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Studies on the synthesis of novel 2,2′-bis(ferrocenyl)propane derivatives and their reactivity with metal carbonyl clusters.

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Title: Studies on the synthesis of novel 2,2′-bis(ferrocenyl)propane derivatives and their reactivity with metal carbonyl clusters.
Authors: Quan-Ling Suo1 szj@imut.edu.cn, Ning Zhu1, Li-Min Han1, Yi-Bing Wang1, Yue-Guang Bai1, Lin-Hong Weng2
Source: Polyhedron. Nov2006, Vol. 25 Issue 16, p3209-3214. 6p.
Subjects: Nuclear magnetic resonance, Electrochemical analysis, Carbonyl compounds, Reactivity (Chemistry)
Abstract: The reaction of new ferrocenylacetylene HC≡C(C5H5FeC5H3)C(CH3)2Fc′C≡CH (1; Fc′ = C5H4FeC5H4) with Co2(CO)8 has been studied and the spectra and molecular structure of complexes [HC≡C(C5H5FeC5H3)C(CH3)2Fc′C≡CH][Co2(CO)6]n [n = 1, (4); n = 2, (5)] have been determined. Novel complex [FcC(CH3)2Fc′CH≡C]FeCo2(CO)9 (6; Fc = C5H5FeC5H4) has been synthesized by using a nuclear expanding reaction of complex [FcC(CH3)2Fc′C≡CH]Co2(CO)6 (3) with Fe2(CO)9 and the structural characterization of complex 6 was accomplished by elemental analysis, IR, 1H, 13C NMR and MS. The electrochemical properties of the compounds with ferrocenylacetylene reveal that there is significant electronic communication between the ferrocenyl groups. [Copyright &y& Elsevier]
Copyright of Polyhedron is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 22950140
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PubTypeId: academicJournal
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  Label: Title
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  Data: Studies on the synthesis of novel 2,2′-bis(ferrocenyl)propane derivatives and their reactivity with metal carbonyl clusters.
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  Data: <searchLink fieldCode="AR" term="%22Quan-Ling+Suo%22">Quan-Ling Suo</searchLink><relatesTo>1</relatesTo><i> szj@imut.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Ning+Zhu%22">Ning Zhu</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Li-Min+Han%22">Li-Min Han</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yi-Bing+Wang%22">Yi-Bing Wang</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yue-Guang+Bai%22">Yue-Guang Bai</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Lin-Hong+Weng%22">Lin-Hong Weng</searchLink><relatesTo>2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Polyhedron%22">Polyhedron</searchLink>. Nov2006, Vol. 25 Issue 16, p3209-3214. 6p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Nuclear+magnetic+resonance%22">Nuclear magnetic resonance</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemical+analysis%22">Electrochemical analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Carbonyl+compounds%22">Carbonyl compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Reactivity+%28Chemistry%29%22">Reactivity (Chemistry)</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The reaction of new ferrocenylacetylene HC≡C(C5H5FeC5H3)C(CH3)2Fc′C≡CH (1; Fc′ = C5H4FeC5H4) with Co2(CO)8 has been studied and the spectra and molecular structure of complexes [HC≡C(C5H5FeC5H3)C(CH3)2Fc′C≡CH][Co2(CO)6]n [n = 1, (4); n = 2, (5)] have been determined. Novel complex [FcC(CH3)2Fc′CH≡C]FeCo2(CO)9 (6; Fc = C5H5FeC5H4) has been synthesized by using a nuclear expanding reaction of complex [FcC(CH3)2Fc′C≡CH]Co2(CO)6 (3) with Fe2(CO)9 and the structural characterization of complex 6 was accomplished by elemental analysis, IR, 1H, 13C NMR and MS. The electrochemical properties of the compounds with ferrocenylacetylene reveal that there is significant electronic communication between the ferrocenyl groups. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Polyhedron is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/j.poly.2006.05.022
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      – Code: eng
        Text: English
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        Type: general
      – SubjectFull: Electrochemical analysis
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      – SubjectFull: Carbonyl compounds
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      – SubjectFull: Reactivity (Chemistry)
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      – TitleFull: Studies on the synthesis of novel 2,2′-bis(ferrocenyl)propane derivatives and their reactivity with metal carbonyl clusters.
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            NameFull: Quan-Ling Suo
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            NameFull: Ning Zhu
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            NameFull: Li-Min Han
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            NameFull: Yi-Bing Wang
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              Text: Nov2006
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              Y: 2006
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