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        PageCount: 18
        StartPage: 722
    Subjects:
      – SubjectFull: Bisphenol A
        Type: general
      – SubjectFull: Granular activated carbon
        Type: general
      – SubjectFull: Environmental remediation
        Type: general
      – SubjectFull: Bimetallic catalysts
        Type: general
      – SubjectFull: Endocrine disruptors
        Type: general
      – SubjectFull: Hydroxyl group
        Type: general
      – SubjectFull: Electrodes
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      – TitleFull: Three-Dimensional Electro-Fenton System with CuFe 2 O 4 -Loaded Granular Activated Carbon as the Catalytic Particle Electrode for Removal of Bisphenol A.
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            NameFull: Tao, Sheng
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              M: 06
              Text: Jun2026
              Type: published
              Y: 2026
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