Effect of Metal Ion (Cu, Zn, Sn) Precursors on Structural and Electrical Properties of Copper Zinc Tin Selenide (Cu2ZnSnSe4) Synthesized via Solvothermal Approach.
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| Title: | Effect of Metal Ion (Cu, Zn, Sn) Precursors on Structural and Electrical Properties of Copper Zinc Tin Selenide (Cu |
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| Authors: | Shitu, Ibrahim Garba1 (AUTHOR) ibrahimgarbashitu@gmail.com, Katibi, Kamil Kayode2,3 (AUTHOR), Amusa, Abiodun Abdulhameed4,5 (AUTHOR), Muhammad, Aminu1 (AUTHOR), Suleiman, Azimov Abdugani Mutalovich6 (AUTHOR), Babani7 (AUTHOR), Tafida, Rabiu Abubakar8 (AUTHOR), Ismail, Usman Idris1 (AUTHOR), Aljfairi, Khaled9 (AUTHOR), Aliyu, Salihu Muhammad1 (AUTHOR), Zakar, Muhammad Nasiru1 (AUTHOR), Isah, Adam Ahmad1 (AUTHOR) |
| Source: | JOM: The Journal of The Minerals, Metals & Materials Society (TMS). Jul2026, Vol. 78 Issue 7, p6421-6434. 14p. |
| Subjects: | Electric properties, Chemical synthesis, Raman spectroscopy, Metal compounds, Zinc selenide, X-ray diffraction, Solid state physics |
| Abstract: | In this study, copper–zinc–tin selenide (CZTSe) was synthesized by a solvothermal route chosen for its cost-efficiency, operational simplicity, and capacity to yield highly crystalline products. Ethylenediamine supplied an alkaline environment that promoted CZTSe formation. To clarify the effect of precursor concentration on phase purity, the molar amounts of CuCl2·2H2O, Zn(CH3COO)2·2H2O, and SnCl4·5H2O were varied independently in three separate experiments. X-ray diffraction confirmed the formation of single-phase tetragonal CZTSe, and X-ray fluorescence analysis verified an almost ideal Cu\:Zn\:Sn\:Se stoichiometry of 2:1:1:4. Raman spectroscopy provided additional evidence of phase purity. Field-emission scanning electron microscopy showed that the precursor concentration strongly influenced particle morphology. Electrical conductivity increased with higher CuCl2·2H2O and Zn(CH3COO)2·2H2O levels but declined at elevated SnCl4·5H2O concentrations, the latter attributable to secondary SnO2 formation. These findings demonstrate that the relative concentrations of metal-ion precursors decisively govern the phase evolution, microstructure, and electronic properties of solvothermally synthesized CZTSe. [ABSTRACT FROM AUTHOR] |
| Copyright of JOM: The Journal of The Minerals, Metals & Materials Society (TMS) is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 194996169 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Effect of Metal Ion (Cu, Zn, Sn) Precursors on Structural and Electrical Properties of Copper Zinc Tin Selenide (Cu<subscript>2</subscript>ZnSnSe<subscript>4</subscript>) Synthesized via Solvothermal Approach. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Shitu%2C+Ibrahim+Garba%22">Shitu, Ibrahim Garba</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> ibrahimgarbashitu@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Katibi%2C+Kamil+Kayode%22">Katibi, Kamil Kayode</searchLink><relatesTo>2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Amusa%2C+Abiodun+Abdulhameed%22">Amusa, Abiodun Abdulhameed</searchLink><relatesTo>4,5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Muhammad%2C+Aminu%22">Muhammad, Aminu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Suleiman%2C+Azimov+Abdugani+Mutalovich%22">Suleiman, Azimov Abdugani Mutalovich</searchLink><relatesTo>6</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Babani%22">Babani</searchLink><relatesTo>7</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Tafida%2C+Rabiu+Abubakar%22">Tafida, Rabiu Abubakar</searchLink><relatesTo>8</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ismail%2C+Usman+Idris%22">Ismail, Usman Idris</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Aljfairi%2C+Khaled%22">Aljfairi, Khaled</searchLink><relatesTo>9</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Aliyu%2C+Salihu+Muhammad%22">Aliyu, Salihu Muhammad</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zakar%2C+Muhammad+Nasiru%22">Zakar, Muhammad Nasiru</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Isah%2C+Adam+Ahmad%22">Isah, Adam Ahmad</searchLink><relatesTo>1</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22JOM%3A+The+Journal+of+The+Minerals%2C+Metals+%26+Materials+Society+%28TMS%29%22">JOM: The Journal of The Minerals, Metals & Materials Society (TMS)</searchLink>. Jul2026, Vol. 78 Issue 7, p6421-6434. 14p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Electric+properties%22">Electric properties</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+synthesis%22">Chemical synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Raman+spectroscopy%22">Raman spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+compounds%22">Metal compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Zinc+selenide%22">Zinc selenide</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22Solid+state+physics%22">Solid state physics</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: In this study, copper–zinc–tin selenide (CZTSe) was synthesized by a solvothermal route chosen for its cost-efficiency, operational simplicity, and capacity to yield highly crystalline products. Ethylenediamine supplied an alkaline environment that promoted CZTSe formation. To clarify the effect of precursor concentration on phase purity, the molar amounts of CuCl2·2H2O, Zn(CH3COO)2·2H2O, and SnCl4·5H2O were varied independently in three separate experiments. X-ray diffraction confirmed the formation of single-phase tetragonal CZTSe, and X-ray fluorescence analysis verified an almost ideal Cu\:Zn\:Sn\:Se stoichiometry of 2:1:1:4. Raman spectroscopy provided additional evidence of phase purity. Field-emission scanning electron microscopy showed that the precursor concentration strongly influenced particle morphology. Electrical conductivity increased with higher CuCl2·2H2O and Zn(CH3COO)2·2H2O levels but declined at elevated SnCl4·5H2O concentrations, the latter attributable to secondary SnO2 formation. These findings demonstrate that the relative concentrations of metal-ion precursors decisively govern the phase evolution, microstructure, and electronic properties of solvothermally synthesized CZTSe. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of JOM: The Journal of The Minerals, Metals & Materials Society (TMS) is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1007/s11837-026-08147-2 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 14 StartPage: 6421 Subjects: – SubjectFull: Electric properties Type: general – SubjectFull: Chemical synthesis Type: general – SubjectFull: Raman spectroscopy Type: general – SubjectFull: Metal compounds Type: general – SubjectFull: Zinc selenide Type: general – SubjectFull: X-ray diffraction Type: general – SubjectFull: Solid state physics Type: general Titles: – TitleFull: Effect of Metal Ion (Cu, Zn, Sn) Precursors on Structural and Electrical Properties of Copper Zinc Tin Selenide (Cu2ZnSnSe4) Synthesized via Solvothermal Approach. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Shitu, Ibrahim Garba – PersonEntity: Name: NameFull: Katibi, Kamil Kayode – PersonEntity: Name: NameFull: Amusa, Abiodun Abdulhameed – PersonEntity: Name: NameFull: Muhammad, Aminu – PersonEntity: Name: NameFull: Suleiman, Azimov Abdugani Mutalovich – PersonEntity: Name: NameFull: Babani – PersonEntity: Name: NameFull: Tafida, Rabiu Abubakar – PersonEntity: Name: NameFull: Ismail, Usman Idris – PersonEntity: Name: NameFull: Aljfairi, Khaled – PersonEntity: Name: NameFull: Aliyu, Salihu Muhammad – PersonEntity: Name: NameFull: Zakar, Muhammad Nasiru – PersonEntity: Name: NameFull: Isah, Adam Ahmad IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 07 Text: Jul2026 Type: published Y: 2026 Identifiers: – Type: issn-print Value: 10474838 Numbering: – Type: volume Value: 78 – Type: issue Value: 7 Titles: – TitleFull: JOM: The Journal of The Minerals, Metals & Materials Society (TMS) Type: main |
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