Influence of Antioxidants and Deep Eutectic Solvent on Vulcanization Kinetics and Mechanical Behaviors of Natural Rubber/Styrene-Butadiene Rubber Blend and Composites.
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| Title: | Influence of Antioxidants and Deep Eutectic Solvent on Vulcanization Kinetics and Mechanical Behaviors of Natural Rubber/Styrene-Butadiene Rubber Blend and Composites. |
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| Authors: | Liu, Zi-Ye1 (AUTHOR), Song, Yi-Hu1 (AUTHOR) s_yh0411@zju.edu.cn, Zheng, Qiang1 (AUTHOR) |
| Source: | Chinese Journal of Polymer Science (Springer Science & Business Media B.V.). Jul2026, Vol. 44 Issue 7, p2341-2351. 11p. |
| Subjects: | Antioxidants, Vulcanization, Mechanical behavior of materials, Rubber, Solvents, Styrene-butadiene rubber, Polymer networks, Reinforcement of rubber |
| Abstract: | Antioxidants are generally used for prolonging the lifespan of rubber products, while their influences on the vulcanization kinetics and mechanical properties are rarely investigated. Herein, the synergistic roles of conventional antioxidants (6PPD, MB, 2246) and deep eutectic solvent (DES) in natural rubber (NR), styrene-butadiene rubber (SBR), their blends, and the blends filled with carbon black (CB) and black talc (BT) were examined. The results showed that antioxidants and DES influenced the vulcanization kinetics, crosslinking density and mechanical behaviors markedly. A combination of MB and DES resulted in NR/SBR-CB/BT composite vulcanizates with high strength and low dissipation characteristics. DES formed hydrogen bond/ion-pair complexes with antioxidants, and, in NR, interacted with non-rubber constituents, thereby modulating cure intermediates and sulfur-bond distributions, paving the way for preparing high performance rubber composites. [ABSTRACT FROM AUTHOR] |
| Copyright of Chinese Journal of Polymer Science (Springer Science & Business Media B.V.) is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 195464559 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Influence of Antioxidants and Deep Eutectic Solvent on Vulcanization Kinetics and Mechanical Behaviors of Natural Rubber/Styrene-Butadiene Rubber Blend and Composites. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Liu%2C+Zi-Ye%22">Liu, Zi-Ye</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Song%2C+Yi-Hu%22">Song, Yi-Hu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> s_yh0411@zju.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Zheng%2C+Qiang%22">Zheng, Qiang</searchLink><relatesTo>1</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Chinese+Journal+of+Polymer+Science+%28Springer+Science+%26+Business+Media+B%2EV%2E%29%22">Chinese Journal of Polymer Science (Springer Science & Business Media B.V.)</searchLink>. Jul2026, Vol. 44 Issue 7, p2341-2351. 11p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Antioxidants%22">Antioxidants</searchLink><br /><searchLink fieldCode="DE" term="%22Vulcanization%22">Vulcanization</searchLink><br /><searchLink fieldCode="DE" term="%22Mechanical+behavior+of+materials%22">Mechanical behavior of materials</searchLink><br /><searchLink fieldCode="DE" term="%22Rubber%22">Rubber</searchLink><br /><searchLink fieldCode="DE" term="%22Solvents%22">Solvents</searchLink><br /><searchLink fieldCode="DE" term="%22Styrene-butadiene+rubber%22">Styrene-butadiene rubber</searchLink><br /><searchLink fieldCode="DE" term="%22Polymer+networks%22">Polymer networks</searchLink><br /><searchLink fieldCode="DE" term="%22Reinforcement+of+rubber%22">Reinforcement of rubber</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Antioxidants are generally used for prolonging the lifespan of rubber products, while their influences on the vulcanization kinetics and mechanical properties are rarely investigated. Herein, the synergistic roles of conventional antioxidants (6PPD, MB, 2246) and deep eutectic solvent (DES) in natural rubber (NR), styrene-butadiene rubber (SBR), their blends, and the blends filled with carbon black (CB) and black talc (BT) were examined. The results showed that antioxidants and DES influenced the vulcanization kinetics, crosslinking density and mechanical behaviors markedly. A combination of MB and DES resulted in NR/SBR-CB/BT composite vulcanizates with high strength and low dissipation characteristics. DES formed hydrogen bond/ion-pair complexes with antioxidants, and, in NR, interacted with non-rubber constituents, thereby modulating cure intermediates and sulfur-bond distributions, paving the way for preparing high performance rubber composites. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Chinese Journal of Polymer Science (Springer Science & Business Media B.V.) is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1007/s10118-026-3632-7 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 11 StartPage: 2341 Subjects: – SubjectFull: Antioxidants Type: general – SubjectFull: Vulcanization Type: general – SubjectFull: Mechanical behavior of materials Type: general – SubjectFull: Rubber Type: general – SubjectFull: Solvents Type: general – SubjectFull: Styrene-butadiene rubber Type: general – SubjectFull: Polymer networks Type: general – SubjectFull: Reinforcement of rubber Type: general Titles: – TitleFull: Influence of Antioxidants and Deep Eutectic Solvent on Vulcanization Kinetics and Mechanical Behaviors of Natural Rubber/Styrene-Butadiene Rubber Blend and Composites. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Liu, Zi-Ye – PersonEntity: Name: NameFull: Song, Yi-Hu – PersonEntity: Name: NameFull: Zheng, Qiang IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 07 Text: Jul2026 Type: published Y: 2026 Identifiers: – Type: issn-print Value: 02567679 Numbering: – Type: volume Value: 44 – Type: issue Value: 7 Titles: – TitleFull: Chinese Journal of Polymer Science (Springer Science & Business Media B.V.) Type: main |
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