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Atomic spectrometry update: review of advances in elemental speciation.

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Title: Atomic spectrometry update: review of advances in elemental speciation.
Authors: Clough, Robert1 (AUTHOR) rclough@plymouth.ac.uk, Harrington, Chris F.2 (AUTHOR), Hill, Steve J.3 (AUTHOR), Madrid, Yolanda4 (AUTHOR), Tyson, Julian F.5 (AUTHOR)
Source: JAAS (Journal of Analytical Atomic Spectrometry). Jul2026, Vol. 41 Issue 7, p2295-2318. 24p.
Subjects: Chemical speciation, Oxidation states, Spectrometry, Metalloproteins, X-ray spectroscopy, Organometallic compounds, Nuclear fuel elements
Abstract: This is the 18th Atomic Spectrometry Update (ASU) to focus on advances in elemental speciation and covers a period of approximately 12 months from January 2025. This ASU review deals with all aspects of analytical atomic spectrometry speciation methods developed for: the determination of oxidation states; organometallic compounds; coordination compounds; metal- and heteroatom-containing biomolecules, including metalloproteins, proteins, peptides and amino acids; and the use of metal tagging to facilitate detection via atomic spectrometry. As with all ASU reviews, the focus of the research reviewed includes those methods that incorporate atomic spectrometry as the measurement technique, although molecular detection techniques are also included where they have provided a complementary approach to speciation analysis. The number of publications covered this year has fallen to the lowest number since this ASU has been published. However, there is still a good breadth of elements covered, with the most popular elements still being As, Hg and Se, and the focus of many papers is on elucidating mechanisms and transformation pathways, particularly in plants and animals/humans, rather than concentrating on the speciation method. A number of papers covering speciation analyses of elements related to nuclear power generation have been published, which reflects the increasing demand for this power source in the global efforts to decarbonise. There has also been a report on the use of XRF spectroscopy as a detector for LC and three papers of note that describe comprehensive methods for metallobiomolecules. Once again, the quality of the abstract for many of the papers is poor, with detail on the methodology, key results with data included, conclusions and implications thereof missing. This is likely to lead to fewer researchers reading the article or considering it for reviews such as those produced by the ASU. [ABSTRACT FROM AUTHOR]
Copyright of JAAS (Journal of Analytical Atomic Spectrometry) is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 195178508
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Atomic spectrometry update: review of advances in elemental speciation.
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  Data: <searchLink fieldCode="AR" term="%22Clough%2C+Robert%22">Clough, Robert</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> rclough@plymouth.ac.uk</i><br /><searchLink fieldCode="AR" term="%22Harrington%2C+Chris+F%2E%22">Harrington, Chris F.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hill%2C+Steve+J%2E%22">Hill, Steve J.</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Madrid%2C+Yolanda%22">Madrid, Yolanda</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Tyson%2C+Julian+F%2E%22">Tyson, Julian F.</searchLink><relatesTo>5</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22JAAS+%28Journal+of+Analytical+Atomic+Spectrometry%29%22">JAAS (Journal of Analytical Atomic Spectrometry)</searchLink>. Jul2026, Vol. 41 Issue 7, p2295-2318. 24p.
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  Data: <searchLink fieldCode="DE" term="%22Chemical+speciation%22">Chemical speciation</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation+states%22">Oxidation states</searchLink><br /><searchLink fieldCode="DE" term="%22Spectrometry%22">Spectrometry</searchLink><br /><searchLink fieldCode="DE" term="%22Metalloproteins%22">Metalloproteins</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+spectroscopy%22">X-ray spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Organometallic+compounds%22">Organometallic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Nuclear+fuel+elements%22">Nuclear fuel elements</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: This is the 18th Atomic Spectrometry Update (ASU) to focus on advances in elemental speciation and covers a period of approximately 12 months from January 2025. This ASU review deals with all aspects of analytical atomic spectrometry speciation methods developed for: the determination of oxidation states; organometallic compounds; coordination compounds; metal- and heteroatom-containing biomolecules, including metalloproteins, proteins, peptides and amino acids; and the use of metal tagging to facilitate detection via atomic spectrometry. As with all ASU reviews, the focus of the research reviewed includes those methods that incorporate atomic spectrometry as the measurement technique, although molecular detection techniques are also included where they have provided a complementary approach to speciation analysis. The number of publications covered this year has fallen to the lowest number since this ASU has been published. However, there is still a good breadth of elements covered, with the most popular elements still being As, Hg and Se, and the focus of many papers is on elucidating mechanisms and transformation pathways, particularly in plants and animals/humans, rather than concentrating on the speciation method. A number of papers covering speciation analyses of elements related to nuclear power generation have been published, which reflects the increasing demand for this power source in the global efforts to decarbonise. There has also been a report on the use of XRF spectroscopy as a detector for LC and three papers of note that describe comprehensive methods for metallobiomolecules. Once again, the quality of the abstract for many of the papers is poor, with detail on the methodology, key results with data included, conclusions and implications thereof missing. This is likely to lead to fewer researchers reading the article or considering it for reviews such as those produced by the ASU. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of JAAS (Journal of Analytical Atomic Spectrometry) is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1039/d6ja90024k
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 24
        StartPage: 2295
    Subjects:
      – SubjectFull: Chemical speciation
        Type: general
      – SubjectFull: Oxidation states
        Type: general
      – SubjectFull: Spectrometry
        Type: general
      – SubjectFull: Metalloproteins
        Type: general
      – SubjectFull: X-ray spectroscopy
        Type: general
      – SubjectFull: Organometallic compounds
        Type: general
      – SubjectFull: Nuclear fuel elements
        Type: general
    Titles:
      – TitleFull: Atomic spectrometry update: review of advances in elemental speciation.
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            NameFull: Clough, Robert
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            NameFull: Hill, Steve J.
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            NameFull: Madrid, Yolanda
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              M: 07
              Text: Jul2026
              Type: published
              Y: 2026
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              Value: 41
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