Atomic and electronic structures of surfaces
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| Title: | Atomic and electronic structures of surfaces |
|---|---|
| Authors: | Takeuchi, F.1, Fukuyama, R.1, Hoshino, Y.2, Nishimura, T.1, Kido, Y.1 ykido@se.ritsumei.ac.jp |
| Source: | Surface Science. May2007, Vol. 601 Issue 10, p2203-2213. 11p. |
| Subjects: | Scattering (Physics), Electronic structure, Atomic structure, Spectrum analysis |
| Abstract: | Abstract: The atomic and electronic structures of reconstructions were analyzed by high-resolution medium energy ion scattering (MEIS) combined with photoelectron spectroscopy. We prepared three types of (3×3) surfaces by (a) annealing the Si-rich (2×2) surface at 1030°C, (b) annealing the silicate surface at 1050°C, and (c) annealing the RCA-treated surface at 1050°C in ultra-high vacuum. The present MEIS analysis reveals the fact that the (3×3) surfaces consist of a Si-adlayer (1.1ML), C-adlayer (0.5ML) and C-adatoms (1/3ML)/C-adlayer (2/3ML) on the 1st C–Si bilayer for samples (a), (b) and (c), respectively. Observation of the valence band spectra shows that all the surfaces are semiconducting and have dangling bond states in the band gap (1.4eV below the Fermi level for sample (a)). The Si-rich surface (a) has one surface-related component in Si 2p and in contrast, the C-rich surfaces (b and c) have two surface-related components in C 1s spectra. It is shown that the (3×3) reconstructions of the are categorized into the above three types and take different atomic configurations. For the Si-rich (3×3) surface, the present analysis supports the structure model proposed by Hoster et al. [H.E. Hoster, M.A. Klakov, B. Bullemer, Surf. Sci. 382 (1997) L658]. The probable structures of the C-rich (3×3) surfaces are also discussed in detail. [Copyright &y& Elsevier] |
| Copyright of Surface Science is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 25032636 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Atomic and electronic structures of surfaces – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Takeuchi%2C+F%2E%22">Takeuchi, F.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Fukuyama%2C+R%2E%22">Fukuyama, R.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Hoshino%2C+Y%2E%22">Hoshino, Y.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Nishimura%2C+T%2E%22">Nishimura, T.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Kido%2C+Y%2E%22">Kido, Y.</searchLink><relatesTo>1</relatesTo><i> ykido@se.ritsumei.ac.jp</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Surface+Science%22">Surface Science</searchLink>. May2007, Vol. 601 Issue 10, p2203-2213. 11p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Scattering+%28Physics%29%22">Scattering (Physics)</searchLink><br /><searchLink fieldCode="DE" term="%22Electronic+structure%22">Electronic structure</searchLink><br /><searchLink fieldCode="DE" term="%22Atomic+structure%22">Atomic structure</searchLink><br /><searchLink fieldCode="DE" term="%22Spectrum+analysis%22">Spectrum analysis</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Abstract: The atomic and electronic structures of reconstructions were analyzed by high-resolution medium energy ion scattering (MEIS) combined with photoelectron spectroscopy. We prepared three types of (3×3) surfaces by (a) annealing the Si-rich (2×2) surface at 1030°C, (b) annealing the silicate surface at 1050°C, and (c) annealing the RCA-treated surface at 1050°C in ultra-high vacuum. The present MEIS analysis reveals the fact that the (3×3) surfaces consist of a Si-adlayer (1.1ML), C-adlayer (0.5ML) and C-adatoms (1/3ML)/C-adlayer (2/3ML) on the 1st C–Si bilayer for samples (a), (b) and (c), respectively. Observation of the valence band spectra shows that all the surfaces are semiconducting and have dangling bond states in the band gap (1.4eV below the Fermi level for sample (a)). The Si-rich surface (a) has one surface-related component in Si 2p and in contrast, the C-rich surfaces (b and c) have two surface-related components in C 1s spectra. It is shown that the (3×3) reconstructions of the are categorized into the above three types and take different atomic configurations. For the Si-rich (3×3) surface, the present analysis supports the structure model proposed by Hoster et al. [H.E. Hoster, M.A. Klakov, B. Bullemer, Surf. Sci. 382 (1997) L658]. The probable structures of the C-rich (3×3) surfaces are also discussed in detail. [Copyright &y& Elsevier] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Surface Science is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.susc.2007.03.035 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 11 StartPage: 2203 Subjects: – SubjectFull: Scattering (Physics) Type: general – SubjectFull: Electronic structure Type: general – SubjectFull: Atomic structure Type: general – SubjectFull: Spectrum analysis Type: general Titles: – TitleFull: Atomic and electronic structures of surfaces Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Takeuchi, F. – PersonEntity: Name: NameFull: Fukuyama, R. – PersonEntity: Name: NameFull: Hoshino, Y. – PersonEntity: Name: NameFull: Nishimura, T. – PersonEntity: Name: NameFull: Kido, Y. IsPartOfRelationships: – BibEntity: Dates: – D: 15 M: 05 Text: May2007 Type: published Y: 2007 Identifiers: – Type: issn-print Value: 00396028 Numbering: – Type: volume Value: 601 – Type: issue Value: 10 Titles: – TitleFull: Surface Science Type: main |
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