View in EDS

Polyphosphazene based composite polymer electrolytes

Saved in:
Bibliographic Details
Title: Polyphosphazene based composite polymer electrolytes
Authors: Kaskhedikar, N.1,2, Paulsdorf, J.1, Burjanadze, M.1, Karatas, Y.1,2, Roling, B.3, Wiemhöfer, H.-D.1,2 hdw@uni-muenster.de
Source: Solid State Ionics. Oct2006, Vol. 177 Issue 26-32, p2699-2704. 6p.
Subjects: Polyphosphazenes, Polymers, Electrolytes, Nanoparticles
Abstract: Abstract: Composite salt-in-polymer electrolyte membranes were prepared from poly[(bis(2-methoxyethyl)amino)1−x (n-propylamino) x -phosphazene] (BMEAP) with dissolved LiCF3SO3 and dispersed Al2O3 nanoparticles (40 nm). Membranes with good mechanical stability were obtained. Low ionic conductivities were found in particle free membranes with maximum conductivities at 10 wt.% LiCF3SO3 ranging from 3.1×10−7 S/cm at 30 °C to 1.8×10−5 S/cm at 90 °C. For the composite membranes, addition of 2 wt.% Al2O3 nanoparticles leads to a steep increase of the conductivity by almost two orders of magnitude as compared to the homogeneous membranes. The highest room temperature conductivity for the investigated BMEAP–LiCF3SO3–Al2O3 composite systems was 10−5 S/cm. [Copyright &y& Elsevier]
Copyright of Solid State Ionics is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 22936442
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Polyphosphazene based composite polymer electrolytes
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Kaskhedikar%2C+N%2E%22">Kaskhedikar, N.</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Paulsdorf%2C+J%2E%22">Paulsdorf, J.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Burjanadze%2C+M%2E%22">Burjanadze, M.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Karatas%2C+Y%2E%22">Karatas, Y.</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Roling%2C+B%2E%22">Roling, B.</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Wiemhöfer%2C+H%2E-D%2E%22">Wiemhöfer, H.-D.</searchLink><relatesTo>1,2</relatesTo><i> hdw@uni-muenster.de</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Solid+State+Ionics%22">Solid State Ionics</searchLink>. Oct2006, Vol. 177 Issue 26-32, p2699-2704. 6p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Polyphosphazenes%22">Polyphosphazenes</searchLink><br /><searchLink fieldCode="DE" term="%22Polymers%22">Polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Electrolytes%22">Electrolytes</searchLink><br /><searchLink fieldCode="DE" term="%22Nanoparticles%22">Nanoparticles</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: Composite salt-in-polymer electrolyte membranes were prepared from poly[(bis(2-methoxyethyl)amino)1−x (n-propylamino) x -phosphazene] (BMEAP) with dissolved LiCF3SO3 and dispersed Al2O3 nanoparticles (40 nm). Membranes with good mechanical stability were obtained. Low ionic conductivities were found in particle free membranes with maximum conductivities at 10 wt.% LiCF3SO3 ranging from 3.1×10−7 S/cm at 30 °C to 1.8×10−5 S/cm at 90 °C. For the composite membranes, addition of 2 wt.% Al2O3 nanoparticles leads to a steep increase of the conductivity by almost two orders of magnitude as compared to the homogeneous membranes. The highest room temperature conductivity for the investigated BMEAP–LiCF3SO3–Al2O3 composite systems was 10−5 S/cm. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Solid State Ionics is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=22936442
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.ssi.2006.05.003
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 6
        StartPage: 2699
    Subjects:
      – SubjectFull: Polyphosphazenes
        Type: general
      – SubjectFull: Polymers
        Type: general
      – SubjectFull: Electrolytes
        Type: general
      – SubjectFull: Nanoparticles
        Type: general
    Titles:
      – TitleFull: Polyphosphazene based composite polymer electrolytes
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Kaskhedikar, N.
      – PersonEntity:
          Name:
            NameFull: Paulsdorf, J.
      – PersonEntity:
          Name:
            NameFull: Burjanadze, M.
      – PersonEntity:
          Name:
            NameFull: Karatas, Y.
      – PersonEntity:
          Name:
            NameFull: Roling, B.
      – PersonEntity:
          Name:
            NameFull: Wiemhöfer, H.-D.
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 31
              M: 10
              Text: Oct2006
              Type: published
              Y: 2006
          Identifiers:
            – Type: issn-print
              Value: 01672738
          Numbering:
            – Type: volume
              Value: 177
            – Type: issue
              Value: 26-32
          Titles:
            – TitleFull: Solid State Ionics
              Type: main
ResultId 1