Radiation grafting of N,N′-dimethylacrylamide and N-isopropylacrylamide onto polypropylene films by two-step method

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Title: Radiation grafting of N,N′-dimethylacrylamide and N-isopropylacrylamide onto polypropylene films by two-step method
Authors: Contreras-García, A.1, Burillo, G.1, Aliev, R.1, Bucio, E. ebucio@nucleares.unam.mx
Source: Radiation Physics & Chemistry. Aug2008, Vol. 77 Issue 8, p936-940. 5p.
Subjects: Radiation, Acrylamide, Polypropylene, Spectrum analysis
Abstract: Abstract: Polypropylene (PP) films were modified by the consecutive grafting of N,N′-dimethylacrylamide (DMAAm) and N-isopropylacrylamide (NIPAAm) (two-step method) using preirradiation method with gamma-rays. The effect of absorbed dose, monomer concentration and reaction time on the degree of grafting was determined. The grafted samples were verified by the FTIR-ATR spectroscopy; thermal properties were analyzed by differential scanning calorimetry (DSC) and the stimuli-responsive behavior was studied by swelling and contact angle in water as well as DSC. Thermoresponsive films of (PP-g-DMAAm)-g-NIPAAm presented a lower critical solution temperature (LCST) at 36.5°C. [Copyright &y& Elsevier]
Copyright of Radiation Physics & Chemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 32555184
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  Data: Radiation grafting of N,N′-dimethylacrylamide and N-isopropylacrylamide onto polypropylene films by two-step method
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  Data: <searchLink fieldCode="AR" term="%22Contreras-García%2C+A%2E%22">Contreras-García, A.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Burillo%2C+G%2E%22">Burillo, G.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Aliev%2C+R%2E%22">Aliev, R.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Bucio%2C+E%2E%22">Bucio, E.</searchLink><i> ebucio@nucleares.unam.mx</i>
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  Data: <searchLink fieldCode="JN" term="%22Radiation+Physics+%26+Chemistry%22">Radiation Physics & Chemistry</searchLink>. Aug2008, Vol. 77 Issue 8, p936-940. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Radiation%22">Radiation</searchLink><br /><searchLink fieldCode="DE" term="%22Acrylamide%22">Acrylamide</searchLink><br /><searchLink fieldCode="DE" term="%22Polypropylene%22">Polypropylene</searchLink><br /><searchLink fieldCode="DE" term="%22Spectrum+analysis%22">Spectrum analysis</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Abstract: Polypropylene (PP) films were modified by the consecutive grafting of N,N′-dimethylacrylamide (DMAAm) and N-isopropylacrylamide (NIPAAm) (two-step method) using preirradiation method with gamma-rays. The effect of absorbed dose, monomer concentration and reaction time on the degree of grafting was determined. The grafted samples were verified by the FTIR-ATR spectroscopy; thermal properties were analyzed by differential scanning calorimetry (DSC) and the stimuli-responsive behavior was studied by swelling and contact angle in water as well as DSC. Thermoresponsive films of (PP-g-DMAAm)-g-NIPAAm presented a lower critical solution temperature (LCST) at 36.5°C. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
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  Group: Ab
  Data: <i>Copyright of Radiation Physics & Chemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.radphyschem.2008.02.007
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      – Code: eng
        Text: English
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    Subjects:
      – SubjectFull: Radiation
        Type: general
      – SubjectFull: Acrylamide
        Type: general
      – SubjectFull: Polypropylene
        Type: general
      – SubjectFull: Spectrum analysis
        Type: general
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      – TitleFull: Radiation grafting of N,N′-dimethylacrylamide and N-isopropylacrylamide onto polypropylene films by two-step method
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            NameFull: Burillo, G.
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            NameFull: Aliev, R.
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              M: 08
              Text: Aug2008
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              Y: 2008
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