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Crystal structure of a Zn-doped derivative of the Li17Ge4 compound

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Title: Crystal structure of a Zn-doped derivative of the Li17Ge4 compound
Authors: Lacroix-Orio, L.1, Tillard, M. mtillard@univ-montp2.fr, Belin, C.1
Source: Journal of Alloys & Compounds. Oct2008, Vol. 465 Issue 1/2, p47-50. 4p.
Subjects: Nanoparticles, Hydrides, Thermodynamics, Electron microscopy
Abstract: Abstract: The compound Li17−ɛZnɛGe4 has been obtained as a side product during the preparation of the intermetallic compound Li8Zn2Ge3 from the elements. Its structure has been determined from single crystal X-ray diffraction intensities measured at 173K. It crystallizes in the cubic system, space group, a =18.842(1)Å, Z =20. Its crystal structure is slightly different from those so far reported in the literature for the Zn-free phase Li17Ge4, particularly concerned are the positions and the site occupations of Li atoms. Most likely, these structural variations result from the presence of a small Zn concentration in the compound. The Zn doping atom has been found only at the specific Li 4d site (about 3at.% Zn). [Copyright &y& Elsevier]
Copyright of Journal of Alloys & Compounds is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 34090081
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: Crystal structure of a Zn-doped derivative of the Li<subscript>17</subscript>Ge<subscript>4</subscript> compound
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  Data: <searchLink fieldCode="AR" term="%22Lacroix-Orio%2C+L%2E%22">Lacroix-Orio, L.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Tillard%2C+M%2E%22">Tillard, M.</searchLink><i> mtillard@univ-montp2.fr</i><br /><searchLink fieldCode="AR" term="%22Belin%2C+C%2E%22">Belin, C.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Alloys+%26+Compounds%22">Journal of Alloys & Compounds</searchLink>. Oct2008, Vol. 465 Issue 1/2, p47-50. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Nanoparticles%22">Nanoparticles</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrides%22">Hydrides</searchLink><br /><searchLink fieldCode="DE" term="%22Thermodynamics%22">Thermodynamics</searchLink><br /><searchLink fieldCode="DE" term="%22Electron+microscopy%22">Electron microscopy</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: The compound Li17−ɛZnɛGe4 has been obtained as a side product during the preparation of the intermetallic compound Li8Zn2Ge3 from the elements. Its structure has been determined from single crystal X-ray diffraction intensities measured at 173K. It crystallizes in the cubic system, space group, a =18.842(1)Å, Z =20. Its crystal structure is slightly different from those so far reported in the literature for the Zn-free phase Li17Ge4, particularly concerned are the positions and the site occupations of Li atoms. Most likely, these structural variations result from the presence of a small Zn concentration in the compound. The Zn doping atom has been found only at the specific Li 4d site (about 3at.% Zn). [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Alloys & Compounds is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.jallcom.2007.10.140
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      – Code: eng
        Text: English
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        PageCount: 4
        StartPage: 47
    Subjects:
      – SubjectFull: Nanoparticles
        Type: general
      – SubjectFull: Hydrides
        Type: general
      – SubjectFull: Thermodynamics
        Type: general
      – SubjectFull: Electron microscopy
        Type: general
    Titles:
      – TitleFull: Crystal structure of a Zn-doped derivative of the Li17Ge4 compound
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            NameFull: Lacroix-Orio, L.
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            NameFull: Tillard, M.
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            NameFull: Belin, C.
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              M: 10
              Text: Oct2008
              Type: published
              Y: 2008
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              Value: 465
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              Value: 1/2
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            – TitleFull: Journal of Alloys & Compounds
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