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Gas-Phase Assembling of Dirhodium Units into a Novel Organometallic Ladder:  Structural and DFT Study.

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Title: Gas-Phase Assembling of Dirhodium Units into a Novel Organometallic Ladder:  Structural and DFT Study.
Authors: Alexander S. Filatov1, Andrey Yu. Rogachev1, Marina A. Petrukhina1
Source: Crystal Growth & Design. Jun2006, Vol. 6 Issue 6, p1479-1484. 6p.
Subjects: Aromatic compounds, Benzene, Organic compounds, Carbon compounds
Abstract: A hydrocarbon that has three separate aromatic rings, namely 1,4-bis(p-tolylethyl)benzene (C24H26), has been structurally characterized for the first time and tested as an elongated aromatic π-donor in assembling reactions under solvent-free conditions. Its gas-phase interaction with the electrophilic dimetal complex, [Rh2(O2CCF3)4], affords single crystals of a novel organometallic complex, [Rh2(O2CCF3)4]2·(C24H26). The product has a ladder type structure built on weak but directional rhodium(II)−π-arene interactions. In the above framework, each C24H26 exhibits a tetradentate-bridging coordination having four rhodium(II) centers attached to the opposite sides of the two peripheral benzene rings. The underlying reasons for such coordination defining the formation of the title product have been discussed based on the results of density functional theory, namely the orbital interaction analysis of the reacting partners. [ABSTRACT FROM AUTHOR]
Copyright of Crystal Growth & Design is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 21630620
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  Data: Gas-Phase Assembling of Dirhodium Units into a Novel Organometallic Ladder:  Structural and DFT Study.
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  Data: <searchLink fieldCode="AR" term="%22Alexander+S%2E+Filatov%22">Alexander S. Filatov</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Andrey+Yu%2E+Rogachev%22">Andrey Yu. Rogachev</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Marina+A%2E+Petrukhina%22">Marina A. Petrukhina</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Crystal+Growth+%26+Design%22">Crystal Growth & Design</searchLink>. Jun2006, Vol. 6 Issue 6, p1479-1484. 6p.
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  Data: <searchLink fieldCode="DE" term="%22Aromatic+compounds%22">Aromatic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Benzene%22">Benzene</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+compounds%22">Organic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Carbon+compounds%22">Carbon compounds</searchLink>
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  Label: Abstract
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  Data: A hydrocarbon that has three separate aromatic rings, namely 1,4-bis(p-tolylethyl)benzene (C24H26), has been structurally characterized for the first time and tested as an elongated aromatic π-donor in assembling reactions under solvent-free conditions. Its gas-phase interaction with the electrophilic dimetal complex, [Rh2(O2CCF3)4], affords single crystals of a novel organometallic complex, [Rh2(O2CCF3)4]2·(C24H26). The product has a ladder type structure built on weak but directional rhodium(II)−π-arene interactions. In the above framework, each C24H26 exhibits a tetradentate-bridging coordination having four rhodium(II) centers attached to the opposite sides of the two peripheral benzene rings. The underlying reasons for such coordination defining the formation of the title product have been discussed based on the results of density functional theory, namely the orbital interaction analysis of the reacting partners. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Group: Ab
  Data: <i>Copyright of Crystal Growth & Design is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1021/cg060118c
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      – Code: eng
        Text: English
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        StartPage: 1479
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      – SubjectFull: Aromatic compounds
        Type: general
      – SubjectFull: Benzene
        Type: general
      – SubjectFull: Organic compounds
        Type: general
      – SubjectFull: Carbon compounds
        Type: general
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      – TitleFull: Gas-Phase Assembling of Dirhodium Units into a Novel Organometallic Ladder:  Structural and DFT Study.
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            NameFull: Alexander S. Filatov
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            NameFull: Andrey Yu. Rogachev
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              Text: Jun2006
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              Y: 2006
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