Adsorption of hydrogen on Pt(111) and Pt(100) surfaces and its role in the HOR
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| Title: | Adsorption of hydrogen on Pt(111) and Pt(100) surfaces and its role in the HOR |
|---|---|
| Authors: | Strmcnik, D. strmcnik@anl.gov, Tripkovic, D.1, van der Vliet, D.1, Stamenkovic, V.1, Marković, N.M.1 |
| Source: | Electrochemistry Communications. Oct2008, Vol. 10 Issue 10, p1602-1605. 4p. |
| Subjects: | Electrochemistry, Physical & theoretical chemistry, Adsorption (Chemistry), Hydrogen |
| Abstract: | Abstract: Hydrogen adsorption isotherms, evaluated by combination of cyclic voltammetry and chronoamperometry, are reported on Pt(111) and Pt(100) surfaces in 0.1M HClO4. We found that at E >0.05V Pt(111) and Pt(100) are only partially covered by the adsorbed hydrogen (Had). On both surfaces, a full monolayer of the adsorbed hydrogen is completed at −0.1V, i.e. the adsorption of atomic hydrogen is observed in the hydrogen evolution potential region. We also found, that the activity of the hydrogen oxidation reaction is mirrored by the shape of the hydrogen adsorption isotherms, implying that Had is in fact a spectator in the HOR. [Copyright &y& Elsevier] |
| Copyright of Electrochemistry Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 34535112 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Adsorption of hydrogen on Pt(111) and Pt(100) surfaces and its role in the HOR – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Strmcnik%2C+D%2E%22">Strmcnik, D.</searchLink><i> strmcnik@anl.gov</i><br /><searchLink fieldCode="AR" term="%22Tripkovic%2C+D%2E%22">Tripkovic, D.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22van+der+Vliet%2C+D%2E%22">van der Vliet, D.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Stamenkovic%2C+V%2E%22">Stamenkovic, V.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Marković%2C+N%2EM%2E%22">Marković, N.M.</searchLink><relatesTo>1</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Electrochemistry+Communications%22">Electrochemistry Communications</searchLink>. Oct2008, Vol. 10 Issue 10, p1602-1605. 4p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Electrochemistry%22">Electrochemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Physical+%26+theoretical+chemistry%22">Physical & theoretical chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Adsorption+%28Chemistry%29%22">Adsorption (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen%22">Hydrogen</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Abstract: Hydrogen adsorption isotherms, evaluated by combination of cyclic voltammetry and chronoamperometry, are reported on Pt(111) and Pt(100) surfaces in 0.1M HClO4. We found that at E >0.05V Pt(111) and Pt(100) are only partially covered by the adsorbed hydrogen (Had). On both surfaces, a full monolayer of the adsorbed hydrogen is completed at −0.1V, i.e. the adsorption of atomic hydrogen is observed in the hydrogen evolution potential region. We also found, that the activity of the hydrogen oxidation reaction is mirrored by the shape of the hydrogen adsorption isotherms, implying that Had is in fact a spectator in the HOR. [Copyright &y& Elsevier] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Electrochemistry Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.elecom.2008.08.019 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 4 StartPage: 1602 Subjects: – SubjectFull: Electrochemistry Type: general – SubjectFull: Physical & theoretical chemistry Type: general – SubjectFull: Adsorption (Chemistry) Type: general – SubjectFull: Hydrogen Type: general Titles: – TitleFull: Adsorption of hydrogen on Pt(111) and Pt(100) surfaces and its role in the HOR Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Strmcnik, D. – PersonEntity: Name: NameFull: Tripkovic, D. – PersonEntity: Name: NameFull: van der Vliet, D. – PersonEntity: Name: NameFull: Stamenkovic, V. – PersonEntity: Name: NameFull: Marković, N.M. IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 10 Text: Oct2008 Type: published Y: 2008 Identifiers: – Type: issn-print Value: 13882481 Numbering: – Type: volume Value: 10 – Type: issue Value: 10 Titles: – TitleFull: Electrochemistry Communications Type: main |
| ResultId | 1 |
