Microstructure and Mechanical Properties of a Ti-Al-Mo-V-Cr-Sn-Zr Titanium Alloy via Double-Annealing Heat Treatment.

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Title: Microstructure and Mechanical Properties of a Ti-Al-Mo-V-Cr-Sn-Zr Titanium Alloy via Double-Annealing Heat Treatment.
Authors: Shu, Jinfeng1,2 (AUTHOR), Qu, Bao2 (AUTHOR), Ma, Yingjie3 (AUTHOR), Li, Kang1,2 (AUTHOR), Hao, Fang2 (AUTHOR), Zhao, Ning2,3 (AUTHOR), Ju, Biao2 (AUTHOR), Ren, Yong2 (AUTHOR), Yang, Jing2 (AUTHOR), Wang, Tao2 (AUTHOR), Lei, Jinwen2 (AUTHOR), Liu, Xianghong1,2 (AUTHOR)
Source: Materials (1996-1944). Jun2026, Vol. 19 Issue 12, p2553. 17p.
Subjects: Heat treatment, Microstructure, Titanium alloys, Tensile strength, Solid-state phase transformations, Aerospace materials, Mechanical behavior of materials
Abstract: Achieving a favorable synergy of strength, ductility, and toughness is a critical challenge for expanding the engineering applications of titanium alloys. In this work, a medium-strength and high-toughness novel Ti-Al-Mo-V-Cr-Sn-Zr (named Ti62F) titanium alloy in the form of a Φ400 mm bar was adopted to systematically investigate the regulation behavior of double annealing on its microstructure and mechanical properties, and quantitative correlations between microstructural parameters and macroscopic properties were established. Increasing the cooling rate during the first annealing stage (air cooling, force air cooling and water quenching) significantly refined the secondary α (αs) phase and reduced the volume fraction and size of the primary α (αp) phase, leading to an increase in the ultimate tensile strength of the alloy from 1077 MPa to 1229 MPa. However, the impact-absorbed energy decreased from 51.5 J to 23.3 J. When the second annealing temperature was varied within the range of 625–675 °C, the ultimate tensile strength fluctuated slightly and the impact toughness increased moderately. Equiaxed αp phase and relatively thick αs can induce multiple crack deflections, prolong the crack propagation path and enhance energy absorption. Dislocations are mainly piled up at α/β phase boundaries, triggering void nucleation and growth, which dominate the ductility and toughness levels. Tensile twinning acts only as an auxiliary deformation mechanism and contributes limitedly to toughness. After heat treatment under the optimized schedule of 880 °C/2 h/AC + 650 °C/4 h/AC, the Ti62F alloy exhibits a superior strength–toughness balance compared with conventional medium-strength titanium alloys such as TA15, TC4, and TC4-DT. The findings can provide a heat treatment basis for microstructural regulation of large-size Ti62F bars and their engineering applications in aerospace structural components. [ABSTRACT FROM AUTHOR]
Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Microstructure and Mechanical Properties of a Ti-Al-Mo-V-Cr-Sn-Zr Titanium Alloy via Double-Annealing Heat Treatment.
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  Data: Achieving a favorable synergy of strength, ductility, and toughness is a critical challenge for expanding the engineering applications of titanium alloys. In this work, a medium-strength and high-toughness novel Ti-Al-Mo-V-Cr-Sn-Zr (named Ti62F) titanium alloy in the form of a Φ400 mm bar was adopted to systematically investigate the regulation behavior of double annealing on its microstructure and mechanical properties, and quantitative correlations between microstructural parameters and macroscopic properties were established. Increasing the cooling rate during the first annealing stage (air cooling, force air cooling and water quenching) significantly refined the secondary α (αs) phase and reduced the volume fraction and size of the primary α (αp) phase, leading to an increase in the ultimate tensile strength of the alloy from 1077 MPa to 1229 MPa. However, the impact-absorbed energy decreased from 51.5 J to 23.3 J. When the second annealing temperature was varied within the range of 625–675 °C, the ultimate tensile strength fluctuated slightly and the impact toughness increased moderately. Equiaxed αp phase and relatively thick αs can induce multiple crack deflections, prolong the crack propagation path and enhance energy absorption. Dislocations are mainly piled up at α/β phase boundaries, triggering void nucleation and growth, which dominate the ductility and toughness levels. Tensile twinning acts only as an auxiliary deformation mechanism and contributes limitedly to toughness. After heat treatment under the optimized schedule of 880 °C/2 h/AC + 650 °C/4 h/AC, the Ti62F alloy exhibits a superior strength–toughness balance compared with conventional medium-strength titanium alloys such as TA15, TC4, and TC4-DT. The findings can provide a heat treatment basis for microstructural regulation of large-size Ti62F bars and their engineering applications in aerospace structural components. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/ma19122553
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        Text: English
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        PageCount: 17
        StartPage: 2553
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      – SubjectFull: Microstructure
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      – SubjectFull: Titanium alloys
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      – SubjectFull: Tensile strength
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      – SubjectFull: Solid-state phase transformations
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      – SubjectFull: Mechanical behavior of materials
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              Text: Jun2026
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              Y: 2026
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