Impact of the Se evaporation rate on the microstructure and texture of Cu(In,Ga)Se2 thin films for solar cells
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| Title: | Impact of the Se evaporation rate on the microstructure and texture of Cu(In,Ga)Se |
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| Authors: | Abou-Ras, D.1 daniel.abou-ras@hmi.de, Contreras, M.A.2, Noufi, R.2, Schock, H.-W.1 |
| Source: | Thin Solid Films. Feb2009, Vol. 517 Issue 7, p2218-2221. 4p. |
| Subjects: | Selenium, Evaporation (Chemistry), Chalcopyrite, Thin films, Solar cells, Microstructure, Crystal texture |
| Abstract: | Abstract: Coevaporated Cu(In,Ga)Se2 layers on Mo-coated soda-lime glass substrates were produced by a three-stage process using various Se overpressure conditions during the three stages. Cross-sections of these samples were analyzed by electron backscatter diffraction (EBSD) in a scanning electron microscope in order to reveal the microstructures in the Cu(In,Ga)Se2 layers. In addition, the preferential orientations of these Cu(In,Ga)Se2 layers were studied by plan-view EBSD measurements. It was found that Cu(In,Ga)Se2 exhibits a texture in 110 orientation for Se/(Cu+In+Ga) atomic flux ratios R which are sufficiently large (≥4). In one Cu(In,Ga)Se2 layer produced with approximately R =4, a large density of (near) Σ3 (twin) boundaries were detected which are oriented preferentially perpendicular to the substrate. By comparison of the local textures of neighboring grains and the theoretically possible changes in orientation by twinning, it is possible to retrace how the twinning occurred. [Copyright &y& Elsevier] |
| Copyright of Thin Solid Films is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 36404393 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Impact of the Se evaporation rate on the microstructure and texture of Cu(In,Ga)Se<subscript>2</subscript> thin films for solar cells – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Abou-Ras%2C+D%2E%22">Abou-Ras, D.</searchLink><relatesTo>1</relatesTo><i> daniel.abou-ras@hmi.de</i><br /><searchLink fieldCode="AR" term="%22Contreras%2C+M%2EA%2E%22">Contreras, M.A.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Noufi%2C+R%2E%22">Noufi, R.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Schock%2C+H%2E-W%2E%22">Schock, H.-W.</searchLink><relatesTo>1</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Thin+Solid+Films%22">Thin Solid Films</searchLink>. Feb2009, Vol. 517 Issue 7, p2218-2221. 4p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Selenium%22">Selenium</searchLink><br /><searchLink fieldCode="DE" term="%22Evaporation+%28Chemistry%29%22">Evaporation (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Chalcopyrite%22">Chalcopyrite</searchLink><br /><searchLink fieldCode="DE" term="%22Thin+films%22">Thin films</searchLink><br /><searchLink fieldCode="DE" term="%22Solar+cells%22">Solar cells</searchLink><br /><searchLink fieldCode="DE" term="%22Microstructure%22">Microstructure</searchLink><br /><searchLink fieldCode="DE" term="%22Crystal+texture%22">Crystal texture</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Abstract: Coevaporated Cu(In,Ga)Se2 layers on Mo-coated soda-lime glass substrates were produced by a three-stage process using various Se overpressure conditions during the three stages. Cross-sections of these samples were analyzed by electron backscatter diffraction (EBSD) in a scanning electron microscope in order to reveal the microstructures in the Cu(In,Ga)Se2 layers. In addition, the preferential orientations of these Cu(In,Ga)Se2 layers were studied by plan-view EBSD measurements. It was found that Cu(In,Ga)Se2 exhibits a texture in 110 orientation for Se/(Cu+In+Ga) atomic flux ratios R which are sufficiently large (≥4). In one Cu(In,Ga)Se2 layer produced with approximately R =4, a large density of (near) Σ3 (twin) boundaries were detected which are oriented preferentially perpendicular to the substrate. By comparison of the local textures of neighboring grains and the theoretically possible changes in orientation by twinning, it is possible to retrace how the twinning occurred. [Copyright &y& Elsevier] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Thin Solid Films is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.tsf.2008.10.133 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 4 StartPage: 2218 Subjects: – SubjectFull: Selenium Type: general – SubjectFull: Evaporation (Chemistry) Type: general – SubjectFull: Chalcopyrite Type: general – SubjectFull: Thin films Type: general – SubjectFull: Solar cells Type: general – SubjectFull: Microstructure Type: general – SubjectFull: Crystal texture Type: general Titles: – TitleFull: Impact of the Se evaporation rate on the microstructure and texture of Cu(In,Ga)Se2 thin films for solar cells Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Abou-Ras, D. – PersonEntity: Name: NameFull: Contreras, M.A. – PersonEntity: Name: NameFull: Noufi, R. – PersonEntity: Name: NameFull: Schock, H.-W. IsPartOfRelationships: – BibEntity: Dates: – D: 02 M: 02 Text: Feb2009 Type: published Y: 2009 Identifiers: – Type: issn-print Value: 00406090 Numbering: – Type: volume Value: 517 – Type: issue Value: 7 Titles: – TitleFull: Thin Solid Films Type: main |
| ResultId | 1 |