Programming Failure Mode Transitions in Polyurea-Reinforced 3D-Printed ABS and PA-GF Cellular Metamaterial Composites.

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Title: Programming Failure Mode Transitions in Polyurea-Reinforced 3D-Printed ABS and PA-GF Cellular Metamaterial Composites.
Authors: Valle, Rodrigo1 (AUTHOR), Garrido, César2 (AUTHOR), Tuninetti, Víctor3 (AUTHOR) victor.tuninetti@ufrontera.cl
Source: Polymers (20734360). Jun2026, Vol. 18 Issue 12, p1466. 26p.
Subjects: Structural failures, Energy dissipation, Metamaterials, Acrylonitrile butadiene styrene resins, Glass-reinforced plastics, Flexural strength testing, Polymers, Three-dimensional printing
Abstract: Additively manufactured cellular architectures frequently exhibit brittle failure under impact due to layer-induced stress concentrations. Through the programming of architectural and material design, specifically combining Fused Deposition Modeling (FDM) lattice topology with hyperelastic polyurea infiltration, this study achieves active control over the macroscopic transition from catastrophic structural fragmentation to stable progressive collapse. To evaluate this, auxetic and honeycomb specimens printed with ABS and glass-fiber-reinforced polyamide (PA-GF) were evaluated in unreinforced and polyurea-infiltrated states under quasi-static compression, three-point bending, and Charpy impact loading. Results show that the compressive response depends primarily on cellular topology; the pure auxetic (A-A) configuration provided the highest stiffness and energy absorption. Polyurea infiltration did not significantly alter elastic stiffness but increased post-yield stability, leading to a 96.6% elastic recovery in PA-GF A-A structures. In flexure, the base polymer governed stiffness, with ABS structures measuring 68% stiffer than PA-GF. Unreinforced ABS achieved 34% higher specific energy absorption (SEA) than PA-GF under compression, with the A-H topology maximizing SEA. Under dynamic impact, PA-GF absorbed an average of 70% more energy than ABS, and the H-A configuration recorded the highest impact resistance. The addition of polyurea shifted the failure mode from brittle fragmentation to stable elastomeric deformation, increasing absorbed impact energy by 52% for ABS and over 30% for PA-GF, preventing catastrophic structural failure. Integrating topological sequencing with elastomeric confinement provides a direct method to control energy dissipation and damage tolerance in 3D-printed cellular composites. [ABSTRACT FROM AUTHOR]
Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Programming Failure Mode Transitions in Polyurea-Reinforced 3D-Printed ABS and PA-GF Cellular Metamaterial Composites.
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  Data: <searchLink fieldCode="DE" term="%22Structural+failures%22">Structural failures</searchLink><br /><searchLink fieldCode="DE" term="%22Energy+dissipation%22">Energy dissipation</searchLink><br /><searchLink fieldCode="DE" term="%22Metamaterials%22">Metamaterials</searchLink><br /><searchLink fieldCode="DE" term="%22Acrylonitrile+butadiene+styrene+resins%22">Acrylonitrile butadiene styrene resins</searchLink><br /><searchLink fieldCode="DE" term="%22Glass-reinforced+plastics%22">Glass-reinforced plastics</searchLink><br /><searchLink fieldCode="DE" term="%22Flexural+strength+testing%22">Flexural strength testing</searchLink><br /><searchLink fieldCode="DE" term="%22Polymers%22">Polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Three-dimensional+printing%22">Three-dimensional printing</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Additively manufactured cellular architectures frequently exhibit brittle failure under impact due to layer-induced stress concentrations. Through the programming of architectural and material design, specifically combining Fused Deposition Modeling (FDM) lattice topology with hyperelastic polyurea infiltration, this study achieves active control over the macroscopic transition from catastrophic structural fragmentation to stable progressive collapse. To evaluate this, auxetic and honeycomb specimens printed with ABS and glass-fiber-reinforced polyamide (PA-GF) were evaluated in unreinforced and polyurea-infiltrated states under quasi-static compression, three-point bending, and Charpy impact loading. Results show that the compressive response depends primarily on cellular topology; the pure auxetic (A-A) configuration provided the highest stiffness and energy absorption. Polyurea infiltration did not significantly alter elastic stiffness but increased post-yield stability, leading to a 96.6% elastic recovery in PA-GF A-A structures. In flexure, the base polymer governed stiffness, with ABS structures measuring 68% stiffer than PA-GF. Unreinforced ABS achieved 34% higher specific energy absorption (SEA) than PA-GF under compression, with the A-H topology maximizing SEA. Under dynamic impact, PA-GF absorbed an average of 70% more energy than ABS, and the H-A configuration recorded the highest impact resistance. The addition of polyurea shifted the failure mode from brittle fragmentation to stable elastomeric deformation, increasing absorbed impact energy by 52% for ABS and over 30% for PA-GF, preventing catastrophic structural failure. Integrating topological sequencing with elastomeric confinement provides a direct method to control energy dissipation and damage tolerance in 3D-printed cellular composites. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.3390/polym18121466
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 26
        StartPage: 1466
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      – SubjectFull: Structural failures
        Type: general
      – SubjectFull: Energy dissipation
        Type: general
      – SubjectFull: Metamaterials
        Type: general
      – SubjectFull: Acrylonitrile butadiene styrene resins
        Type: general
      – SubjectFull: Glass-reinforced plastics
        Type: general
      – SubjectFull: Flexural strength testing
        Type: general
      – SubjectFull: Polymers
        Type: general
      – SubjectFull: Three-dimensional printing
        Type: general
    Titles:
      – TitleFull: Programming Failure Mode Transitions in Polyurea-Reinforced 3D-Printed ABS and PA-GF Cellular Metamaterial Composites.
        Type: main
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            NameFull: Valle, Rodrigo
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            NameFull: Garrido, César
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            NameFull: Tuninetti, Víctor
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            – D: 15
              M: 06
              Text: Jun2026
              Type: published
              Y: 2026
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