Biodegradable Polyester–Starch Composite Films Functionalized with Phenolic Compounds: Advances, Challenges, and Prospects for Sustainable Active Packaging.

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Title: Biodegradable Polyester–Starch Composite Films Functionalized with Phenolic Compounds: Advances, Challenges, and Prospects for Sustainable Active Packaging.
Authors: Shin, Bongsoo1,2 (AUTHOR), Singh, Ajit Kumar1,2 (AUTHOR) nattinee.bu@ku.ac.th, Bumbudsanpharoke, Nattinee3 (AUTHOR), Ko, Seonghyuk1 (AUTHOR) s.ko@yonsei.ac.kr
Source: Polymers (20734360). Jun2026, Vol. 18 Issue 12, p1437. 34p.
Subjects: Active food packaging, Biodegradable materials, Polylactic acid, Controlled release preparations, Antibacterial agents, Phenols, Compostable materials
Abstract: The growing demand for sustainable food packaging has intensified interest in biodegradable materials that can reduce environmental impact while preserving food quality. Among these materials, biodegradable polyester–starch composite films functionalized with phenolic compounds have gained attention as promising active packaging systems. They combine the melt processability and structural stability of polyesters, such as poly(lactic acid) (PLA), poly(butylene adipate-co-terephthalate) (PBAT), poly(butylene succinate) (PBS), and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) with the renewability and biodegradability of starch and the antioxidant, antimicrobial, and UV-protective functions of phenolics, such as ferulic acid, quercetin, tea polyphenols, and anthocyanins. This review discusses recent advances in the selection of biodegradable polyesters, starch and thermoplastic starch blending, phenolic incorporation strategies, and their effects on compatibility, morphology, mechanical strength, barrier properties, optical behavior, release, and active packaging functionality. The characteristics and functionality of these films are governed not only by the individual components but also by phase morphology, interfacial interactions, phenolic location, processing conditions, and release control. Key challenges include polyester–starch incompatibility, TPS moisture sensitivity, phenolic stability during melt processing, migration safety, controlled release, and industrial scale-up. Collectively, biodegradable polyester–starch films functionalized with phenolic compounds represent a promising route for developing next-generation sustainable active packaging and may contribute to circular economy approaches. [ABSTRACT FROM AUTHOR]
Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Biodegradable Polyester–Starch Composite Films Functionalized with Phenolic Compounds: Advances, Challenges, and Prospects for Sustainable Active Packaging.
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  Data: <searchLink fieldCode="JN" term="%22Polymers+%2820734360%29%22">Polymers (20734360)</searchLink>. Jun2026, Vol. 18 Issue 12, p1437. 34p.
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  Data: <searchLink fieldCode="DE" term="%22Active+food+packaging%22">Active food packaging</searchLink><br /><searchLink fieldCode="DE" term="%22Biodegradable+materials%22">Biodegradable materials</searchLink><br /><searchLink fieldCode="DE" term="%22Polylactic+acid%22">Polylactic acid</searchLink><br /><searchLink fieldCode="DE" term="%22Controlled+release+preparations%22">Controlled release preparations</searchLink><br /><searchLink fieldCode="DE" term="%22Antibacterial+agents%22">Antibacterial agents</searchLink><br /><searchLink fieldCode="DE" term="%22Phenols%22">Phenols</searchLink><br /><searchLink fieldCode="DE" term="%22Compostable+materials%22">Compostable materials</searchLink>
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  Label: Abstract
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  Data: The growing demand for sustainable food packaging has intensified interest in biodegradable materials that can reduce environmental impact while preserving food quality. Among these materials, biodegradable polyester–starch composite films functionalized with phenolic compounds have gained attention as promising active packaging systems. They combine the melt processability and structural stability of polyesters, such as poly(lactic acid) (PLA), poly(butylene adipate-co-terephthalate) (PBAT), poly(butylene succinate) (PBS), and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) with the renewability and biodegradability of starch and the antioxidant, antimicrobial, and UV-protective functions of phenolics, such as ferulic acid, quercetin, tea polyphenols, and anthocyanins. This review discusses recent advances in the selection of biodegradable polyesters, starch and thermoplastic starch blending, phenolic incorporation strategies, and their effects on compatibility, morphology, mechanical strength, barrier properties, optical behavior, release, and active packaging functionality. The characteristics and functionality of these films are governed not only by the individual components but also by phase morphology, interfacial interactions, phenolic location, processing conditions, and release control. Key challenges include polyester–starch incompatibility, TPS moisture sensitivity, phenolic stability during melt processing, migration safety, controlled release, and industrial scale-up. Collectively, biodegradable polyester–starch films functionalized with phenolic compounds represent a promising route for developing next-generation sustainable active packaging and may contribute to circular economy approaches. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.3390/polym18121437
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      – Code: eng
        Text: English
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        PageCount: 34
        StartPage: 1437
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        Type: general
      – SubjectFull: Biodegradable materials
        Type: general
      – SubjectFull: Polylactic acid
        Type: general
      – SubjectFull: Controlled release preparations
        Type: general
      – SubjectFull: Antibacterial agents
        Type: general
      – SubjectFull: Phenols
        Type: general
      – SubjectFull: Compostable materials
        Type: general
    Titles:
      – TitleFull: Biodegradable Polyester–Starch Composite Films Functionalized with Phenolic Compounds: Advances, Challenges, and Prospects for Sustainable Active Packaging.
        Type: main
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          Name:
            NameFull: Shin, Bongsoo
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            NameFull: Singh, Ajit Kumar
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            NameFull: Bumbudsanpharoke, Nattinee
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            NameFull: Ko, Seonghyuk
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            – D: 15
              M: 06
              Text: Jun2026
              Type: published
              Y: 2026
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