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A homoleptic SPS-based complex and a double-cubane-type sulfur cluster of an actinide element

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Title: A homoleptic SPS-based complex and a double-cubane-type sulfur cluster of an actinide element
Authors: Arliguie, Thérèse1 arliguieth@corning.com, Thuéry, Pierre1, Floch, Pascal Le2, Mézailles, Nicolas2 mezailles@poly.polytechnique.fr, Ephritikhine, Michel1 michel.ephritikhine@cea.fr
Source: Polyhedron. Jun2009, Vol. 28 Issue 8, p1578-1582. 5p.
Subjects: Ligands (Chemistry), Metal complexes, Sulfides, Microclusters, Actinide elements, Cations, Chemical reactions, Hydrocarbons
Abstract: Abstract: Treatment of UI3(THF)4 with [M(Et2O)][SPSMe] (M=Li, K; [SPSMe]− =1-methyl-2,6-bis(diphenylphosphine sulfide)-3,5-diphenylphosphinine anion) gave the cationic tris SPS complex [U(SPSMe)3]I (1). Similar reaction of U(BH4)3(THF)3 and [M(Et2O)][SPSMe] afforded, in addition to the [U(SPS)3]+ cation, crystals of the sulfido complex [U{(μ3-S)4U3(SPSMe)3(BH4)3}2] (2). The metal environment in 1 is a tricapped trigonal prism and the core of the heptanuclear cluster 2 is a corner-shared double-cubane. [Copyright &y& Elsevier]
Copyright of Polyhedron is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 40116917
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  Data: A homoleptic SPS-based complex and a double-cubane-type sulfur cluster of an actinide element
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  Data: <searchLink fieldCode="AR" term="%22Arliguie%2C+Thérèse%22">Arliguie, Thérèse</searchLink><relatesTo>1</relatesTo><i> arliguieth@corning.com</i><br /><searchLink fieldCode="AR" term="%22Thuéry%2C+Pierre%22">Thuéry, Pierre</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Floch%2C+Pascal+Le%22">Floch, Pascal Le</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Mézailles%2C+Nicolas%22">Mézailles, Nicolas</searchLink><relatesTo>2</relatesTo><i> mezailles@poly.polytechnique.fr</i><br /><searchLink fieldCode="AR" term="%22Ephritikhine%2C+Michel%22">Ephritikhine, Michel</searchLink><relatesTo>1</relatesTo><i> michel.ephritikhine@cea.fr</i>
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  Data: <searchLink fieldCode="JN" term="%22Polyhedron%22">Polyhedron</searchLink>. Jun2009, Vol. 28 Issue 8, p1578-1582. 5p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+complexes%22">Metal complexes</searchLink><br /><searchLink fieldCode="DE" term="%22Sulfides%22">Sulfides</searchLink><br /><searchLink fieldCode="DE" term="%22Microclusters%22">Microclusters</searchLink><br /><searchLink fieldCode="DE" term="%22Actinide+elements%22">Actinide elements</searchLink><br /><searchLink fieldCode="DE" term="%22Cations%22">Cations</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reactions%22">Chemical reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrocarbons%22">Hydrocarbons</searchLink>
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  Data: Abstract: Treatment of UI3(THF)4 with [M(Et2O)][SPSMe] (M=Li, K; [SPSMe]− =1-methyl-2,6-bis(diphenylphosphine sulfide)-3,5-diphenylphosphinine anion) gave the cationic tris SPS complex [U(SPSMe)3]I (1). Similar reaction of U(BH4)3(THF)3 and [M(Et2O)][SPSMe] afforded, in addition to the [U(SPS)3]+ cation, crystals of the sulfido complex [U{(μ3-S)4U3(SPSMe)3(BH4)3}2] (2). The metal environment in 1 is a tricapped trigonal prism and the core of the heptanuclear cluster 2 is a corner-shared double-cubane. [Copyright &y& Elsevier]
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  Data: <i>Copyright of Polyhedron is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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        Value: 10.1016/j.poly.2009.03.027
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      – Code: eng
        Text: English
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        PageCount: 5
        StartPage: 1578
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      – SubjectFull: Ligands (Chemistry)
        Type: general
      – SubjectFull: Metal complexes
        Type: general
      – SubjectFull: Sulfides
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      – SubjectFull: Microclusters
        Type: general
      – SubjectFull: Actinide elements
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      – SubjectFull: Cations
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      – SubjectFull: Chemical reactions
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      – SubjectFull: Hydrocarbons
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      – TitleFull: A homoleptic SPS-based complex and a double-cubane-type sulfur cluster of an actinide element
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            NameFull: Arliguie, Thérèse
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            NameFull: Thuéry, Pierre
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            NameFull: Floch, Pascal Le
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              Text: Jun2009
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