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Construction of a thiourea-functionalized metallomacrocycle for the reductive amination of furfural under mild conditions.

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Title: Construction of a thiourea-functionalized metallomacrocycle for the reductive amination of furfural under mild conditions.
Authors: Zhang, Xiaoyu1 (AUTHOR), Wang, Jinfeng1 (AUTHOR), Wang, Yao1 (AUTHOR), Jing, Xu1 (AUTHOR) xjing@dlut.edu.cn, Duan, Chunying1 (AUTHOR)
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 7/21/2026, Vol. 55 Issue 28, p10507-10511. 5p.
Subjects: Furfural, Homogeneous catalysis, Organic reaction mechanisms, Schiff bases, Catalysis, Hydrogen bonding, Catalysts
Abstract: A thiourea-functionalized metallomacrocycle was constructed as an efficient homogeneous catalyst for the reductive amination of furfural. Its weakly acidic cavity microenvironment with hydrogen-bonding sites built from thiourea ligands enables the encapsulation of substrate molecules, thereby promoting the condensation of imines and their subsequent reduction. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 195547417
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Construction of a thiourea-functionalized metallomacrocycle for the reductive amination of furfural under mild conditions.
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  Data: <searchLink fieldCode="AR" term="%22Zhang%2C+Xiaoyu%22">Zhang, Xiaoyu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Jinfeng%22">Wang, Jinfeng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Yao%22">Wang, Yao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jing%2C+Xu%22">Jing, Xu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> xjing@dlut.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Duan%2C+Chunying%22">Duan, Chunying</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 7/21/2026, Vol. 55 Issue 28, p10507-10511. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Furfural%22">Furfural</searchLink><br /><searchLink fieldCode="DE" term="%22Homogeneous+catalysis%22">Homogeneous catalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+reaction+mechanisms%22">Organic reaction mechanisms</searchLink><br /><searchLink fieldCode="DE" term="%22Schiff+bases%22">Schiff bases</searchLink><br /><searchLink fieldCode="DE" term="%22Catalysis%22">Catalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen+bonding%22">Hydrogen bonding</searchLink><br /><searchLink fieldCode="DE" term="%22Catalysts%22">Catalysts</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A thiourea-functionalized metallomacrocycle was constructed as an efficient homogeneous catalyst for the reductive amination of furfural. Its weakly acidic cavity microenvironment with hydrogen-bonding sites built from thiourea ligands enables the encapsulation of substrate molecules, thereby promoting the condensation of imines and their subsequent reduction. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1039/d6dt00744a
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        Text: English
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      – SubjectFull: Furfural
        Type: general
      – SubjectFull: Homogeneous catalysis
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      – SubjectFull: Organic reaction mechanisms
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      – SubjectFull: Schiff bases
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      – SubjectFull: Catalysis
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      – SubjectFull: Hydrogen bonding
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      – SubjectFull: Catalysts
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            NameFull: Wang, Jinfeng
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              M: 07
              Text: 7/21/2026
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              Y: 2026
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