Synthesis and structural characterization of new p-ferrocenylphenylacetylene bridged cobalt carbonyl clusters
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| Title: | Synthesis and structural characterization of new p-ferrocenylphenylacetylene bridged cobalt carbonyl clusters |
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| Authors: | Li-Ying Wang1, Quan-Ling Suo1 szj@imut.edu.cn, Li-Min Han1, Yi-Bing Wang1, Lin-Hong Weng2 |
| Source: | Polyhedron. Oct2007, Vol. 26 Issue 17, p4981-4985. 5p. |
| Subjects: | Cobalt, Phosgene, Molecular structure, Crystallization |
| Abstract: | A new ferrocenylphenyl butadiynyl compound Fc–C6H4–(C≡C)2–C6H5 (L) has been synthesized by the Glaser cross-coupling reaction and three new complexes with a 4-ferrocenylphenyl-μ-alkyne-dicobalt moiety, [Fc–C6H4–(C≡C)n–R][Co2(CO)6]n′ [Fc=C5H5FeC5H4, R=H, n=1, n′=1 (1); R=C6H5, n=2, n′=2 (2); R=Fc-C6H4, n=2, n′=2 (3) ], were obtained in the reaction of p-ferrocenylphenylacetylene compounds with Co2(CO)8. Compounds L, 1, 2 and 3 were characterized by elemental analysis, IR, 1H, 13C NMR and MS. The molecular and crystal structures of compounds L and 2 have been determined by X-ray single crystal analysis. There is a linear C5H4–C6H4–(C≡C)2–C6H5 linkage in compound L, and the terminal ferrocenylphenyl and phenyl groups in complex 2 are a cis arrangement. [Copyright &y& Elsevier] |
| Copyright of Polyhedron is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 27052151 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Synthesis and structural characterization of new p-ferrocenylphenylacetylene bridged cobalt carbonyl clusters – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Li-Ying+Wang%22">Li-Ying Wang</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Quan-Ling+Suo%22">Quan-Ling Suo</searchLink><relatesTo>1</relatesTo><i> szj@imut.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Li-Min+Han%22">Li-Min Han</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yi-Bing+Wang%22">Yi-Bing Wang</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Lin-Hong+Weng%22">Lin-Hong Weng</searchLink><relatesTo>2</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Polyhedron%22">Polyhedron</searchLink>. Oct2007, Vol. 26 Issue 17, p4981-4985. 5p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Cobalt%22">Cobalt</searchLink><br /><searchLink fieldCode="DE" term="%22Phosgene%22">Phosgene</searchLink><br /><searchLink fieldCode="DE" term="%22Molecular+structure%22">Molecular structure</searchLink><br /><searchLink fieldCode="DE" term="%22Crystallization%22">Crystallization</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: A new ferrocenylphenyl butadiynyl compound Fc–C6H4–(C≡C)2–C6H5 (L) has been synthesized by the Glaser cross-coupling reaction and three new complexes with a 4-ferrocenylphenyl-μ-alkyne-dicobalt moiety, [Fc–C6H4–(C≡C)n–R][Co2(CO)6]n′ [Fc=C5H5FeC5H4, R=H, n=1, n′=1 (1); R=C6H5, n=2, n′=2 (2); R=Fc-C6H4, n=2, n′=2 (3) ], were obtained in the reaction of p-ferrocenylphenylacetylene compounds with Co2(CO)8. Compounds L, 1, 2 and 3 were characterized by elemental analysis, IR, 1H, 13C NMR and MS. The molecular and crystal structures of compounds L and 2 have been determined by X-ray single crystal analysis. There is a linear C5H4–C6H4–(C≡C)2–C6H5 linkage in compound L, and the terminal ferrocenylphenyl and phenyl groups in complex 2 are a cis arrangement. [Copyright &y& Elsevier] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Polyhedron is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.poly.2007.07.017 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 5 StartPage: 4981 Subjects: – SubjectFull: Cobalt Type: general – SubjectFull: Phosgene Type: general – SubjectFull: Molecular structure Type: general – SubjectFull: Crystallization Type: general Titles: – TitleFull: Synthesis and structural characterization of new p-ferrocenylphenylacetylene bridged cobalt carbonyl clusters Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Li-Ying Wang – PersonEntity: Name: NameFull: Quan-Ling Suo – PersonEntity: Name: NameFull: Li-Min Han – PersonEntity: Name: NameFull: Yi-Bing Wang – PersonEntity: Name: NameFull: Lin-Hong Weng IsPartOfRelationships: – BibEntity: Dates: – D: 30 M: 10 Text: Oct2007 Type: published Y: 2007 Identifiers: – Type: issn-print Value: 02775387 Numbering: – Type: volume Value: 26 – Type: issue Value: 17 Titles: – TitleFull: Polyhedron Type: main |
| ResultId | 1 |
