View in EDS

A new corrosion protection coating with polyaniline–TiO2 composite for steel

Saved in:
Bibliographic Details
Title: A new corrosion protection coating with polyaniline–TiO2 composite for steel
Authors: S. Sathiyanarayanan1, Azim, S. Syed1, Venkatachari, G. sathya_cecri@yahoo.co.in
Source: Electrochimica Acta. Jan2007, Vol. 52 Issue 5, p2068-2074. 7p.
Subjects: Coatings industry, Steel, Coating processes, Polymers
Abstract: Abstract: Organic coating strategies for corrosion protection with inherently conducting polymers have become important because of restriction on the use of heavy metals and chromates in coatings due to their environmental problems. This work presents the synthesis of polyaniline–TiO2 composites (PTC) and the corrosion protection behaviour of PTC containing coating on steel. PTC was prepared by chemical oxidation of aniline and TiO2 by ammonium persulfate in phosphoric acid medium. The PTC was characterized by FTIR, XRD and SEM techniques. Suitable coating with PTC was formed on steel using acrylic resin. Using electrochemical impedance spectroscopy, the PTC containing coating''s behaviour in 3% NaCl immersion test and salt spray test has been found out. Results indicate that the coating containing PTC is able to maintain the potential of steel in passive region due to its redox property. The resistance of the coating containing PTC was more than 107 Ωcm2 in 3% NaCl solution after 60 days and 109 Ωcm2 in the salt spray test of 35 days. But the resistance of the TiO2 containing coating was found to be less than 104 Ωcm2 in both the cases. The high performance of PTC containing coating is attributed to the passivation of steel by polyaniline. [Copyright &y& Elsevier]
Copyright of Electrochimica Acta is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 23517172
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: A new corrosion protection coating with polyaniline–TiO<subscript>2</subscript> composite for steel
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22S%2E+Sathiyanarayanan%22">S. Sathiyanarayanan</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Azim%2C+S%2E+Syed%22">Azim, S. Syed</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Venkatachari%2C+G%2E%22">Venkatachari, G.</searchLink><i> sathya_cecri@yahoo.co.in</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Electrochimica+Acta%22">Electrochimica Acta</searchLink>. Jan2007, Vol. 52 Issue 5, p2068-2074. 7p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Coatings+industry%22">Coatings industry</searchLink><br /><searchLink fieldCode="DE" term="%22Steel%22">Steel</searchLink><br /><searchLink fieldCode="DE" term="%22Coating+processes%22">Coating processes</searchLink><br /><searchLink fieldCode="DE" term="%22Polymers%22">Polymers</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: Organic coating strategies for corrosion protection with inherently conducting polymers have become important because of restriction on the use of heavy metals and chromates in coatings due to their environmental problems. This work presents the synthesis of polyaniline–TiO2 composites (PTC) and the corrosion protection behaviour of PTC containing coating on steel. PTC was prepared by chemical oxidation of aniline and TiO2 by ammonium persulfate in phosphoric acid medium. The PTC was characterized by FTIR, XRD and SEM techniques. Suitable coating with PTC was formed on steel using acrylic resin. Using electrochemical impedance spectroscopy, the PTC containing coating''s behaviour in 3% NaCl immersion test and salt spray test has been found out. Results indicate that the coating containing PTC is able to maintain the potential of steel in passive region due to its redox property. The resistance of the coating containing PTC was more than 107 Ωcm2 in 3% NaCl solution after 60 days and 109 Ωcm2 in the salt spray test of 35 days. But the resistance of the TiO2 containing coating was found to be less than 104 Ωcm2 in both the cases. The high performance of PTC containing coating is attributed to the passivation of steel by polyaniline. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Electrochimica Acta is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=23517172
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.electacta.2006.08.022
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 7
        StartPage: 2068
    Subjects:
      – SubjectFull: Coatings industry
        Type: general
      – SubjectFull: Steel
        Type: general
      – SubjectFull: Coating processes
        Type: general
      – SubjectFull: Polymers
        Type: general
    Titles:
      – TitleFull: A new corrosion protection coating with polyaniline–TiO2 composite for steel
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: S. Sathiyanarayanan
      – PersonEntity:
          Name:
            NameFull: Azim, S. Syed
      – PersonEntity:
          Name:
            NameFull: Venkatachari, G.
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 01
              Text: Jan2007
              Type: published
              Y: 2007
          Identifiers:
            – Type: issn-print
              Value: 00134686
          Numbering:
            – Type: volume
              Value: 52
            – Type: issue
              Value: 5
          Titles:
            – TitleFull: Electrochimica Acta
              Type: main
ResultId 1