Sensing H2O2 with layer-by-layer assembled Fe3O4–PDDA nanocomposite film

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Title: Sensing H2O2 with layer-by-layer assembled Fe3O4–PDDA nanocomposite film
Authors: Zhang, Lihua1, Zhai, Yueming1, Gao, Na1, Wen, Dan1, Dong, Shaojun dongsj@ciac.jl.cn
Source: Electrochemistry Communications. Oct2008, Vol. 10 Issue 10, p1524-1526. 3p.
Subjects: Electrochemistry, Physical & theoretical chemistry, Nanostructures, Physics
Abstract: Abstract: It was found that Fe3O4 nanoparticles (Fe3O4 NPs) possess intrinsic enzyme mimetic activity similar to that found in natural peroxidase. Here, we applied Fe3O4 NPs to the construction of efficient electrochemical sensor to detect the concentration of hydrogen peroxide. The sensor was fabricated with layer-by-layer assembly of Fe3O4 NPs and poly(diallyldimethylammonium chloride) (PDDA) through the electrostatic interaction, and the multilayer film was characterized with UV–vis absorption spectra, atomic force microscopy, and cyclic voltammetry. Moreover, the sensor showed prominent electrocatalytic activity toward the reduction of H2O2, and the interferences of ascorbic acid (AA) and uric acid (UA) were completely avoided. Unlike the inherent instability of enzyme, Fe3O4 NPs-based sensor demonstrated outstanding stability. [Copyright &y& Elsevier]
Copyright of Electrochemistry Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
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  Data: <searchLink fieldCode="AR" term="%22Zhang%2C+Lihua%22">Zhang, Lihua</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Zhai%2C+Yueming%22">Zhai, Yueming</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Gao%2C+Na%22">Gao, Na</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Wen%2C+Dan%22">Wen, Dan</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Dong%2C+Shaojun%22">Dong, Shaojun</searchLink><i> dongsj@ciac.jl.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Electrochemistry+Communications%22">Electrochemistry Communications</searchLink>. Oct2008, Vol. 10 Issue 10, p1524-1526. 3p.
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  Data: <searchLink fieldCode="DE" term="%22Electrochemistry%22">Electrochemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Physical+%26+theoretical+chemistry%22">Physical & theoretical chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Nanostructures%22">Nanostructures</searchLink><br /><searchLink fieldCode="DE" term="%22Physics%22">Physics</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Abstract: It was found that Fe3O4 nanoparticles (Fe3O4 NPs) possess intrinsic enzyme mimetic activity similar to that found in natural peroxidase. Here, we applied Fe3O4 NPs to the construction of efficient electrochemical sensor to detect the concentration of hydrogen peroxide. The sensor was fabricated with layer-by-layer assembly of Fe3O4 NPs and poly(diallyldimethylammonium chloride) (PDDA) through the electrostatic interaction, and the multilayer film was characterized with UV–vis absorption spectra, atomic force microscopy, and cyclic voltammetry. Moreover, the sensor showed prominent electrocatalytic activity toward the reduction of H2O2, and the interferences of ascorbic acid (AA) and uric acid (UA) were completely avoided. Unlike the inherent instability of enzyme, Fe3O4 NPs-based sensor demonstrated outstanding stability. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Electrochemistry Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.elecom.2008.05.022
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      – Code: eng
        Text: English
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      – SubjectFull: Nanostructures
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              M: 10
              Text: Oct2008
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              Y: 2008
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