Construction of a thiourea-functionalized metallomacrocycle for the reductive amination of furfural under mild conditions.
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| Title: | Construction of a thiourea-functionalized metallomacrocycle for the reductive amination of furfural under mild conditions. |
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| Authors: | Zhang, Xiaoyu1 (AUTHOR), Wang, Jinfeng1 (AUTHOR), Wang, Yao1 (AUTHOR), Jing, Xu1 (AUTHOR) xjing@dlut.edu.cn, Duan, Chunying1 (AUTHOR) |
| Source: | Dalton Transactions: An International Journal of Inorganic Chemistry. 7/21/2026, Vol. 55 Issue 28, p10507-10511. 5p. |
| Subjects: | Furfural, Homogeneous catalysis, Organic reaction mechanisms, Schiff bases, Catalysis, Hydrogen bonding, Catalysts |
| Abstract: | A thiourea-functionalized metallomacrocycle was constructed as an efficient homogeneous catalyst for the reductive amination of furfural. Its weakly acidic cavity microenvironment with hydrogen-bonding sites built from thiourea ligands enables the encapsulation of substrate molecules, thereby promoting the condensation of imines and their subsequent reduction. [ABSTRACT FROM AUTHOR] |
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| Database: | Engineering Source |
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