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Synthesis, crystal structure and characterization of a new zinc phthalocyanine complex

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Title: Synthesis, crystal structure and characterization of a new zinc phthalocyanine complex
Authors: Cui, Li-Ying1, Yang, Jin1, Fu, Qiang fqiang@nenu.edu.cn, Zhao, Bao-Zhong1, Tian, Lei1, Yu, Hai-Ling1
Source: Journal of Molecular Structure. Feb2007, Vol. 827 Issue 1-3, p149-154. 6p.
Subjects: Phthalocyanines, Zinc compounds, X-ray diffraction, Fluorescence spectroscopy
Abstract: Abstract: A new complex [ZnPc(H2O)]·2DMF (1), where Pc=phthalocyanine and DMF= N,N-dimethylformamide, has been synthesized and its crystal has been determined by single-crystal X-ray diffraction method. The compound crystallizes in the triclinic space group P −1. The lattice parameters are a =11.668(5) Å, b =12.186(5) Å, c =13.939(6) Å, α =78.697(7)°, β =88.045 (7)°, γ =62.949(7)°, V =1727.4(12) Å3 and Z =2. The Zn(II) ion is five-coordinated by four nitrogen atoms from Pc ligands and one oxygen atom from one water molecule. Notably, there are strong π–π interactions between Pc ligands, leading to 1D superamolecular structure. Moreover, the elemental analyses, FT-IR, UV–vis and Fluorescence spectra for this complex were also determined. [Copyright &y& Elsevier]
Copyright of Journal of Molecular Structure is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 23870351
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Synthesis, crystal structure and characterization of a new zinc phthalocyanine complex
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  Data: <searchLink fieldCode="AR" term="%22Cui%2C+Li-Ying%22">Cui, Li-Ying</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yang%2C+Jin%22">Yang, Jin</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Fu%2C+Qiang%22">Fu, Qiang</searchLink><i> fqiang@nenu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Zhao%2C+Bao-Zhong%22">Zhao, Bao-Zhong</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Tian%2C+Lei%22">Tian, Lei</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yu%2C+Hai-Ling%22">Yu, Hai-Ling</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Molecular+Structure%22">Journal of Molecular Structure</searchLink>. Feb2007, Vol. 827 Issue 1-3, p149-154. 6p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Phthalocyanines%22">Phthalocyanines</searchLink><br /><searchLink fieldCode="DE" term="%22Zinc+compounds%22">Zinc compounds</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22Fluorescence+spectroscopy%22">Fluorescence spectroscopy</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: A new complex [ZnPc(H2O)]·2DMF (1), where Pc=phthalocyanine and DMF= N,N-dimethylformamide, has been synthesized and its crystal has been determined by single-crystal X-ray diffraction method. The compound crystallizes in the triclinic space group P −1. The lattice parameters are a =11.668(5) Å, b =12.186(5) Å, c =13.939(6) Å, α =78.697(7)°, β =88.045 (7)°, γ =62.949(7)°, V =1727.4(12) Å3 and Z =2. The Zn(II) ion is five-coordinated by four nitrogen atoms from Pc ligands and one oxygen atom from one water molecule. Notably, there are strong π–π interactions between Pc ligands, leading to 1D superamolecular structure. Moreover, the elemental analyses, FT-IR, UV–vis and Fluorescence spectra for this complex were also determined. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Molecular Structure is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/j.molstruc.2006.05.030
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 6
        StartPage: 149
    Subjects:
      – SubjectFull: Phthalocyanines
        Type: general
      – SubjectFull: Zinc compounds
        Type: general
      – SubjectFull: X-ray diffraction
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      – SubjectFull: Fluorescence spectroscopy
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      – TitleFull: Synthesis, crystal structure and characterization of a new zinc phthalocyanine complex
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            NameFull: Yang, Jin
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            NameFull: Fu, Qiang
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            NameFull: Zhao, Bao-Zhong
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            NameFull: Tian, Lei
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            NameFull: Yu, Hai-Ling
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              Text: Feb2007
              Type: published
              Y: 2007
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