Impact of the Se evaporation rate on the microstructure and texture of Cu(In,Ga)Se2 thin films for solar cells

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Title: Impact of the Se evaporation rate on the microstructure and texture of Cu(In,Ga)Se2 thin films for solar cells
Authors: Abou-Ras, D.1 daniel.abou-ras@hmi.de, Contreras, M.A.2, Noufi, R.2, Schock, H.-W.1
Source: Thin Solid Films. Feb2009, Vol. 517 Issue 7, p2218-2221. 4p.
Subjects: Selenium, Evaporation (Chemistry), Chalcopyrite, Thin films, Solar cells, Microstructure, Crystal texture
Abstract: Abstract: Coevaporated Cu(In,Ga)Se2 layers on Mo-coated soda-lime glass substrates were produced by a three-stage process using various Se overpressure conditions during the three stages. Cross-sections of these samples were analyzed by electron backscatter diffraction (EBSD) in a scanning electron microscope in order to reveal the microstructures in the Cu(In,Ga)Se2 layers. In addition, the preferential orientations of these Cu(In,Ga)Se2 layers were studied by plan-view EBSD measurements. It was found that Cu(In,Ga)Se2 exhibits a texture in 110 orientation for Se/(Cu+In+Ga) atomic flux ratios R which are sufficiently large (≥4). In one Cu(In,Ga)Se2 layer produced with approximately R =4, a large density of (near) Σ3 (twin) boundaries were detected which are oriented preferentially perpendicular to the substrate. By comparison of the local textures of neighboring grains and the theoretically possible changes in orientation by twinning, it is possible to retrace how the twinning occurred. [Copyright &y& Elsevier]
Copyright of Thin Solid Films is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Impact of the Se evaporation rate on the microstructure and texture of Cu(In,Ga)Se<subscript>2</subscript> thin films for solar cells
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  Data: <searchLink fieldCode="AR" term="%22Abou-Ras%2C+D%2E%22">Abou-Ras, D.</searchLink><relatesTo>1</relatesTo><i> daniel.abou-ras@hmi.de</i><br /><searchLink fieldCode="AR" term="%22Contreras%2C+M%2EA%2E%22">Contreras, M.A.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Noufi%2C+R%2E%22">Noufi, R.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Schock%2C+H%2E-W%2E%22">Schock, H.-W.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Thin+Solid+Films%22">Thin Solid Films</searchLink>. Feb2009, Vol. 517 Issue 7, p2218-2221. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Selenium%22">Selenium</searchLink><br /><searchLink fieldCode="DE" term="%22Evaporation+%28Chemistry%29%22">Evaporation (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Chalcopyrite%22">Chalcopyrite</searchLink><br /><searchLink fieldCode="DE" term="%22Thin+films%22">Thin films</searchLink><br /><searchLink fieldCode="DE" term="%22Solar+cells%22">Solar cells</searchLink><br /><searchLink fieldCode="DE" term="%22Microstructure%22">Microstructure</searchLink><br /><searchLink fieldCode="DE" term="%22Crystal+texture%22">Crystal texture</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: Coevaporated Cu(In,Ga)Se2 layers on Mo-coated soda-lime glass substrates were produced by a three-stage process using various Se overpressure conditions during the three stages. Cross-sections of these samples were analyzed by electron backscatter diffraction (EBSD) in a scanning electron microscope in order to reveal the microstructures in the Cu(In,Ga)Se2 layers. In addition, the preferential orientations of these Cu(In,Ga)Se2 layers were studied by plan-view EBSD measurements. It was found that Cu(In,Ga)Se2 exhibits a texture in 110 orientation for Se/(Cu+In+Ga) atomic flux ratios R which are sufficiently large (≥4). In one Cu(In,Ga)Se2 layer produced with approximately R =4, a large density of (near) Σ3 (twin) boundaries were detected which are oriented preferentially perpendicular to the substrate. By comparison of the local textures of neighboring grains and the theoretically possible changes in orientation by twinning, it is possible to retrace how the twinning occurred. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Thin Solid Films is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.tsf.2008.10.133
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      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 4
        StartPage: 2218
    Subjects:
      – SubjectFull: Selenium
        Type: general
      – SubjectFull: Evaporation (Chemistry)
        Type: general
      – SubjectFull: Chalcopyrite
        Type: general
      – SubjectFull: Thin films
        Type: general
      – SubjectFull: Solar cells
        Type: general
      – SubjectFull: Microstructure
        Type: general
      – SubjectFull: Crystal texture
        Type: general
    Titles:
      – TitleFull: Impact of the Se evaporation rate on the microstructure and texture of Cu(In,Ga)Se2 thin films for solar cells
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            NameFull: Abou-Ras, D.
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            NameFull: Contreras, M.A.
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            NameFull: Noufi, R.
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            NameFull: Schock, H.-W.
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              Text: Feb2009
              Type: published
              Y: 2009
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              Value: 517
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            – TitleFull: Thin Solid Films
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