Novel polyacrylonitrile/Na-MMT/silica nanocomposite: Co-incorporation of two different form nano materials into polymer matrix

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Title: Novel polyacrylonitrile/Na-MMT/silica nanocomposite: Co-incorporation of two different form nano materials into polymer matrix
Authors: Yu, Tianshi1, Lin, Jiaping jplinlab@online.sh.cn, Xu, Jiafu1, Chen, Tao1, Lin, Shaoliang1, Tian, Xiaohui1
Source: Composites Science & Technology. Dec2007, Vol. 67 Issue 15/16, p3219-3225. 7p.
Subjects: Polymers, Polymerization, Silicon compounds, Polymeric composites
Abstract: Abstract: Polyacrylonitrile (PAN)/Na-montmorillonite (Na-MMT)/SiO2 nanocomposites were synthesized via in-situ emulsion polymerization. The X-ray diffraction (XRD) measurements and transmission electron microscopy (TEM) observations show that the Na-MMT layers were exfoliated in polymerization and the nano materials are well dispersed in the polymer matrix. The thermogravimetric analysis (TGA) suggests that co-incorporating Na-MMT and SiO2 into the polymer matrix significantly enhances the thermal stability of the polymer. At same nano material loading, the PAN/Na-MMT/SiO2 nanocomposites show superior thermal stability with respect to the PAN/Na-MMT and PAN/SiO2 nanocomposites. The mechanical properties of the nanocomposites were also examined. It was found that the PAN/Na-MMT/SiO2 nanocomposites exhibit considerably enhanced moduli compared with the PAN/Na-MMT and PAN/SiO2 nanocomposites due to the synergistic reinforcing effect. [Copyright &y& Elsevier]
Copyright of Composites Science & Technology is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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An: 27052089
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  Data: Novel polyacrylonitrile/Na-MMT/silica nanocomposite: Co-incorporation of two different form nano materials into polymer matrix
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  Data: <searchLink fieldCode="AR" term="%22Yu%2C+Tianshi%22">Yu, Tianshi</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Lin%2C+Jiaping%22">Lin, Jiaping</searchLink><i> jplinlab@online.sh.cn</i><br /><searchLink fieldCode="AR" term="%22Xu%2C+Jiafu%22">Xu, Jiafu</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Chen%2C+Tao%22">Chen, Tao</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Lin%2C+Shaoliang%22">Lin, Shaoliang</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Tian%2C+Xiaohui%22">Tian, Xiaohui</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Composites+Science+%26+Technology%22">Composites Science & Technology</searchLink>. Dec2007, Vol. 67 Issue 15/16, p3219-3225. 7p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Polymers%22">Polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Polymerization%22">Polymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Silicon+compounds%22">Silicon compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Polymeric+composites%22">Polymeric composites</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: Polyacrylonitrile (PAN)/Na-montmorillonite (Na-MMT)/SiO2 nanocomposites were synthesized via in-situ emulsion polymerization. The X-ray diffraction (XRD) measurements and transmission electron microscopy (TEM) observations show that the Na-MMT layers were exfoliated in polymerization and the nano materials are well dispersed in the polymer matrix. The thermogravimetric analysis (TGA) suggests that co-incorporating Na-MMT and SiO2 into the polymer matrix significantly enhances the thermal stability of the polymer. At same nano material loading, the PAN/Na-MMT/SiO2 nanocomposites show superior thermal stability with respect to the PAN/Na-MMT and PAN/SiO2 nanocomposites. The mechanical properties of the nanocomposites were also examined. It was found that the PAN/Na-MMT/SiO2 nanocomposites exhibit considerably enhanced moduli compared with the PAN/Na-MMT and PAN/SiO2 nanocomposites due to the synergistic reinforcing effect. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Composites Science & Technology is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/j.compscitech.2007.04.004
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      – Code: eng
        Text: English
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        PageCount: 7
        StartPage: 3219
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      – SubjectFull: Polymers
        Type: general
      – SubjectFull: Polymerization
        Type: general
      – SubjectFull: Silicon compounds
        Type: general
      – SubjectFull: Polymeric composites
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      – TitleFull: Novel polyacrylonitrile/Na-MMT/silica nanocomposite: Co-incorporation of two different form nano materials into polymer matrix
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            NameFull: Yu, Tianshi
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            NameFull: Lin, Jiaping
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            NameFull: Xu, Jiafu
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            NameFull: Chen, Tao
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            NameFull: Lin, Shaoliang
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            NameFull: Tian, Xiaohui
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            – D: 01
              M: 12
              Text: Dec2007
              Type: published
              Y: 2007
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              Value: 67
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              Value: 15/16
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